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[Determination of fumes and their elements from flux cored arc welding].

BACKGROUND: The aim of this work was to assay the concentration levels and composition of welding fumes, released during flux cored arc welding, to assess exposure of welders. MATERIALS AND METHODS: Concentrations and welding fume components, such as iron, manganese, chromium (including the soluble and chromium VI), nickel, copper, calcium, aluminium, barium, and fluorides (including hydrogen fluoride) were determined in the air of six industrial plants (shipyards, mechanical engineering plants and a power station) at the breathing zones of the welders who used 10 types of wires during flux cored arc welding. The following determination methods were used: gravimetry (fumes), AAS (metals), and spectrophotometry (chromium VI, fluorides--including hydrogen fluoride). RESULTS: The results made it possible to determine the relationship between concentrations of welding fume and its elements, and to assess worker's exposure. Time weighted average concentrations of the welding fumes and its elements at the worker's breathing zone were: mg/m3: dust 0.2-24.3; Fe 0.2-6.7; Mn 0.01-1.8; Cr 0.004-0.5 (mainly Cr III); Ca 0.004-2.5; Ni < or = 0.004; Cu < 0.002-0.05; Al < 0.14-0.4; Ba < 0.14; F- 0.07-0.43. CONCLUSIONS: The welders using some types of flux cored welding wires worked in conditions harmful to their health owing to the considerably exceeded TLV value for fume and MAC values for manganese, and occasional slightly excessive MAC values for calcium and iron.

Air Pollutants, Occupational↗

Fatigue life of a Nd:YAG laser-welded metal ceramic alloy.

Fifteen laser-welded Olympia alloy samples were divided into three groups of five samples each, with different gap distances between the welded halves. The first group was welded with a 0.0-mm gap distance. The second and third groups had Olympia shims placed in 0.3- and 1.0-mm gaps, respectively, prior to laser welding. Each of the samples was tested to failure in load fatigue at 30 Hz in a fatigue testing device using an applied stress of 35,000 psi (241.4 MPa). The means and standard deviations for the number of cycles required to produce fatigue failure for each group was 494,618 +/- 118,311 cycles for the group welded with 0.0-mm gap distance, and 242,741 +/- 44,623 and 232,021 +/- 55,877 cycles for the 0.3- and 1.0-mm specimens, respectively. A one-way analysis of variance showed that the 0.0-mm gap specimens had the greatest number of cycles to failure (P < or = 0.05). There was no significant difference between the other two groups. With the exception of two specimens that failed at the weld center, all failures occurred at the edge of the weld.

Analysis of Variance↗

Laser welding in the dental laboratory: an alternative to soldering.

Only recently has laser welding been applied to dental technology, primarily as an alternative to soldering. This article addresses how the laser is used for welding, the effect welding has on metals as the energy is converted into heat and reacts with the alloy's surface and the practicality of laser welding in the dental laboratory. A step-by-step procedure for accomplishing laser-welded connections in a fixed partial denture is included. A laser-welded clasp repair using wrought wire and the addition of custom cast parts welded to an existing removable partial denture framework on the master model are also shown.

Dental Soldering↗

Preliminary study of laser welding for aortic dissection in a porcine model using a diode laser with indocyanine green.

BACKGROUND AND OBJECTIVES: The objective of this study was to determine whether a dissected aorta could be welded by a diode laser with a solder using an in vitro porcine aortic dissection model. STUDY DESIGN/MATERIALS AND METHODS: Porcine aortic strips were dissected into two flaps and the dissected faces were immersed in a solution of indocyanine green. The two flaps were pressed at 0.2 kg/cm2 with contact between the two immersed faces. The pressed flaps were irradiated with a diode laser (810 nm) at intensities of 170-425 W/cm2 for 8 seconds. The welded flaps were studied by light microscopy and the adhesive strengths were measured. RESULTS: The irradiated flaps were successfully welded. The breaking stress, the maximum stress recorded in a stress-strain curve, increased with increase in irradiation intensity up to 396 W/cm2 (2.7 x 10(2) mmHg) and decreased when the intensity reached 425 W/cm2. In the specimen irradiated at 396 W/cm2, the welded faces showed continuous fusion of elastin layers, while some voids were seen between the welded faces in the specimen irradiated at 425 W/cm2. CONCLUSIONS: The dissected porcine aortas were successfully welded using a laser with solder. The results suggest that the welded aorta can bear physiological blood pressure.

