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PubMed2005

Oxidative and tribological properties of amorphous and quasicrystalline approximant Al-Cu-Fe thin films.

The origins of the tribological properties and corrosion resistance of amorphous and quasicrystalline approximant alloys have been studied by comparing their properties in thin Al-Cu-Fe alloy films with compositions lying near the quasicrystalline region of the ternary compositional phase diagram. Six sputtered thin films of an Al-Cu-Fe alloy were studied using X-ray diffraction, X-ray photoemission spectroscopy (XPS), and an in situ ultrahigh vacuum (UHV) tribometer. The films were annealed in UHV to induce the formation of orthorhombic, rhombohedral, and amorphous bulk structures. The properties of these thin films were then determined in the same UHV apparatus without exposing the films to air. The rates of surface oxidation by H2O and O2 were measured using XPS. Although the oxidation rates and oxide thicknesses were dependent on the oxidant, they were not sensitive to the structures of the films. Friction was measured between identical samples in sliding contact. The friction coefficients (micros = 0.36 +/- 0.11 to 0.56 +/- 0.08) were comparable to those observed in other experiments using quasicrystals and approximants in UHV; however, there was no strong correlation between the friction coefficients and either the film structure or the degree of surface oxidation. These results suggest that the tribological and corrosion resistance properties of these quasicrystalline approximant alloys are not directly connected to crystalline structure.

Journal Article↗
PubMed2005

Surfactant boundary lubricant film modified by an amphiphilic diblock copolymer.

The effect of the uptake of a low-molecular-weight amphiphilic diblock copolymer on the morphology of didodecyldimethylammonium bromide (DDAB) adsorbed layers on mica, the interactions between two coated surfaces, and the frictional properties of the boundary film have been studied using an atomic force microscope and a dynamic surface forces apparatus nanotribometer. When DDAB-coated surfaces in aqueous solution were compressed, hemifusion or removal of the adsorbed surfactant bilayers could not be induced, and no frictional force could be measured between the surfaces, which display superior lateral cohesion and lubricant properties. Coadsorbing octadecyl end modified poly(ethylene oxide) chains at low density facilitates hemifusion, generating significant shear stress and leading to stick-slip instabilities. The mixed films regain their lateral cohesion at higher adsorbed copolymer densities, but an extra short-range attraction brings the adsorbed layers into adhesive contact without causing bilayer hemifusion. Here, noticeable frictional forces are also measured.

Journal Article↗
PubMed2004

Surface self-assembly of fluorosurfactants during film formation of MMA/nBA colloidal dispersions.

These studies focus on the behavior of fluorosurfactants (FS) containing hydrophobic and ionic entities in the presence of methyl methacrylate/n-butyl acrylate (MMA/nBA) colloidal dispersions stabilized by sodium dodecyl sulfate (SDS). The presence of FS significantly not only alters the mobility of SDS in MMA/nBA films, but their hydrophobic and ionic nature results in self-assembly near the film-air (F-A) interface leading to different surface morphologies. Spherical islands and rodlike morphologies are formed which diminish the kinetic coefficient of friction of films by at least 3 orders of magnitude, and the presence of dual hydrophobic tails and an anionic head appears to have the largest effect on the surface friction. Using internal reflection IR imaging, these studies show that structural and chemical features of FS are directly related to their ability to migrate to the F-A interface and self-assemble to form specific morphological features. While the anionic nature of FS allows for SDS migration to the F-A interface and the formation of stable domains across the surface, intermolecular cohesion of nonionic FS allows for the formation of rodlike structures due to inability to form mixed micelles with SDS. These studies also establish the relationship between surface morphologies, kinetic coefficient of friction, and structural features of surfactants in the complex environments.

Acrylates↗
PubMed2006

Quantitative nanotribology by AFM: a novel universal calibration platform.

