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At least 163 records · Page 9Linked to original sources
PubMed2006

Synthesis, characterization, and DFT-TDDFT computational study of a ruthenium complex containing a functionalized tetradentate ligand.

A ruthenium complex trans-[Ru(L)(NCS)2], L = 4,4' ''-di-tert-butyl-4',4' '-bis(carboxylic acid)-2,2':6',2' ':6' ',2' ''-quaterpyridine (N886), was synthesized and characterized by spectroscopic and electrochemical methods. The absorption spectrum of the N886 complex shows metal-to-ligand charge-transfer transitions in the entire visible region and quasi-reversible oxidation and reduction potentials at E(1/2) = +0.38 and -1.92 V vs ferrocene, respectively. The electronic spectra of the N886 complex were calculated by density functional theory (DFT)-time-dependent DFT, which qualitatively reproduces the experimental absorption spectra for both the protonated and deprotonated species. From the analysis of the computed optical transitions of N886, we assign its absorption bands as mixed Ru/SCN-to-quaterpyridine charge-transfer transitions, which extend from the near-IR to the UV regions. The panchromatic response of the N886 complex renders it as a suitable sensitizer for solar energy conversion applications based on titanium dioxide mesoporous electrodes. The preliminary results using the N886 complex as a sensitizer in a dye-sensitized solar cell, with an electrolyte containing 0.60 M butylmethylimidazolium iodide, 0.03 M I2, and 0.50 M tert-butylpyridine in a mixture of acetonitrile and valeronitrile (volume ratio 1:1), show 40% incident photon-to-current efficiencies, yielding under standard AM 1.5 sunlight a short-circuit photocurrent density of 11.8 +/- 0.2 mA/cm(2), an open-circuit voltage of 680 +/- 30 mV, and a fill factor of 0.73 +/- 0.03, corresponding to an overall conversion efficiency of 5.85%.

Journal Article↗
PubMed2005

Solar mass-varying neutrino oscillations.

We propose that the solar neutrino deficit may be due to oscillations of mass-varying neutrinos (MaVaNs). This scenario elucidates solar neutrino data beautifully while remaining comfortably compatible with atmospheric neutrino and K2K data and with reactor antineutrino data at short and long baselines (from CHOOZ and KamLAND). We find that the survival probability of solar MaVaNs is independent of how the suppression of neutrino mass caused by the acceleron-matter couplings varies with density. Measurements of MeV and lower energy solar neutrinos will provide a rigorous test of the idea.

Journal Article↗
PubMed1976

Solar heating and cooling.

Solar energy is discussed as an energy resource that can be converted into useful energy forms to meet a variety of energy needs. The review briefly explains the nature of this energy resource, the kinds of applications that can be made useful, and the status of several systems to which it has been applied. More specifically, information on solar collectors, solar water heating, solar heating of buildings, solar cooling plus other applications, are included.

Air Conditioning↗
PubMed1996

Body temperatures of free-living African penguins (Spheniscus demersus) and bank cormorants (Phalacrocorax neglectus).

Two free-living seabirds (the African penguin Spheniscus demersus and the bank cormorant Phalacrocorax neglectus) were equipped with stomach temperature-loggers to study body temperature changes during foraging. Body temperature in these endotherms was environmentally and activity-dependent and varied in the case of the cormorant by over 5 degrees C. Considerations of heat flux show that such flexibility confers considerable energetic advantages: by allowing body temperature to drop when the heat loss to the environment is high, such as in water, birds may save the energy that would normally be necessary to compensate for this drop. It appears that, in cormorants, low body temperature resulting from extended time in water can subsequently be elevated using solar energy when birds return to land in a manner similar to that of ectotherms. In the better-insulated penguins, muscle-generated heat during swimming is used to re-elevate low body temperature. Continued swimming eventually causes body temperature to rise above normal resting levels so that metabolic rate could theoretically be dramatically reduced immediately post-exercise when the temperature drops to some critical level before any increase in metabolism is necessary to correct it.

Animals↗
PubMed2004

[Advances in energy analysis of agro-ecosystems].

The energy analysis of agro-ecosystems from the view point of energy flow is a quantitative study on the function of agro-ecosystem, and is one of the most important aspects in agro-ecosystem study. In this paper, the history and some current progresses of energy analysis on agro-ecosystems were reviewed briefly, and the difference and breakthrough of emergy analysis theory with the traditional energy analysis method, some current challenges in front of emergy analysis of agro-ecosystems, and some of the new trends were discussed. Using the direct and indirect cost of solar energy to evaluate any energy or material, emergy analysis is the new development of energy analysis, not only in concept but also on calculation method. Developing to emergy analysis phase, there were still some deficiencies on energy analysis of agro-ecosystem, such as the complicate calculation of transformation and the vacancy of energy index for sustainable development, etc. How to solve these problems combined with the clearing of the maximum Em-power principle, the combination among energy analysis, emergy analysis, material analysis and landscape analysis has made up of the current and future trends of energy analysis of agro-ecosystem.

