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S Sano

Publications and source records attributed to S Sano.

At least 343 records · Page 19Linked to original sources

The chemical structure of pemptoporphyrin.

1. Pemptoporphyrin dimethyl ester was further purified on an alumina column and then crystallized from chloroform and methanol with melting point 215-218 degrees . The absorption spectra in the visible and ultraviolet with molar extinction coefficients are presented. 2. The nuclear-magnetic-resonance spectrum of pemptoporphyrin dimethyl ester in deuterochloroform solution is reported, together with those of several other porphyrins. 3. One vinyl and one hydryl group were found at positions 2 and 4 (or 4 and 2) in the molecule. The structure of pemptoporphyrin is 2(4)-hydryl-1,3,5,8-tetramethyl-4(2)-vinyldeuteroporphyrin IX. 4. Reduction of pemptoporphyrin dimethyl ester with resorcinol gave deuteroporphyrin IX dimethyl ester.

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