The quantitative determination of friction forces by atomic force microscopy (AFM) in nanotribology requires the conversion of the output voltage signal of the sector area-sensitive photodiode to force using (a) the torsional spring constant of the cantilever and (b) the lateral sensitivity of the photodiode. Many existing methods provide calibration factors with large errors and suffer from poor reproducibility. We report on the fabrication, validation, and application of a new, universally applicable standard specimen that enables one to accurately calibrate all types of AFM cantilevers and tips for quantitative friction force measurements. The Si(100) calibration standard, which exhibits 30 and 50 mum wide notches with tilt angles theta between 20 degrees and 35 degrees with respect to the wafer surface, was fabricated by focused ion beam (FIB) milling. The quantification of friction forces obtained on this universal standard specimen using a direct method (the improved wedge calibration method, as introduced by Ogletree, Carpick, and Salmeron Rev. Sci. Instrum. 1996, 67, 3298-3306), which yields (a) and (b) simultaneously, was critically tested for various types of Si3N4 integrated cantilever-tip assemblies. The error in the calibration factors obtained was found to be ca. 5%, which is a significant improvement compared to errors of 30-50% observed for the often applied two-step calibration procedures of cantilever lateral force constant and photodiode sensitivity. As demonstrated for oxidized Si(100), thin films of poly(methyl methacrylate) (PMMA), and micropatterned self-assembled monolayers (SAMs) on gold, the calibration of various V-shaped and single beam cantilevers based on the application of the new universal standard in conjunction with the direct wedge method proposed allows one to conveniently perform quantitative nanotribological measurements for a wide range of materials and applications.

Journal Article↗
PubMed1999

Diamond-like carbon coatings for orthopaedic applications: an evaluation of tribological performance.

A detailed investigation of the tribological behaviour of vacuum arc diamond-like carbon coated Ti-6Al-4V against a medical grade ultra-high molecular weight polyethylene is conducted in this work in order to investigate the potential use of diamond-like carbon coatings for orthopaedic appplications. Lubricated and non-lubricated wear experiments are performed using a standard pin-on-disc wear tester. The coefficient of friction is monitored continuously during testing and wear rate calculations are performed using surface profilometry measurements of worn disc surfaces. Sliding wear tests show the existence of two distinct friction and wear regimes distinguished by physically different mechanisms. In the first stages of wear, adhesion and abrasion are the dominant mechanisms of wear while fatigue processes are activated later in the tests. The effects of diamond-like carbon coating structure, surface roughness and lubrication on tribological behaviour are presented. Optimal process-structure-property design for vacuum arc plasma deposition is utilized in order to obtain strong adhesion to the titanium alloy substrate. Diamond-like carbon coatings significantly improve the friction and wear performance of the orthopaedic bearing pair and show exceptional promise for biomedical applications.

Journal Article↗
PubMed2002

Corrosion and permanent fracture resistance of coated and conventional orthodontic wires.

The corrosion processes are presumed to have negative consequences on biocompatibility, aesthetic appearance and the frictional behavior between the bracket and the guiding arch during orthodontic treatment. A group of new guiding arches are the coated orthodontic wires. The present in-vitro study investigated the corrosion behavior and permanent fracture resistance of eight coated wires of different dimensions. Five superelastic nickel titanium (NiTi) wires (Titanol Low Force River Finish Gold and Gold 2: Forestadent Corp.; Titanol Superelastic tooth colored: Forestadent Corp.; Bioforce Sentalloy longuard: GAC Corp.; NiTi Imagination: GAC Corp.), two beta-titanium-wires (TMA Low Friction longuard: Ormco Corp.; TMA Low Friction longuard Purple: Ormco Corp.) and one steel wire (Stainless Steel Imagination: GAC Corp.) were selected. For comparison reasons three uncoated arch wires (Rematitan Lite Dimple: Dentaurum Corp.; Titanol Low Force River Finish: Forestadent Corp.; Bioforce Sentalloy: GAC Corp.) were included in the investigation. Surface modifications were made of teflon, polyethylene and by ion implantation. The corrosion processes have been carried out by the use of a specialized electrochemical cell. In a second experimental series the wires were exposed to mechanical stresses. Finally, all wires were examined in a scanning electron microscope. The results indicated that teflon coating prevented the corrosion of the wires. As expected, the beta-titanium wires did not corrode either. The other wires showed rupture potentials between 187 mV and 602 mV (NHE). After mechanical stress testing the wires could be subdivided into three groups. In the first group no differences could be recognized, the second group showed changes in their crystallographic structure and in the last group the teflon coating was peeled off from the surface of the wires.

Journal Article↗
PubMed1997

The optimum dose of gamma radiation-heavy doses to low wear polyethylene in total hip prostheses.