Aortic Dissection↗

Mechanism of tissue fusion in argon laser-welded vein-artery anastomoses.

The mechanism of laser vascular tissue welding remains unknown. This study compared the acute tissue response and long-term healing of sutured and laser-welded anastomoses of vein segments used to bypass ligated canine femoral arteries. For each procedure, one anastomosis was formed using running 6-0 polypropylene suture (control), and the other anastomosis was formed using argon laser tissue welding (experimental). The vein grafts were harvested at 4 (n = 2), 8 (n = 1), 12 (n = 1), and 16 (n = 2) weeks, and selected samples were evaluated by histologic examination, electron microscopy, tensile strength testing, and by measuring the formation of [3H]hydroxyproline as an index of collagen synthesis. Examination of successful laser fusions immediately after they were formed showed bonding of collagen to collagen and elastin to collagen. Follow-up evaluations showed that the precision of tissue apposition affected the rate of healing and tensile strength. Laser-welded anastomoses demonstrated a progression of healing similar to sutured repairs, with remodeling of fibrous tissue and collagen being the primary component of weld integrity. This study demonstrates that sutured and argon laser-welded vein-artery anastomoses heal comparably up to 16 weeks postoperatively, and that laser welding is a satisfactory alternative to sutured anastomoses.

Animals↗

CO2 and argon laser vascular welding: acute histologic and thermodynamic comparison.

CO2 and argon lasers have been used successfully for vascular welding in both experimental and clinical settings. This study compared the thermodynamics during CO2 and argon laser welding of 1-cm longitudinal arteriotomies in a canine model. Continuous recordings using an AGA 782 digital thermographic system with spatial and thermal resolution of +/-0.2 mm and +/-0.2 degree C, respectively, were analyzed. A HGM argon laser using a 300-microns optic fiber held at 1 cm from the vessel edges (spot diameter = 2.8 mm) with concomitant room temperature saline irrigation (1 drop/sec) was used for argon welds. Total exposure time was 150 sec/cm. CO2 welds were performed with a Sharplan CO2 laser (spot diameter = 0.22 mm) with no irrigation for total exposure time of 10 sec/cm. Thermodynamic results and laser parameters are summarized as follows: Argon-n = 20; power = 500 mW; energy fluence = 1,400 J/cm2; Tmax = 48.8 degrees C; T mean +/- S.D. = 45.1 +/- 2.7 degrees C; CO2-n = 20; power = 150 mW; energy fluence = 3,000 J/cm2; Tmax 84.0 degrees C; T mean +/- S.D. = 60.7 +/- 9.8 degrees C. There was a significant difference (P less than .05) in thermal measurements between successful CO2 and argon vascular welds. Temperature rise during the argon welds was limited by saline irrigation. In contrast, during CO2 laser welding, the temperature rose quickly to its maximum and was maintained at a relatively high level as the laser progressed (0.1 cm/sec) along the anastomosis.(ABSTRACT TRUNCATED AT 250 WORDS)

Animals↗

Absorption characteristics at 1.9 microns: effect on vascular welding.

A 1.9 microns laser was used to investigate the acute weld strengths for anastomoses of rat and rabbit aortas and femoral arteries. The wall thicknesses for these vessels approximately matched the optical absorption depth of 125 microns for 1.9 microns radiation in vascular tissues. A low power (150 mW) 1.9 microns laser was used. Laser power was delivered through silica fiber optics for manual control. The fiber tip was held approximately 1 mm from the target resulting in a laser spot size of 0.7 mm at the tissue. The linear delivery rate was approximately 0.3 mm/sec. Acute burst pressures of the welds showed a linear correlation with the reciprocal of the vessel radius. These results suggest that the product of the weld strength times the optical absorption depth is constant over the range of vessel sizes studied. A weld strength for a weld thickness equal to the optical absorption depth was determined to be 4 x 10(6) dynes/cm2, which is comparable to the strength of sutured anastomoses. These acute studies suggest that a laser wavelength with absorption depth in tissue matched to the vessel wall thickness should yield optimum welds. Therefore, a laser operating near 1.9 microns is suitable for small vessel welding.

