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Results for “Phosphorous Acids”

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At least 19 recordsLinked to original sources
PubMed1983

Ambient air quality in the vicinity of a works manufacturing sulphuric acid, phosphoric acid and sodium tripolyphosphate.

Airborne concentrations of sulphur dioxide, nitrogen dioxide, sulphate and fluorides have been determined in the vicinity of a large industrial producer of sulphuric acid, phosphoric acid and sodium tripolyphosphate. The results indicate that the Works does not contribute significantly to 24-h average levels of nitrogen dioxide or sulphuric acid, but does cause an elevation in local sulphur dioxide and fluoride concentrations. Measurements of phosphate deposition demonstrate that the Works is a source of both condensed phosphate and orthophosphate emissions. It is concluded that ambient air pollution concentrations are well within accepted standards for human health, but that alleged damage to garden plants may be due to airborne fluorides and/or phosphate deposition.

Air↗
PubMed2005

The effects of boric acid and phosphoric acid on the compressive strength of glass-ionomer cements.

OBJECTIVES: Both boric acid (H3BO3) and phosphoric acid (H3PO4) are components of dental cements, commonly incorporated into glass (as ingredients in the melt) and occasionally added to the powder or liquid components. This study investigated the effect of boric acid addition to an experimental glass-ionomer powder and the effect of phosphoric acid addition to a glass-ionomer liquid on the 24-h compressive strength. METHODS: Boric acid powder was added in various concentrations to an experimental glass-ionomer powder and, separately, phosphoric acid was added to an experimental glass-ionomer liquid. Powders and liquids were dosed into capsules at various powder:liquid ratios and cements thus formed were assessed for 24-h compressive strength. RESULTS: Incorporation of boric acid in glass-ionomer powder resulted in a pronounced decrease (p < 0.05 at 1% boric acid) in compressive strength. Addition of phosphoric acid produced initially stronger cements (up to 13% increase at 1% phosphoric acid) before also declining. SIGNIFICANCE: The incorporation of less than 2% w/w phosphoric acid in glass-ionomer liquids may improve cement strengths without compromising clinical usefulness. The incorporation of boric acid in glass-ionomer cements is contraindicated.

Boric Acids↗
PubMed1990

Ceramic bracket bonding: a comparison of bond strength with polyacrylic acid and phosphoric acid enamel conditioning.

The purpose of this study was to compare in vitro shear bond strength with three different enamel surface preparations: (1) 37% phosphoric acid etch, (2) sulfated polyacrylic acid etch with removal of crystals by vigorous rinsing and (3) polyacrylic acid etch with crystal growth. Forty extracted human premolar teeth were divided into four groups of ten. Ceramic brackets were bonded to teeth in each of three groups. The fourth group used was bonded with metal brackets and a phosphoric acid enamel preparation. The same lightly filled resin cement was used for all groups. A shearing force was applied to the teeth. The results demonstrated that the shear force needed to debond with ceramic brackets was 21% greater than the shear force with metal brackets. The polyacrylic acid crystal growth group had shear bond strength values approximately one half as great as the phosphoric acid etch group when ceramic brackets were used. Bond failures in the phosphoric acid etch group were at the bracket/resin interface with the bulk of the resin remaining on the tooth compared with the polyacrylic acid crystal growth group in which the bond failure was at the enamel resin interface. Enamel fractures were not found when healthy nonrestored teeth were subjected to the shearing force. In a preliminary test using phosphoric acid etch and teeth with compromised enamel (large restorations involving three or more surfaces), half of the teeth fractured during debonding. The study demonstrated that a polyacrylic acid conditioning of the enamel surface produces different retentive surfaces, depending on the presence or absence of crystal growth.(ABSTRACT TRUNCATED AT 250 WORDS)

Acid Etching, Dental↗
PubMed2003

Determination of chloride and sulfate in semiconductor-grade etchants comprised of acetic acid, nitric acid and phosphoric acid.

The variable-capacity Dionex Cryptand A1 column was used for the determination of low-ppm levels of chloride and sulfate in etchants comprised of acetic acid, nitric acid and phosphoric acid. All possible ratios of the three acids could be analyzed for chloride and sulfate, if the samples were first diluted 1:100. However, a suitable eluent program was found to be needed for each mixture. A proprietary formulation was chosen to undergo this suitability determination. The resulting gradient was 10 mM KOH with a step to 30 mM NaOH at 15 min, flow-rate=0.5 ml/min; column temperature=29 degrees C; sample loop=7.5 microl. Under these conditions, a low-ppm calibration study (using the proprietary mix as the matrix) was performed and the associated prediction intervals were determined. At 50 ppm (in the original etchant), the +/- prediction interval was +/- 7 ppm for chloride and +/- 20 ppm for sulfate, both at the 95% confidence level. This step gradient was found to be a good starting place for separating the five components in all other ratios of these three acids.

Acetic Acid↗
PubMedDate not supplied

Study of vibrational spectra of polyaniline doped with sulfuric acid and phosphoric acid.