Wear volume, surface area and coefficient of friction of UHMWPE cup crosslinked with gamma radiation of 0, 50, 75, 100, 125, 150 and 200 Mrad sliding against an alumina ball were measured using a sphere-on-flat reciprocating type tribology testing machine. The effects of gamma radiation were scarcely observed in coefficient of friction. The coefficient of friction under lubricated (distilled water) and non-lubricated testing conditions was 0.08 to 0.12 and 0.20 to 0.25, respectively. The wear volume of UHMWPE with radiation of 50 Mrad, 75 to 150 Mrad, and 200 Mrad was 70 to 80%, 18 to 25%, and 12 to 15%, respectively, in comparison to non-irradiated specimens. Elongation and tensile strength of UHMWPE with radiation of 100 Mrad decreased to 6%, and 50% of that without radiation, respectively. The hardness increased with increase of the radiation dose. From several kinds of tribological findings, mechanical strength tests, and studies of long-term clinical findings, it is concluded that approximately 200 Mrad is the optimum dose of gamma radiation for clinical use in total hip prostheses.

Journal Article↗
PubMed2002

Tribological study of lubricious DLC biocompatible coatings.

DLC (diamond-like carbon) coatings have remarkable tribological properties due mainly to their good frictional behavior. These coatings can be applied in many industrial and biomedical applications, where sliding can generate wear and frictional forces on the components, such as orthopaedic metal implants. This work reports on the development and tribological characterization of functionally gradient titanium alloyed DLC coatings. A PVD-magnetron sputtering technique has been used as the deposition method. The aim of this work was to study the tribological performance of the DLC coating when metal to metal contact (cobalt chromium or titanium alloys) takes place under dry and lubricated test conditions. Prior work by the authors demonstrates that the DLC coating reduced considerably the wear of the ultra-high-molecular-weight polyethylene (UHMWPE). The DLC coating during mechanical testing exhibited a high elastic recovery (65%) compared to the values obtained from Co-Cr-Mo (15%) and Ti-6Al-4V (23%). The coating exhibited an excellent tribo-performance against the Ti-6Al-4V and Co-Cr-Mo alloys, especially under dry conditions presenting a friction value of 0.12 and almost negligible wear. This coating has passed biocompatibility tests for implant devices on tissue/bone contact according to international standards (ISO 10993).

Journal Article↗
PubMed1997

Rumination and psychological distress among bereaved partners.

Recently bereaved men who evidenced more negative ruminative thoughts in free-response interviews showed greater psychological distress on several outcome measures both 1 month and 12 months after their loss and less increase in positive morale over this 12-month period. Men who engaged in more analysis of themselves and the meaning of their loss reported greater positive morale 1 month after their loss but showed more persistent depression and absence of positive states of mind over the 12 months following their loss. Finally, men who reported more social friction also evidenced more enduring depressive symptoms over the year than did men who reported less social friction. These results are generally consistent with other studies that have shown that self-reflective, ruminative coping with negative emotions and social friction are associated with longer and more severe periods of depressed mood following stressful events.

Acquired Immunodeficiency Syndrome↗
PubMed2003

Lubrication by charged polymers.

Long-ranged forces between surfaces in a liquid control effects from colloid stability to biolubrication, and can be modified either by steric factors due to flexible polymers, or by surface charge effects. In particular, neutral polymer 'brushes' may lead to a massive reduction in sliding friction between the surfaces to which they are attached, whereas hydrated ions can act as extremely efficient lubricants between sliding charged surfaces. Here we show that brushes of charged polymers (polyelectrolytes) attached to surfaces rubbing across an aqueous medium result in superior lubrication compared to other polymeric surfactants. Effective friction coefficients with polyelectrolyte brushes in water are lower than about 0.0006-0.001 even at low sliding velocities and at pressures of up to several atmospheres (typical of those in living systems). We attribute this to the exceptional resistance to mutual interpenetration displayed by the compressed, counterion-swollen brushes, together with the fluidity of the hydration layers surrounding the charged, rubbing polymer segments. Our findings may have implications for biolubrication effects, which are important in the design of lubricated surfaces in artificial implants, and in understanding frictional processes in biological systems.

Journal Article↗
PubMed2005

The breakdown of continuum models for mechanical contacts.