Anastomosis, Surgical↗

Information contained in the radiating ultrasound during ultrasonic welding

During ultrasonic welding, unnecessary ultrasound together with audible sound is radiated into the air. Audible sound is noisy and uncomfortable, and ultrasound may have bed effects on adjacent equipment. However, it is considered that these sounds potentially contain useful information such as welding state. This article reports the relationship between radiated ultrasound and the change of the welding state during ultrasonic welding. It is known that the welding state can be presumed from the change of the mechanical load impedance, which can be calculated from resonant frequency, motional voltage and the driving current of the vibrating system for the welder when a constant-velocity motional-feedback power oscillator is used. In this study, radiated ultrasound picked up with a microphone and an amplifier is recorded and analyzed with a personal computer. Analyzed results are compared with the change of the mechanical load impedance that is also calculated from the recorded data of the resonant frequency, motional voltage and the driving current of the vibrating system for the welding. Experiments were made on the ultrasonic welding of plastic rods. The relationship between the parameters of radiated ultrasound and the electrical parameters of the vibrating system were compared. The peak amplitude of the radiated ultrasound and the mechanical impedance versus time were very similar. It is shown in this study that radiated ultrasound contains lots of useful information.

Journal Article↗

Preliminary study of microsurgical repairs of the inferior alveolar nerve in rats using primary suturing and laser weld techniques.

A comparison of primary suturing and a new laser weld technique is described for the microsurgical repair of the inferior alveolar nerve in Wistar rats. A reliable method of exposure of the inferior alveolar nerve has been developed in order to allow intraosseous repairs of the nerve involving suturing with 10:0 nylon and a laser weld technique using an albumin-based solder, containing indocynine cardiogreen, plus an infrared (810 nm wavelength) diode laser. Seven cases of microsuture and laser weld repairs were performed with a 29.4% reduction in total operating time in the laser weld group. Histochemical analysis showed comparable mean neuron counts and mean tracer uptake by neurons for the microsuture and laser weld groups. Giant cell reactions were identified in two of the primary suture cases and axon deflection in three cases demonstrating possible advantages of the laser weld technique which showed no adverse reactions by axons or epineurium to the coagulative repair with the solder. The technique of laser weld repair, on initial analysis, therefore appears comparable with traditional suture repairs and indeed may possess several advantages. Further studies are recommended.

Animals↗

Mechanical and structural characteristics of commercially pure grade 2 Ti welds and solder joints.

This study aimed at determining whether data previously gathered for a laser welds and IR brazings using a Au-Pd alloy were applicable to titanium joints. As to its resistance under fatigue loading, Au-Pd alloy had shown a poor response to pre-ceramic laser welding and post-ceramic brazing. The present study was designed to assess the mechanical resistance, the microstructure and the elemental diffusion of laser welded, electric arch welded and brazed joints using commercially pure titanium as substrate metal. Mechanical resistance was determined by determining the joints' ultimate tensile strength and their resistance to fatigue loading. Elemental diffusion to and from the joints was assessed using microprobe tracings. Optical micrographs of the joints were also obtained and evaluated. Under monotonic tensile stress, three groups emerged: (1) the GTAW and the native (i.e. as received) substrate, (2) the annealed substrate and the laser welds and (3) the brazed joints. Under fatigue stress, the order was: first the native and annealed substrate, second the brazings and laser welds, third the GTAW joints. No Au-filler brazing withstood the applied fatigue loading. The micrographs showed various patterns, an absence of HAZ cracking and several occurrences of Widmanstätten structures. Elemental diffusion to and from the Ti substrate was substantial in the Ti filler brazings and virtually nil in the Au-based brazings. Under fatigue stress application, the titanium-based brazings as well as the laser- and electric arc welds performed equally well if not better than a previously tested AuPd alloy. There was a definite increase in grain size with increased heat application. However, no feature of the microstructures observed or the elemental analysis could be correlated with the specimen's resistance to fatigue stress application.

Journal Article↗

Radiofrequency electromagnetic leakage fields from plastic welding machines. Measurements and reducing measures.