Agriculture↗
PubMed1992

The deep, hot biosphere.

There are strong indications that microbial life is widespread at depth in the crust of the Earth, just as such life has been identified in numerous ocean vents. This life is not dependent on solar energy and photosynthesis for its primary energy supply, and it is essentially independent of the surface circumstances. Its energy supply comes from chemical sources, due to fluids that migrate upward from deeper levels in the Earth. In mass and volume it may be comparable with all surface life. Such microbial life may account for the presence of biological molecules in all carbonaceous materials in the outer crust, and the inference that these materials must have derived from biological deposits accumulated at the surface is therefore not necessarily valid. Subsurface life may be widespread among the planetary bodies of our solar system, since many of them have equally suitable conditions below, while having totally inhospitable surfaces. One may even speculate that such life may be widely disseminated in the universe, since planetary type bodies with similar subsurface conditions may be common as solitary objects in space, as well as in other solar-type systems.

Bacterial Physiological Phenomena↗
PubMed2001

[Energy production of plants in grass, Dicranopteris dichotoma and Rhodomyrtus tomentosa communities in Hong Kong].

With harvest method and caloric value analysis, this paper studied the caloric values, standing energy, net fixed energy and net standing energy increment of three plant communities i.e., grass, Dicranopteris dichotoma and Rhodomyrtus tomentosa, in Hong Kong. The results showed that the caloric value was higher in D. dichotoma community and lower in grass community. The standing energy of plants in grass, D. dichotoma and R. tomentosa community was 18,638, 38,436 and 65,632 kJ.m-2; net fixed energy was 13,286, 20,354 and 18,784 kJ.m-2.yr-1; and net standing energy increment was 3437, 9626 and 6695 kJ.m-2.yr-1, respectively. Compared with southern subtropical evergreen broad-leaved forest, the standing energy, net fixed energy and net standing energy increment were lower in grass, D. dichotoma and R. tomentosa communities, which resulted from deforestation and other human disturbance. This indicated that vegetation conversion due to human disturbance would reduce the utilization coefficient of solar energy. Net fixed energy was also found to be reduced significantly with increasing intensity of human disturbance.

Energy Metabolism↗
PubMed2005

Terrestrial gamma-ray flashes observed up to 20 MeV.

Terrestrial gamma-ray flashes (TGFs) from Earth's upper atmosphere have been detected with the Reuven Ramaty High Energy Solar Spectroscopic Imager (RHESSI) satellite. The gamma-ray spectra typically extend up to 10 to 20 megaelectron volts (MeV); a simple bremsstrahlung model suggests that most of the electrons that produce the gamma rays have energies on the order of 20 to 40 MeV. RHESSI detects 10 to 20 TGFs per month, corresponding to approximately 50 per day globally, perhaps many more if they are beamed. Both the frequency of occurrence and maximum photon energy are more than an order of magnitude higher than previously known for these events.

Journal Article↗
PubMedDate not supplied

Radioactivity as a significant energy source in prebiotic synthesis.

Radioactivity in the continental crust (due mainly to the isotopes 238U, 235U, 232Th and 40K), as a energy source for chemical evolution in the early Archean (between 3.5 and approximately 4 Ga bp), is reviewed. The most important radioactive source in the continental crust is due to the production and accumulation of radioactive gases within the crust voids (porosity). The study of such mechanism has allowed us to reach a deeper understanding about the nature of the radioactive source and to describe its behavior, particularly with regard to prebiotic chemical evolution. An effective total energy of 3 x 10(18) Ja-1 has been obtained for a depth of 1 km, 4 Ga ago. If a depth of 30 km is taken, the obtained value is almost equal to the UV solar energy radiation (lambda < 150 nm). Within the voids the radioactive source of the continental crust played a relevant role in prebiotic synthesis. In uranium deposits of the same age, the role of radioactivity must have been even more relevant in favoring chemical evolution.

Earth, Planet↗
PubMed2006

An overview of challenges in modeling heat and mass transfer for living on Mars.