Forces acting within the area of atomic contact between surfaces play a central role in friction and adhesion. Such forces are traditionally calculated using continuum contact mechanics, which is known to break down as the contact radius approaches atomic dimensions. Yet contact mechanics is being applied at ever smaller lengths, driven by interest in shrinking devices to nanometre scales, creating nanostructured materials with optimized mechanical properties, and understanding the molecular origins of macroscopic friction and adhesion. Here we use molecular simulations to test the limits of contact mechanics under ideal conditions. Our findings indicate that atomic discreteness within the bulk of the solids does not have a significant effect, but that the atomic-scale surface roughness that is always produced by discrete atoms leads to dramatic deviations from continuum theory. Contact areas and stresses may be changed by a factor of two, whereas friction and lateral contact stiffness change by an order of magnitude. These variations are likely to affect continuum predictions for many macroscopic rough surfaces, where studies show that the total contact area is broken up into many separate regions with very small mean radius.

Journal Article↗
PubMed2004

Physics embedded in visual perception of three-dimensional shape from motion.

Visual perception, and by implication underlying neural events, can become unstable when optical information specifying objects is ambiguous. Here we report that one striking form of instability-perceived three-dimensional structure-from-motion (SFM)-can be stabilized when an otherwise ambiguous object appears within a context implying frictional interactions with another rotating object; violations of physical conditions specifying friction disrupt stabilization. Evidently, information about frictional interaction is embedded within neural mechanisms specifying SFM.

Humans↗
PubMed2000

The importance of osmolality for intermittent catheterization of the urethra.

OBJECTIVES: The urethral trauma after catheterization with intermittent catheters was studied histologically using unconscious rabbits. SETTING: The study was performed at Astra Hässle, Mölndal, Sweden. MATERIALS AND METHODS: Fifteen rabbits were randomized into five groups (three rabbits in each group), one control group and four groups catheterized with four different LoFric catheters (Astra Tech, Mölndal, Sweden): (1) control (not catheterized); (2) salt coated (i.e. high osmolality catheters) with drainage eyes; (3) without salt (i.e. low osmolality catheters) and with eyes; (4) with salt coating but without drainage eyes; and (5) without neither salt coating nor drainage eyes. The urethral injuries were evaluated using a four graded histological scale. RESULTS: The results showed that salt coated LoFric catheters gave less urethral trauma than LoFric catheters without salt. This was also supported by the significantly lower removal friction measured during withdrawal of the high osmolality catheters. No significant differences either in removal friction or in urethral trauma could be observed between LoFric catheters with or without drainage eyes. CONCLUSION: It may be concluded that osmolality is one important factor (there might be others, like e.g. water binding ability) when comparing different hydrophilic catheters, in regards to removal friction and urethral trauma. Furthermore it is suggested that there is no difference in urethral trauma between catheters with eyes or without eyes. To minimize the risk of urethral trauma, high osmolality catheters are recommended, especially when the catheterization times are a few minutes or more.

Animals↗
PubMed2003

Rotational diffusion of the 7-diethylamino-4-methylcoumarin C1 dye molecule in polar protic and aprotic solvents.

Fluorescence anisotropy decays of the 7-diethylamino-4-methylcoumarin C1 in various polar solvents of different viscosities and hydrogen bond donor/acceptor character have been recorded by means of the fluorescence upconversion and time-correlated single photon counting techniques. The resulting characteristic times for the rotational diffusion fall into two classes with regards to the viscosity-dependency: n-alcohols and "other" solvents. This deviation from the simple Stokes-Einstein-Debye model may be interpreted in terms of rotation of the coumarin molecule under two different hydrodynamic boundary-conditions ("stick" or "slip") in the two solvent classes. Possible explanations for this behaviour are discussed, and in particular solvent attachment and additional dielectric friction. Both these phenomena may in fact, under certain conditions, explain our findings. Our opinion, however, is that the dielectric friction model offers a more realistic picture of the additional rotational friction experienced by C1 in n-alcohols.

Journal Article↗
PubMed2006

Particle-surface capillary forces with disjoining pressure.