Operators of unshielded plastic welding machines are often exposed to radiofrequency (RF) electromagnetic leakage fields that substantially exceed all present occupational standards. Measurements show that the Swedish ceiling values (SE = SH = 250 W/m2) in many cases are exceeded at distances up to 1 meter from the electrode. To reduce the stray fields to an acceptable level at the location of the operator, RF field suppression devices should be fitted to the machine. We have studied the strength and the extent of the RF leakage field under various operating conditions and also investigated different methods for reducing the leakage field. The following measurements have been performed: E- and H-field strengths as a function of distance from the electrode, and as a function of load/tuning; the time dependence of [E]2 for various combinations of tuning and welding times producing a welding seam with the same strength; isopower density curves for SE and SH = 250 W/m2 with different types of RF emission control devices fitted to the machine; the RF voltage between the electrode and the welding table and the RF voltage on the machine casing. By decreasing the RF power and increasing the welding time the field strengths at the location of the operator can be reduced to levels below the ceiling values. The RF voltage between the electrode and the welding table ranged from 800 V up to 2100 V for the different plastic material that was welded. The RF voltage on certain parts on the chassis could be as high as 200 V. In order to reduce these voltages and the stray fields the machine should be equipped with a "large capacitive shield" in cases where this is possible.

Electrodes↗

Cryogen spray cooling during laser tissue welding.

Cryogen cooling during laser tissue welding was explored as a means of reducing lateral thermal damage near the tissue surface and shortening operative time. Two centimetre long full-thickness incisions were made on the epilated backs of guinea pigs, in vivo. India ink was applied to the incision edges then clamps were used to appose the edges. A 4 mm diameter beam of 16 W, continuous-wave, 1.06 microm, Nd:YAG laser radiation was scanned over the incisions, producing approximately 100 ms pulses. There was a delay of 2 s between scans. The total irradiation time was varied from 1-2 min. Cryogen was delivered to the weld site through a solenoid valve in spurt durations of 20, 60 and 100 ms. The time between spurts was either 2 or 4 s, corresponding to one spurt every one or two laser scans. Histology and tensile strength measurements were used to evaluate laser welds. Total irradiation times were reduced from 10 min without surface cooling to under 1 min with surface cooling. The thermal denaturation profile showed less denaturation in the papillary dermis than in the mid-dermis. Welds created using optimized irradiation and cooling parameters had significantly higher tensile strengths (1.7 +/- 0.4 kg cm(-2)) than measured in the control studies without cryogen cooling (1.0 +/- 0.2 kg cm(-2)) (p < 0.05). Cryogen cooling of the tissue surface during laser welding results in increased weld strengths while reducing thermal damage and operative times. Long-term studies will be necessary to determine weld strengths and the amount of scarring during wound healing.

Anesthetics↗

Laser welding of rat's facial nerve.

The aim of this study is to compare regeneration of the severed nerves that were repaired by laser welding with those repaired by microsurgical suturing and evaluate the value in use of laser nerve welding in the head and neck area. In 12 rats the buccal branches of the facial nerves on the both sides were transected, and CO2 laser welding of the epineurium was performed on the right side and microsurgical suture technique was applied on the left side. In six rats Cholera Toxin B Subunit (CTb) was injected in the epineurium distal to the nerve anastomosis site at postoperative week 4. Another six rats were treated exactly in the same way in postoperative week 8. Six normal rats were used as controls. Intact facial nerve was observed after injection of CTb as well. Neurons of facial nuclei labeled positively by CTb were detected immunohistochemically, and the numbers were counted. CTb-positive neurons in the control group were 1311 +/- 258 (n = 6). CTb-positive neurons in the group (n = 6) with laser nerve welding were 1174 +/- 122 in postoperative week 4 and 1562 +/- 565 in postoperative week 8. CTb-positive neurons in the group (n = 6) with microsurgical suture were 1066 +/- 89 in postoperative week 4 and 1443 +/- 531 in postoperative week 8. CTb-positive neurons were seen significantly more in the group with laser welding than in the group with microsurgical suture in postoperative week (P = 0.028), but there was not much difference in postoperative week 8 (P = 0.463). None of 12 rats showed dehiscence at the nerve anastomosis done by laser welding. This study shows that nerve regeneration is more apparent in the nerve repaired by laser welding than in that repaired by microsurgical suture.

Animals↗

An investigation of the potential for laser nerve welding.