Engineering a life-support system for living on Mars requires the modeling of heat and mass transfer. This report describes the analysis of heat and mass transfer phenomena in a greenhouse dome, which is being designed as a pressurized life-support system for agricultural production on Mars. In this Martian greenhouse, solar energy will be converted into chemical energy in plant biomass. Agricultural products will be harvested for food and plant cultivation, and waste materials will be processed in a composting microbial ecosystem. Transpired water from plants will be condensed and recycled. In our thermal design and analysis for the Martian greenhouse, we addressed the question of whether temperature and pressure would be maintained in the appropriate range for humans as well as plants. Energy flow and material circulation should be controlled to provide an artificial ecological system on Mars. In our analysis, we assumed that the greenhouse would be maintained at a subatmospheric pressure under 1/3-G gravitational force with 1/2 solar light intensity on Earth. Convection of atmospheric gases will be induced inside the greenhouse, primarily by heating from sunlight. Microclimate (thermal and gas species structure) could be generated locally around plant bodies, which would affect gas transport. Potential effects of those environmental factors are discussed on the phenomena including plant growth and plant physiology and focusing on transport processes. Fire safety is a crucial issue and we evaluate its impact on the total gas pressure in the greenhouse dome.

Agriculture↗
PubMed1982

Cassava as a food.

This review has attempted to examine information pertaining to the role of cassava (Manihot esculenta) as a major food source for a large part of the world population, particularly the countries of South America, Africa, and Asia, where it is primarily a major source of energy for 300 to 500 million people. Its cultivation, usually on small farms with little technology, is estimated to cover on an annual basis about 11 million hectares providing about 105 million tons, more than half of which is consumed by humans. The importance of cassava as an energy source can be seen by its growing demand in the European economic community countries where it forms up to 60% of the balanced diets for swine. Cassava is one of the crops that converts the greatest amount of solar energy into soluble carbohydrates per unit of area, thus 1 kg of moisture-free cassava meal may yield up to about 3750 kcal which would mean that a yearly production of 15 tons of cassava meal per hectare would yield some 56 million kcal. The major limitations of cassava as food appear to be its poor protein content and quality and the rapid post harvest deterioration of its roots which usually prevents their storage in the fresh state for more than a few days. However, in addition to its use for culinary purposes, cassava finds application in industrial products such as an adhesive for laundry purposes, for manufacturing paper, alcohol, butanol, dextrin, adhesive tape, textile sizing, and glue.

Animal Feed↗
PubMed2003

Renewable energy for the aeration of wastewater ponds.

The application of a decentralised renewable energy supply for the aeration of wastewater ponds, and the influence of an unsteady oxygen supply on the specific conversion rate and biocoenose was investigated. With the discontinuous aeration the specific conversion rate is increased as compared to facultative ponds. The estimation of the microorganisms consortia was done with in situ hybridisation techniques. A significant shift in the bacteria population with the chosen specific probes for anaerobic, sulphate reducing and nitrifying bacteria could not be detected. Wastewater ponds have sufficient buffer volume to compensate for the fluctuating energy supply. But the efficiency of the energy supply of a photovoltaic plant decreases in shallow lakes (d < 1.5 m) corresponding to a high oxygen production of algae. For the layout of the individual components: photovoltaic and wind power plant, energy management, aeration system and wastewater pond, a simulation model was developed and tested. The application of renewable energy for the aeration of wastewater ponds is a useful alternative for the redevelopment of overloaded ponds as well as the construction of new wastewater ponds, especially in areas with an inadequate central electricity grid and a high availability of wind and solar energy.

Conservation of Energy Resources↗
PubMed2005

Improved photobiological H2 production in engineered green algal cells.

Oxygenic photosynthetic organisms use solar energy to split water (H2O) into protons (H+), electrons (e-), and oxygen. A select group of photosynthetic microorganisms, including the green alga Chlamydomonas reinhardtii, has evolved the additional ability to redirect the derived H+ and e- to drive hydrogen (H2) production via the chloroplast hydrogenases HydA1 and A2 (H2 ase). This process occurs under anaerobic conditions and provides a biological basis for solar-driven H2 production. However, its relatively poor yield is a major limitation for the economic viability of this process. To improve H2 production in Chlamydomonas, we have developed a new approach to increase H+ and e- supply to the hydrogenases. In a first step, mutants blocked in the state 1 transition were selected. These mutants are inhibited in cyclic e- transfer around photosystem I, eliminating possible competition for e- with H2ase. Selected strains were further screened for increased H2 production rates, leading to the isolation of Stm6. This strain has a modified respiratory metabolism, providing it with two additional important properties as follows: large starch reserves (i.e. enhanced substrate availability), and a low dissolved O2 concentration (40% of the wild type (WT)), resulting in reduced inhibition of H2ase activation. The H2 production rates of Stm6 were 5-13 times that of the control WT strain over a range of conditions (light intensity, culture time, +/- uncoupler). Typically, approximately 540 ml of H2 liter(-1) culture (up to 98% pure) were produced over a 10-14-day period at a maximal rate of 4 ml h(-1) (efficiency = approximately 5 times the WT). Stm6 therefore represents an important step toward the development of future solar-powered H2 production systems.

