[Bioactive coats on titanium implants and biocompatibility of titanium compounds for orthopedic implants].
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The corrosion behaviors of Ti, Ti-6Al-7Nb and Ti-6Al-4V alloys, and an experimentally produced Ti-0.5Pt alloy in 0.05% to 2.0% concentrations of Acidulated Phosphate Fluoride (APF) solutions (corresponding to 226 to 9,050 ppm fluoride at pH 3.5 or 3.6) were examined. While the corrosion of Ti, Ti-6Al-7Nb and Ti-6Al-4V alloys might occur easily even in a diluted 0.05% APF solution, dissolution of Ti from the Ti-0.5Pt alloy was observed only in test solutions with APF concentration exceeding 0.2%. When Ti-6Al-7Nb and Ti-6Al-4V alloys were immersed in 2.0% APF solution, their surfaces were entirely covered by compact corrosion products of Na3TiF6 due to severe corrosion. As a result, Ti dissolution was prevented and the amount of Ti dissolved decreased. However, since Ti was covered by porous, large-sized corrosion products of Na3TiF6 and that Ti-0.5Pt alloy was not covered with any corrosion product, the amount of Ti dissolved increased in the 2.0% APF solution.
The adaptability of the upper complete denture base made from superplastic alloy 90Ti-6A1-4V was investigated by measuring the space between the master model and the denture base. The denture bases showed a high adaptability with the space less than 0.1 mm, whereas after curing resin for denture, it became worse especially with the heat-curing resin. In addition, the thinnest area of the denture base was observed at the middle of the plate with 38% reduction in thickness, and distortion of the base plate of 0.55mm thickness by curing resin was found to be nearly the same as that of type 304 stainless steel plate of 0.50 mm thickness.
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