Search PubMedSearch

PubMed · 2137395

Patch testing with cement containing iron sulfate.

Abstract

Addition of iron sulfate to cement means transformation of water-soluble hexavalent chromium into nonwater-soluble trivalent chromium. This has been the basis for preventive measures concerning sensitization to hexavalent chromium (chromate) in cement. For some years, iron sulfate has been added to cement manufactured in the Scandinavian countries. In the present in vivo study, cements with and without iron sulfate were compared concerning their capacity to elicit allergic patch-test reactions in eight chromate-hypersensitive individuals. No patch-test reactions were obtained from a water extract of cement with iron sulfate when appropriately buffered.

Explore related subjects

Keep this discovery

Explore connections, maps & timelines

BibTeXRIS

M Bruze, S Fregert, B Gruvberger. 1990. Patch testing with cement containing iron sulfate.. https://pubmed.ncbi.nlm.nih.gov/2137395/

Cite the original work for its findings. Save a collection to share your selection of sources.

KEEP EXPLORING

Related citations

Study of chromium and nickel content in white asparagus (Asparagus officinalis, L.).

The modifications in the chromium (Cr) and nickel (Ni) content and the distribution of these trace elements in white asparagus spears (Asparagus officinalis, L.) were investigated. Samples were taken of two varieties of white asparagus, Desto and Ciprés, and grouped in function of their thickness in spears of < 11 mm and of > 14 mm. All the asparagus samples were cut in lengths of 20 cm and divided into 10 portions of 2 cm each. The determinations of chromium and nickel were carried out by atomic absorption spectrophotometry with air-acetylene flame. The mean concentrations were 0.675 +/- 0.19 and 5.578 +/- 1.39 mg/kg dry weight for chromium and nickel, respectively. By means of three-factor analyses of variance (varieties, thickness and portions), statistically significant differences were determined between the concentrations of chromium and nickel and each one of the sources of variation established. The chromium content showed a variable distribution throughout the white asparagus portions as a result of the notable differences between varieties and thickness. In the case of nickel, its levels underwent a generalized decrease as the spear portions were further and further away from the apical area or tip of the white asparagus.

Chromium

Occurrences, uses, and properties of chromium.

Chromium is the 21st most abundant element in the Earth's crust with a mean concentration in United States soils of about 40 mg/kg. Although it exists in several oxidation states, the zero, trivalent, and hexavalent states are the most important in commercial products and the environment. Nearly all naturally occurring chromium is in the trivalent state, usually in combination with iron or other metal oxides. Although only about 15% of the chromium mined is used in the manufacture of chemicals, most applications of chromium utilize the chemistry of chromium. For instance, the "stainless" nature of stainless steel is due to the chemical properties of the chromium oxides which form on the surface of the alloy. Similarly, the protective properties of chrome plating of metals, chromated copper arsenate (CCA) treatment of wood, and chrome tanning of leather are all dependent on chromium chemistry. The key to these uses is that under typical environmental and biological conditions of pH and oxidation-reduction potential, the most stable form of chromium is the trivalent oxide. This form has very low solubility and low reactivity resulting in low mobility in the environment and low toxicity in living organisms. In this paper the chemical properties of chromium are discussed for the major commercial products in the context of the Eh-pH diagram for chromium.

Chromium

Chromium as an essential nutrient for humans.

Chromium is an essential nutrient required for sugar and fat metabolism. Normal dietary intake of Cr for humans is suboptimal. The estimated safe and adequate daily dietary intake for Cr is 50 to 200 microg. However, most diets contain less than 60% of the minimum suggested intake of 50 microg. Insufficient dietary intake of Cr leads to signs and symptoms that are similar to those observed for diabetes and cardiovascular diseases. Supplemental Cr given to people with impaired glucose tolerance or diabetes leads to improved blood glucose, insulin, and lipid variables. Chromium has also been shown to improve lean body mass in humans and swine. Response to Cr is dependent upon form and amount of supplemental Cr. Chromium is a nutrient; therefore, it will only be of benefit to those who are marginally or overtly Cr deficient. Trivalent Cr has a very large safety range and there have been no documented signs of Cr toxicity in any of the nutritional studies at levels up to 1 mg per day.

Chromium