PubMed · 7103435
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R A Robb. 1982. X-ray computed tomography: from basic principles to applications.. https://doi.org/10.1146/annurev.bb.11.060182.001141
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Small deformation dynamic oscillation was used to develop an index of physical significance for the rationalisation of the mechanical properties of high co-solute/biopolymer systems during vitrification. The index is based on the combined framework of Williams-Landel-Ferry equation with the free volume theory and is called the 'rheological glass transition temperature, T(g)' thus differentiating it from the empirical calorimetric T(g) used in thermal analysis. The rheological T(g) is located at the conjunction of two distinct molecular processes, namely: free-volume effects in the glass transition region and the predictions of the reaction-rate theory in the glassy state. The method of reduced variables was used to shift the mechanical spectra of shear moduli to composite curves. The temperature dependence of shift factors for all materials was identical provided that they were normalised at suitably different reference temperatures, which reflect iso-free-volume states. The treatment makes free volume the overriding parameter governing the mechanical relaxation times during vitrification of high co-solute/biopolymer systems regardless of physicochemical characteristics. We believe that potential applications resulting from this fundamental work are numerous for the food and pharmaceutical industries.
The purpose of our study was to examine the extent of patient-independent intrinsic error associated with multiple, repeat remounting of the Laitinen Stereoadapter. The Laitinen frame was repeatedly mounted on a solid water phantom and imaged using computed tomography (CT). The phantom contained five targets located in the center, anterior, right, left, and posterior orientations. The images were processed, fused, and analyzed on the Pinnacle 3-D treatment planning system. The coordinate values (in the x, y, and z directions) for each target were determined for each mounting, and an absolute mean deviation was calculated for 11 repetitions. The mean deviation in the x, y, and z direction for the central and right target, and in the x and y direction for the posterior and anterior target was less than 2.0 mm. However, the mean error in the z direction of the anterior and posterior targets was 1.79 +/- 1.02 mm and 2.20 +/- 1.32 mm, respectively. Rotational misalignment during repeat frame fixation contributed to the observed deviations and in particular affected the antero-posterior plane. With the exception of two occasions where an obvious mounting error occurred, a significant portion of error from remounting the Laitinen Stereoadapter is associated with the operator and the imaging process. The observation of an angular displacement around the axis through the earplugs suggests that a certain degree of rotational misalignment in daily remounting is possible. Targets in the antero-posterior plane are most susceptible to localization error as a consequence of rotational misalignment. In summary, the overall error is within the limits of current imaging technology but not within submillimeter accuracy. Clinical application should take these errors into consideration when designing field margins.
The total force between two like charged surfaces is investigated as a function of counterion concentration in aqueous solution and surfaces distance of separation. A smooth and a discrete density of surface charge sigma(s) lead to differences in the force distance curve at high sigma(s), which are negligible for low surface charge. The total force per unit area with divalent counterions is an oscillating function of sigma(s). At fixed surfaces separation and region of attraction (increasing sigma(s)), there is a variation in its strength that results from a competition between the ideal kinetic and ion-ion correlation force components as predicted from the anisotropic hypernetted chain approximation.