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At least 19 recordsLinked to original sources
PubMed1995

Friction analysis of kinetic schemes: the friction coefficient.

Friction analysis is proposed as the application of general control analysis to single enzymes to describe the control of elementary kinetic steps on the overall catalytic rate. For each transition, a friction coefficient is defined that measures the sensitivity of the turnover rate to the free energy of the transition state complex of the transition. The latter is captured in a single property of the transition, termed friction, as the geometrical mean of the inverse of the forward and backward rate constants. By definition, the friction coefficient measures the relative change in the turnover rate in response to a small change in the friction. The friction coefficient is the sum of the flux control coefficients of the forward and backward rate constants from general control theory and measures the extent to which an elementary step is rate determining. Two basic rules apply to the friction coefficients: (i) the summation theorem states that summation of the friction coefficients over all the steps in a scheme results in a value of 1, and (ii) the group rule states that grouping of rate constants of similar transitions results in a friction coefficient for the group that is the sum of the friction coefficients of the individual steps in the group. The friction coefficients are derived for a number a kinetic schemes taking the rate equations as the starting point and both rules are demonstrated. In fully coupled systems the friction coefficients of individual steps lie between 0 and 1. In partially uncoupled systems the summation theorem applies to all the rates in the system, however, the summation of subsets of friction coefficients may exceed the value of one, implying negative values for other steps in the scheme. The values of individual friction coefficients lie between -1 and 1. The friction coefficient is redefined in a numerical treatment of the steady state of more complex enzymatic schemes.

Enzymes↗
PubMed1991

Friction ... Friction resistance between edgewise brackets and archwires.

This study quantified the dynamic frictional force encountered when TMA, Orthonol and multistranded stainless steel archwires were pulled a distance of 2mm through ceramic and stainless steel brackets. The current literature is inadequate and incomplete, for example, no data was found on rectangular multistranded archwires. The following factors were investigated: archwire material, archwire size, archwire-to-bracket angulation, bracket material, archwire and bracket slot surface roughness and lubrication in the form of artificial saliva. A total of 156 different combinations were investigated. A universal testing machine was used to pull the ligated archwires through the brackets, and record the friction. A four way analysis of variance with one nesting (archwire size) was carried out on 1,560 measurements to assess the results. All factors and interactions tested were significant in determining friction. Friction was found to increase with: archwire angulation and archwire size (exceptions were seen in some TMA archwires). Friction decreased with lubrication. There was a definite relationship between friction and archwire and bracket material. There was no definite relationship between archwire surface roughness and friction. Highest friction was observed with ceramic bracket and TMA archwire. The range of friction was 1.02 to 9.95 Newtons. The magnitude of the friction recorded is substantially larger than the forces applied in orthodontic movement clinically. It is proposed that the values recorded should be utilised as a means of comparing the effects of different factors, rather than for the quantification of friction in vivo.

Analysis of Variance↗
PubMed1997

The normal stress effect and equilibrium friction coefficient of articular cartilage under steady frictional shear.

During creep or stress relaxation, articular cartilage exhibits a time-dependent friction coefficient which has been shown to reach an equilibrium value, mu eq, as the tissue deformation equilibrates. This study investigates the frictional properties of articular cartilage explants under steady frictional shear and constant compressive strain after the tissue reaches stress-relaxation equilibrium. The two parameters measured are the normal force and frictional torque, from which the friction coefficient was then calculated. It is shown in this experimental study that: (1) Under a prescribed infinitesimal compressive strain, cartilage supports higher compressive normal stress under steady shear than it does in the absence of frictional shear. Furthermore, the normal stress increases with increasing sliding velocity, resulting in a velocity-dependent value of mu eq. The observed normal stress effectively increases the compressive stiffness of cartilage by a factor up to 3.1. (2) Under a prescribed steady frictional shear both the normal stress and frictional shear stress increase, though not proportionally, with increasing compressive strain, producing a decreasing friction coefficient. (3) This velocity-dependent normal stress effect is also shown to result, at least partly, from intrinsic properties of cartilage. The normal stress effect has not been previously reported for articular cartilage, and represents an intriguing mechanical response not commonly encountered in solids, though common in non-Newtonian fluids.

Animals↗
PubMed1988

Wear, creep, and frictional heating of femoral implant articulating surfaces and the effect on long-term performance--Part II, Friction, heating, and torque.