A new, atomic force microscopy (AFM) based experimental setup for the continuous acquisition of friction force data as a function of humidity has been developed. The current model of interactions between wet contacts under the influence of capillary effects, has been amended to include a vertical component due to the disjoining pressure and takes into account the influence of liquid films adsorbed on the surface. This is a 'switching' model, i.e. the contact between nanometer-sized sphere and a flat surface can exist in two distinct states due to capillary bridge formation/destruction as the humidity is varied. The model has been qualitatively verified on samples of differing wettability produced by UV-ozone treatment of polystyrene (PS). Results of AFM analysis of the friction vs. vapor pressure curves collected from the surface are presented. Correlation between important surface properties such as wettability, adsorption, and contact angle and friction force under varying humidity were found and discussed.

Microscopy, Atomic Force↗
PubMed1999

Sealing properties of mechanical seals for an axial flow blood pump.

A miniature intraventricular axial flow blood pump for left ventricular support is under development. One of the key technologies required for such pumps is sealing of the motor shaft. In this study, to prevent blood backflow into the motor side, mechanical seals were developed and their sealing properties investigated. In the experimental apparatus, the mechanical seal separated the bovine blood on the chamber side from the cooling water on the motor side. A leakage of the blood was measured by inductively coupled plasma (ICP) light emission analysis. The rate of hemolysis was measured by the cyanmethemoglobin method. Frictional torque acting on the shaft was measured by a torque transducer. In the experiments, the rotational speed of the shaft was changed from 1,000 to 10,000 rpm, and the contact force of the seal faces was changed from 1.96 to 4.31 N. To estimate lubrication regimes, the Stribeck curve, a diagram of the coefficient of friction against the bearing characteristic G number, was drawn. The results of the experiments showed that both the leakage of blood and the rate of hemolysis were very small. The friction loss was also very small. The mechanical seal was operated in various lubrication regimes, from a fluid lubrication regime to a mixed lubrication regime.

Animals↗
PubMed2004

Spherical particle in Poiseuille flow between planar walls.

We study a spherical mesoparticle suspended in Newtonian fluid between plane-parallel walls with incident Poiseuille flow. Using a two-dimensional Fourier transform technique we obtain a symmetric analytic expression for the Green tensor for the Stokes equations describing the creeping flow in this geometry. From the matrix elements of the Green tensor with respect to a complete vector harmonic basis, we obtain the friction matrix for the sphere. The calculation of matrix elements of the Green tensor is done in large part analytically, reducing the evaluation of these elements to a one-dimensional numerical integration. The grand resistance and mobility matrices in Cartesian form are given in terms of 13 scalar friction and mobility functions which are expressed in terms of certain matrix elements calculated in the spherical basis. Numerical calculation of these functions is shown to converge well and to agree with earlier numerical calculations based on boundary collocation. For a channel width broad with respect to the particle radius, we show that an approximation defined by a superposition of single-wall functions is reasonably accurate, but that it has large errors for a narrow channel. In the two-wall geometry the friction and mobility functions describing translation-rotation coupling change sign as a function of position between the two walls. By Stokesian dynamics calculations for a polar particle subject to a torque arising from an external field, we show that the translation-rotation coupling induces sideways migration at right angles to the direction of fluid flow.

Journal Article↗
PubMed2005

Dynamic characterization of hysteresis elements in mechanical systems. II. Experimental validation.

The industrial demand for machine tools with ever increasing speed and accuracy calls for a closer look at the physical phenomena that are present at small movements of those machine's slides. One of these phenomena, and probably the most dominant one, is the dependence of the friction force on displacement that can be described by a rate-independent hysteresis function with nonlocal memory. The influence of this highly nonlinear effect on the dynamics of the system has been theoretically analyzed in Part I of this paper. This part (II) aims at verifying these theoretical results on three experimental setups. Two setups, consisting of linearly driven rolling element guideways, have been built to specifically study the hysteretic friction behavior. The experiments performed on these specially designed setups are then repeated on one axis of an industrial pick-and-place device, driven by a linear motor and guided by commercial guideways. The results of the experiments on all the setups agree qualitatively well with the theoretically predicted ones and point to the inherent difficulty of accurate quantitative identification of the hysteretic behavior. They further show that the hysteretic friction behavior has a direct bearing on the dynamics of machine tools and its presence should therefore be carefully considered in the dynamic identification process of these systems.

Computers↗