[Fresh water baths, sea water baths and thermal baths].
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By using the Boltzmann approach, we study the steady-state dynamics of a granular capped rectangle placed in a two-dimensional bath of thermalized hard disks. Hard core collisions are assumed elastic between disks and inelastic between the capped rectangle and the disks, with a normal coefficient of restitution alpha < 1. Assuming a Gaussian ansatz for the probability distribution functions, we obtain analytical expressions for the granular temperatures. We show the absence of equipartition and investigate both the role of the anisotropy of the capped rectangle and of the relative ratio of the bath particles to the linear sizes of the capped rectangle. In addition, we investigate a model of a capped rectangle with two normal coefficients of restitution for collisions along the straight and curved surfaces of the capped rectangle. In this case one observes equipartition for a nontrivial ratio of the normal coefficient of restitutions.
Significant exposure to hydrogen sulfide may occur in workers at sulphureous thermal baths. Work-related exposure to hydrogen sulfide may be shown by measuring sulfhemoglobin (S-Hb) blood levels. In this study we measured S-Hb blood levels in two groups of workers at two different thermal baths and compared these with hydrogen sulfide concentrations in the air of the two work environments. Our results show that blood S-Hb levels can be considered a reliable measure of individual exposure to hydrogen sulfide.
The stationary state of a quantum particle strongly coupled to a quantum thermal bath is known to be non-Gibbsian, due to entanglement with the bath. For harmonic potentials, where the system can be described by effective temperatures, thermodynamic relations are shown to take a generalized Gibbsian form that may violate the Clausius inequality. For the weakly anharmonic case, a Fokker-Planck-type description is constructed. It is shown that then work can be extracted from the bath by cyclic variation of a parameter. These apparent violations of the second law are the consequence of quantum coherence in the presence of the slightly off-equilibrium nature of the bath.
We develop a unified theory of dynamically suppressed decay and decoherence by external fields in qubits coupled to arbitrary thermal baths and dephasing sources. This general theory does not invoke the rotating-wave approximation, which fails for ultrafast field-induced modulations of qubit-bath coupling. Considerations for optimizing the dynamical suppression are outlined.
Classical heat engines produce work by operating between a high temperature energy source and a low temperature entropy sink. The present quantum heat engine has no cooler reservoir acting as a sink of entropy but has instead an internal reservoir of negentropy which allows extraction of work from one thermal bath. The process is attended by constantly increasing entropy and does not violate the second law of thermodynamics.
The present study investigates the short- and long-term effects of radon ((222)Rn) released from water on the progeny exposure in a thermal spa. For the purposes of this work, the Polichnitos spa was used as a case study. The bathroom was supplied with water containing 110-210 kBq m(-3) of (222)Rn. The (222)Rn concentration in air and the short-lived (222)Rn progenies in attached and unattached form were monitored into the bathroom and the surrounding premises. The equilibrium factor (F-factor) and the unattached fraction were estimated. The results of this study show that water flow during bath filling is by far the dominant mechanism by which (222)Rn is released in the air of the bathroom. The progeny exposure was correlated linearly with the (222)Rn concentration in the entering water. The annual effective dose received by a worker was found to be below the lower limit value of 3 mSv recommended by ICRP 65. The dose limit was exceeded only for water containing more than 300 kBq m(-3).
A model for electron transfer in donor-bridge-acceptor complexes with electronic coupling to nuclear bridge modes is studied using the Redfield formulation. We demonstrate that the transport mechanism through the molecular bridge is controlled by the location of the electronic-nuclear coupling term along the bridge. As the electronic-nuclear coupling term is shifted from the donor/acceptor-bridge contact sites into the bridge, the mechanism changes from kinetic transport (incoherent, thermally activated, and bridge-length independent) to coherent tunneling oscillations. This study joins earlier works aiming to explore the factors which control the mechanism of electronic transport through molecular bridges and molecular wires.
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