In Part I, (J.A. Davidson and G. Schwartz, "Wear, creep, and frictional heating of femoral implant articulating surfaces and the effect on long-term performance--Part I, A review," J. Biomed. Mater. Res., 21, 000-000 (1987) it was shown that lubrication of the artificial hip joint was complex and that long-term performance is governed by the combined wear, creep, and to a lesser extent, oxidation degradation of the articulating materials. Importantly, it was shown that a tendency for heating exists during articulation in the hip joint and that elevated temperatures can increase the wear, creep, and oxidation degradation rate of UHMWPE. The present study was performed to examine closely the propensity to generate heat during articulation in a hip joint simulator. The systems investigated were polished Co-Cr-Mo alloy articulating against UHMWPE, polished alumina ceramic against UHMWPE, and polished alumina against itself. Frictional torque was also evaluated for each system at various levels of applied loads. A walking load history was used in both the frictional heating and torque tests. The majority of tests were performed with 5 mL of water lubricant. However, the effect of various concentrations of hyaluronic acid was also evaluated. Results showed frictional heating to occur in all three systems, reaching an equilibrium after roughly 30 min articulation time. Ceramic systems showed reduced levels of heating compared to the cobalt alloy-UHMWPE system. The level of frictional torque for each system ranked similar to their respective tendencies to generate heat. Hyaluronic acid had little effect, while dry conditions and the presence of small quantities of bone cement powder in water lubricant significantly increased frictional torque.

Hip Prosthesis↗
PubMed1979

[Importance of the friction between plate and bone in the anchoring of plates for osteosynthesis. Determination of the coefficient of metal-bone friction in animal in vivo].

In mechanical devices in general the friction plays an important role in force transmission. To find out about the magnitude of frictional forces between internal fixation plate and bone in vivo, simultaneous strain recording in plated bone and instrumented plate were performed. After 3 weeks of implantation the torque applied to a single plate-screw was set to definite levels. Thus it could be determined at what level of screw compression and at what tangential load of the related surface bone-plate, gliding occurred. The coefficient of friction was found to be 0.2 +/- 0.09 (x +/- Sx). It can be concluded that in vivo friction produced at the plate-bone contact surface is able to guarantee stability of fixation.

Animals↗
PubMed2000

Surface and friction characterization by thermoelectric measurements during ultrasonic friction processes

Even though friction is one of the oldest problems in physics many aspects of friction processes are not clear today. We present an experimental setup, which permits the study of tribological systems by measuring the dissipated heat at the interface of two surfaces during a friction process with a time resolution of 1 ms. The apparatus is based on a standard ultrasonic wire-bond machine used in semiconductor industries to connect the internal semiconductor die to the external leads, but the standard bond wire is replaced by a thermocouple. To demonstrate the ability of the apparatus it will be shown that bond substrates used in semiconductor industries can be unequivocally characterized.

Journal Article↗
PubMed1989

[Study on frictional characteristics of KB horizontal brackets. A comparative study of kinetic frictional forces to be caused between various kinds of brackets and wires].

KB horizontal brackets were designed to tip no more than 6 degrees at the maximum. This tipping amount is based on the idea of reducing friction between a wire and brackets to allow the effective tooth movement of the Begg technique even with horizontally long brackets, and does not originate in the concept of carrying out tipping movement. Thereon, experimental measurements by use of Rheometer were conducted to review for comparison of the kinetic frictional forces caused between various wires and the following four types of brackets; KB horizontal brackets, Tip edge brackets, Straight edge brackets and Begg brackets. 1. In case of utilizing ribbon arch wires and rectangular wires, no significant difference was acknowledged among Tip edge, KB horizontal and Straight edge brackets. 2. There proved to be a reduction in the kinetic frictional forces by incorporating tip into the edgewise slots, when using smaller dimensions of the wires which call for the effective tooth movement, however, Begg brackets (in conjunction with Ordinary T-pins and/or Safety T-pins) showed the small value which is far less than that of the three kinds of brackets.

Orthodontic Appliances↗
PubMed1998

Frictional forces related to self-ligating brackets.

Orthodontic tooth movement can be regarded as teeth sliding on a wire like pearls on a string, the force being supplied by springs or elastics. The movement implies friction between wire and bracket, taking up part of the force and leaving an uncontrolled amount to act on the teeth. The friction is likely to depend on bracket construction and wire material. Therefore, in this investigation the friction of self-ligating brackets and beta-titanium wires was evaluated, as opposed to more conventional configurations. Carried by low-friction linear ball bearings, a bracket was made to slide along an out-stretched archwire with minimal (and known) basic friction, either parallel or at an angle to the wire. Two self-ligating brackets were used in their closed position without any normal force. Friction was tested against four wires: stainless steel and beta-titanium, both in round and rectangular cross-sections. The force used to overcome friction and to move the bracket was measured on a testing machine at 10 mm/min, and the basic friction was subtracted. The results show that round wires had a lower friction than rectangular wires, the beta-titanium wires had a markedly higher friction than stainless steel wires, and friction increased with angulation for all bracket/wire combinations. The self-ligating brackets had a markedly lower friction than conventional brackets at all angulations, and self-ligating brackets, closed by the capping of a conventional design, exhibited a significantly lower friction than self-ligating brackets closed by a spring. The selection of bracket design, wire material, and wire cross-section significantly influences the forces acting in a continuous arch system.