Vibrational spectra of insulator emeraldine base (EB) form of polyaniline and electrical conductive sulfuric acid- and phosphoric acid-doped emeraldine salts (ES) were studied in the region of 4000-400 cm(-1) at ambient temperature by Fourier transform infrared spectroscopy. Infrared transmittance spectra of EB and ES were investigated to understand the bonding behavior of different organic and inorganic groups present in the polymeric chains and their structural variations on protonation by sulfate or phosphate ion inclusion in the polymer salt network. These studies revealed the para-coupling of deformed disubstituted benzenoid (B) and quinoid (Q) rings with ends capped predominantly by (B4Q1) units. The deformation of B and Q rings was confirmed by the appearance of many weak bands, very weak bands, and satellite structures in strong transmittance peaks of polymeric chain-constituting groups. Protonation takes place at the nitrogen sites of Q rings and forms semiquinone radical ions in ES. The vibrational bands pertaining to B rings, Q rings, B4Q1 units, semiquinone segment, sulfate ions, and phosphate ions were observed and assigned from these measurements. The shift in peak position of some bands with gain or loss in intensity and appearance of some new bands were observed in sulfuric acid- and phosphoric acid-doped ES spectra. These variations are attributed to the formation of new structural groups in ES on protonation and a change in crystalline field by sulfate and phosphate ion doping for crosslinking the polymeric chains.

Aniline Compounds↗
PubMed2002

Bone reactions to oxidized titanium implants with electrochemical anion sulphuric acid and phosphoric acid incorporation.

BACKGROUND: The importance of the surface properties of implants for a successful osseointegration has been emphasized. It is generally known that bone response to implant surfaces is considerably related to the various surface properties. PURPOSE: The purpose of this study was to investigate bone tissue reactions to multifactorial biocompatibility of the surface oxide of electrochemically oxidized titanium implants. The ultimate objective was to improve surface quality, resulting in enhancement of clinical outcomes of osseointegrated implants. MATERIALS AND METHODS: Three different surface types of commercially pure titanium (c.p. Ti) implants were prepared. Turned implants were used for controls and test implants were prepared by the micro arc oxidation (MAO) method, either in sulphuric acid (S implants) or in phosphoric acid (P implants). Implants were inserted in the femur and tibia of 10 mature New Zealand White rabbits. The bone response was evaluated by biomechanical tests, histology, and histomorphometry. The follow-up time was 6 weeks. RESULTS: The mean peak values of the removal torque showed significant differences between control and test S implants (p =.022) but showed no significant differences between control and test P implants (p =.195) or between test S and test P implants (p =.457). In addition, the histomorphometric comparisons of the bone-to-metal contact around entire implants demonstrated 186% increase in S implants (p =.028) and 232% increase in P implants (p =.028) compared with the paired control groups. Quantification of the bone area in the threads did not show any significant differences. CONCLUSIONS: The present results suggest that the primary mode of action in strong bone response to S implants is mechanical interlocking, and to P implants, it is biochemical interaction. It is possible that the phosphate groups in the titanium oxide of P implants provide potential chemical bonding sites for calcium ions and hydroxyapatite of the bone matrix during biologic mineralization. key words: bone responses, histomorphometry, oxidized implants, removal torque test, surface oxide properties

Animals↗
PubMed1989

Formic acid as a milder alternative to trifluoroacetic acid and phosphoric acid in two-dimensional peptide mapping.

In reversed-phase chromatography of peptides, formic acid has been shown to successfully replace the stronger traditional trifluoroacetic and phosphoric acids. Detection of non-aromatic peptide at lower wavelength is not impaired and being volatile the acid is easily removed, enabling further studies of the peptides. Also in ion-exchange chromatography (the first step of a two-dimensional approach) formic acid works well with a sulphonic acid ion-exchange resin.

Animals↗
PubMed1986

Direct bonding comparing a polyacrylic acid and a phosphoric acid technique.

The purpose of this study was to compare in vitro a polyacrylic acid technique (crystal bonding) with a conventional phosphoric acid-etch technique for the preparation of teeth for bonding. The potential value of the polyacrylic acid technique was evaluated for bond strength, enamel loss, cleanup, and fracture location--with and without the use of a sealant. Ninety-six premolars were evenly divided into two groups. Group A was preconditioned with polyacrylic acid and group B with phosphoric acid. Half of each group was treated with a sealant before direct bonding of orthodontic brackets. Sealant was not used on the other half of each group and brackets were bonded directly to the conditioned labial surfaces with a composite cement. Bonding and rebonding shear strength tests were carried out for both groups. Results indicated that shear bond strength values for the polyacrylic acid group were approximately one third those of the phosphoric acid group using a composite cement as the adhesive. Enamel loss was measured on the lingual surfaces of 30 of the 96 premolars. The lingual surfaces were conditioned with polyacrylic acid. Following debonding and cleanup procedures, the polyacrylic acid treated surface was left slightly pitted with no resin tags remaining. Cleanup procedures required only a rubber-cup silicate prophylaxis. The total enamel loss was minimal (4.5 micron), thus preserving most of the outermost fluoride-rich layer of enamel.

Acrylic Resins↗