PubMed · 3713287
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N D Donaldson. 1986. Passive signalling via inductive coupling.. https://doi.org/10.1007/bf02443943
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Four series of tetradentate tripodal ligands containing pyridyl, 2-imidazolyl, 4-imidazolyl, amino, and/or carboxylic groups were synthesized as hydrolytic zinc enzyme models in order to elucidate the effect of various coordination environments on zinc binding and the acidity of zinc-bound water. In aqueous solution, ligands with same charges showed a good correlation between zinc binding (log K(ZnL)) and zinc-bound water acidity (pK(a) of LZnOH(2)); the stronger the zinc binding, the higher the pK(a). The zinc-bound water acidity decreased as pyridyl groups were replaced by carboxylate groups. However, exchanging amino groups for carboxylate groups gave no change in zinc-bound water acidity regardless of the charge of the atoms in the inner coordination sphere of the metal ion. The results are consistent with the conventional notion that negatively charged carboxylate groups inherently increase zinc binding and result in decreasing zinc-bound water acidity, but also suggest that environmental effects may modulate or dominate control of acidity.
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Evaluation of the pleasantness of odours is an important function of the olfactory system. Electrodermal recordings monitor activity in the autonomic nervous system and it has been hypothesized that such measurements could be especially valuable for investigations of affective processes in the olfactory system. In this study we measured changes in skin conductance on both hands while subjects were exposed birhinally to two pleasant and two unpleasant odours. All odours were iso-intense and non-trigeminal. We wanted to test the hypothesis that skin conductance is contra laterally governed. Furthermore, we tested the hypothesis that unpleasant odours produce larger skin conductance responses than pleasant odours. Our results indicate that there are differential skin conductance responses to different odours, but we did not find that unpleasant odours in general produce larger skin conduction responses than pleasant odours. Neither did we find support for the hypothesis that skin conduction is contralaterally governed. Rather, our data are consistent with the existence of an ipsilateral system for the control of emotional responses.