Analog-Digital Conversion↗
PubMed1996

Friction, not texture, dictates grip forces used during object manipulation.

1. Three men and seven women, 25-40 yr of age, were asked to use the thumb and index fingers to grasp, lift, and hold the armature of a linear motor generating a 2.0-N opposing force (simulating an object weighing approximately 200 g) for 2 s. The surface in contact with the fingers was composed of smooth or polyamide plastic etched with 1.0-mm high Braille beads separated at 2.0- or 3.0-mm intervals measured from apex to apex. The surfaces were left either untreated or coated with talc, water, or sucrose films designed to change the coefficient of friction with the skin. Talc reduced the coefficient of friction, whereas water and sucrose both increased the friction against the skin. In all, 12 surface conditions were used to evaluate the effects of texture and friction on the grip force during lifting and holding. 2. For all subjects the inverse coefficient of friction was associated with proportionately scaled increases in grip force, regardless of surface texture. The peak lifting force as well as the static force used to hold the object stationary were significantly correlated with the inverse of the coefficient of friction. When coatings were applied to dissimilar surface textures to produce similar coefficients of friction, the grip force profiles were nearly identical. When strong adhesives increased the friction of the smooth surface compared with textured surfaces, grip forces decreased as friction increased. That is, although the untreated smooth surface had less friction than either of the two textured surfaces, the addition of sucrose increased the smooth surface friction to a higher level than either of the similarly treated textured surfaces. As a result, the effect of surface friction could be dissociated from the effect of either surface texture or coating. Friction appears to be a more important factor in determining the grip force than either texture or surface films at least for the range of textures and coatings examined in this study.

Adhesiveness↗
PubMed1999

The influence of continuous sliding and subsequent surface wear on the friction of articular cartilage.

Reciprocating motion friction tests were conducted upon cartilage-on-metal contacts while subjected to a constant load. Initial friction coefficients were compared with repeat friction coefficients following a sufficient load removal period. The repeat friction coefficients were marginally higher than the initial values and both were primarily dependent on the loading time. It was concluded that while a wear component had been identified, which modestly increased friction coefficients, the overriding parameter influencing friction was loading time. The authors postulate that fluid phase load carriage (being dependent on loading time) within the articular cartilage is largely responsible for low friction coefficients in the mixed and boundary lubrication regimes. This mechanism has been referred to as biphasic lubrication. Both synovial fluid and Ringer's solution were used as lubricants. Over the assessed 120 min loading time friction coefficients rose from 0.005 (for both lubricants) after 5 s to 0.50 and 0.57 for synovial fluid and Ringer's solution respectively. Synovial fluid was found to significantly reduce friction coefficients compared to Ringer's solution over broad ranges of the assessed loading times (p < 0.05). Stylus and non-contacting laser profilometry were successfully employed to provide reliable, quantitative and accurate measures of surface roughness. Laser profilometry before and after a continuous sliding friction test revealed a significant increase in surface roughness from Ra = 0.8 (+/- 0.2) micron to Ra = 2.1 (+/- 0.2) microns, (p < 0.0005); confirming that surface wear was occurring. Scanning electron microscopy (SEM) revealed the typical highly orientated collagen fibres of the superficial tangential zone. Environmental SEM (ESEM) of fully hydrated cartilage specimens provided largely featureless images of the surface which suggested that sample preparation for conventional SEM was detrimental to the authenticity of the cartilage surface appearance using SEM. Two distinct acellular, non-collagenous surface layers were identified using ESEM and transmission electron microscopy (TEM); respectively referred to as the boundary layer and surface lamina. The phospholipid/glycoprotein based boundary layer will provide boundary lubrication during intimate contact of opposing cartilage surfaces. The surface lamina, being a continuum of the proteoglycan interfibrillar matrix, is present to prevent fibrillation of the underlying collagen fibres. Both layers may contribute to the time dependent frictional response of articular cartilage. Although laser profilometry did reveal surface wear which was consistent with a small increase in friction, the primary variable controlling the friction coefficient was the period of loading.

Animals↗