Animals↗
PubMed2006

Light and singlet oxygen in plant defense against pathogens: phototoxic phenalenone phytoalexins.

Plants defend themselves from pathogen infections or mechanical injury by a number of mechanisms, including the induced biosynthesis of antimicrobial secondary metabolites. These compounds, termed phytoalexins, represent a very economical way to counteract hazard, because the carbon and energy resources are diverted to phytoalexin synthesis only at the early period of attack and only at its site. The occurrence of phenalenone chromophores in phytoalexins of plants originally nonphototoxic suggests that these plants respond to pathogen attacks by biosynthesizing singlet oxygen photosensitizers able to use solar energy for defense. This concept may have implications for the development of novel crop protection strategies.

Light↗
PubMed2006

Energy, charge, and spin transport in molecules and self-assembled nanostructures inspired by photosynthesis.

Electron transfer in biological molecules provides both insight and inspiration for developing chemical systems having similar functionality. Photosynthesis is an example of an integrated system in which light harvesting, photoinduced charge separation, and catalysis combine to carry out two thermodynamically demanding processes, the oxidation of water and the reduction of carbon dioxide. The development of artificial photosynthetic systems for solar energy conversion requires a fundamental understanding of electron-transfer reactions between organic molecules. Since these reactions most often involve single-electron transfers, the spin dynamics of photogenerated radical ion pairs provide important information on how the rates and efficiencies of these reactions depend on molecular structure. Given this knowledge, the design and synthesis of large integrated structures to carry out artificial photosynthesis is moving forward. An important approach to achieving this goal is the development of small, functional building blocks, having a minimum number of covalent bonds, which also have the appropriate molecular recognition sites to facilitate self-assembly into a complete, functional artificial photosynthetic system.

Carbon Dioxide↗
PubMed1992

Solar flares: an overview.

This is a survey of solar phenomena and physical models that may be useful for improving forecasts of solar flares and proton storms in interplanetary space. Knowledge of the physical processes that accelerate protons has advanced because of gamma-ray and X-ray observations from the Solar Maximum Mission telescopes. Protons are accelerated at the onset of flares, but the duration of any subsequent proton storm at 1 AU depends on the structure of the interplanetary fields. X-ray images of the solar corona show possible fast proton escape paths. Magnetographs and high-resolution visible-band images show the magnetic field structure near the acceleration region and the heating effects of sunward-directed protons. Preflare magnetic field growth and shear may be the most important clues to the physical processes that generate high energy solar particles. Any dramatic improvement in flare forecasts will require high resolution solar telescopes in space. Several possibilities for improvements in the art of flare forecasting are presented, among them: the use of acoustic tomography to probe for subsurface magnetic fields; a satellite-borne solar magnetograph; and an X-ray telescope to monitor the corona for eruptions.

Astronomical Phenomena↗
PubMed2006

Efficient energy transfer from peripheral chromophores to the self-assembled zinc chlorin rod antenna: a bioinspired light-harvesting system to bridge the "green gap".

An artificial light-harvesting rod aggregate based on zinc chlorin and covalently linked naphthalene bisimide chromophore has been realized by self-assembly. Efficient energy transfer (phiET >/= 0.99) takes place upon excitation at 620 nm from peripheral naphthalene bisimides to the zinc chlorin rod aggregate backbone. The appended naphthalene bisimide dyes improve the total LH efficiency of the rod aggregate by 26%. Thus, the present bioinspired antenna system is promising for application in nanodevices for the effective utilization of solar energy by bridging the "green gap".

Energy Transfer↗
PubMed2000

Vibrational promotion of electron transfer.

By using laser methods to prepare specific quantum states of gas-phase nitric oxide molecules, we examined the role of vibrational motion in electron transfer to a molecule from a metal surface free from the complicating influence of solvation effects. The signature of the electron transfer process is a highly efficient multiquantum vibrational relaxation event, where the nitrogen oxide loses hundreds of kilojoules per mole of energy on a subpicosecond time scale. These results cannot be explained simply on the basis of Franck-Condon factors. The large-amplitude vibrational motion associated with molecules in high vibrational states strongly modulates the energetic driving force of the electron transfer reaction. These results show the importance of molecular vibration in promoting electron transfer reactions, a class of chemistry important to molecular electronics devices, solar energy conversion, and many biological processes.

Journal Article↗