Suture repair of a severed peripheral nerve is cumbersome, presents a focus for infection and neuroma formation, and does not always produce adequate stump alignment. An alternative form of repair is laser nerve welding, which is attractive because it does not introduce foreign material into the anastomotic site, it forms a circumferential seal, and it can be performed in difficult-to-reach areas. Laser repair has not been widely accepted both because the effect of laser irradiation on intact nerves is not well documented, and the anastomotic strength of the weld has been inferior to suture repair. In the first part of the present study, rat sciatic nerves were exposed and irradiated with increasing intensities from a Sharplan CO2 and KTP laser to document nerve damage as recorded by decreases in the peak compound action potential. A new technique of laser repair (S-Q weld) was then developed that involved harvesting subcutaneous tissue from the adjacent dermis, wrapping it around the two opposed nerve stumps, and lasering it to the epineurium to effect a weld. The strength of the S-Q weld (6.1 grams) was considerably greater than that produced by laser welding alone. The third phase of the study compared regeneration at 2 months in severed rat sciatic nerves repaired by either microsuture or S-Q weld. Analysis of the compound action potential values indicated that the number of regenerating fibers after laser repair was greater than that after suture repair, although a significant difference could not be demonstrated.(ABSTRACT TRUNCATED AT 250 WORDS)

Action Potentials↗

A comparison of ultrasonic suture welding and traditional knot tying.

The slippage of knots and the technical challenge of tying them securely are potential impediments to certain arthroscopic procedures. Ultrasonic energy delivered at 70 kHz can be used to weld No. 2 polypropylene suture. This method was compared with a traditional knot (surgeon's knot with four alternating half hitches) tied with an open technique to determine whether welding of sutures is comparable, in mechanical properties, to hand-tied knots. Both loops were fashioned around a 0.25-inch mandrel and then tested. The load to reach 3-mm elongation (point of likely biologic failure of a repair) was significantly greater for welded sutures than for knots. The elongation at ultimate failure was significantly less for welded sutures than for knots. The number of cycles to failure and the creep after initial displacement were similar for both welded and knotted suture loops. The ultimate load to failure was significantly greater for the knotted than for the welded suture. The welding of suture for the repair of musculoskeletal soft tissue presents an attractive alternative to traditional knot tying, particularly for arthroscopic applications.

Equipment Failure Analysis↗

Responses to welding fumes: lung injury, inflammation, and the release of tumor necrosis factor-alpha and interleukin-1 beta.

Possible mechanisms were examined whereby welding fumes may elicit injury and inflammation in the lungs. The effects of different welding fumes on lung macrophages and on the in vivo production of two inflammatory cytokines, tumor necrosis factor-alpha (TNF-alpha), and interleukin-1 beta (IL-1 beta), were assessed. Fume was collected during flux-covered manual metal are welding using a stainless steel consumable electrode (MMA-SS) and gas metal are welding using a mild steel electrode (GMA-MS). For the in vitro study, bronchoalveolar lavage was performed on untreated rats to recover lung macrophages, and the effects of the welding fumes on macrophage viability and respiratory burst were examined. In vivo, additional rats were intratracheally instilled with the welding fumes at a dose of 1 mg/100 g body weight. These rats were lavaged 1, 14, and 35 days postinstillation, and indicators of lung damage (cellular differential, albumin. TNF-alpha and IL-1 beta release, and lactate dehydrogenase and beta-n-acetyl glucosaminidase activities) were measured. In vitro, the MMA-SS fume was more cytotoxic to the macrophages and induced a greater release of reactive oxygen species as measured by the respiratory burst compared to the GMA-MS fume. In vivo, evidence of lung damage was observed for both fumes 1 day postinstillation. By 14 days, lung responses to the GMA-MS fume had subsided and were not different from the saline vehicle control group. Significant lung damage was still observed for the MMA-SS group at 14 days, but by 35 days, the responses had returned to control values. One day after the instillations, both welding fumes had detectable levels of TNF-alpha and IL 1 beta within the lavage fluid. However, the MMA-SS particles caused a significantly greater release of both cytokines in the lavage fluid than did the GMA-MS group. The results demonstrate that MMA-SS fume caused more pneumoloxicity than GMA-MS. This increased response may reflect enhanced macrophage activation, the increased production of reactive oxygen species, as well as secretion of TNF-alpha and IL-1 beta.

Air Pollutants, Occupational↗

[Effects of laser welding on bond of porcelain fused cast pure titanium].

OBJECTIVE: To investigate the influence of the laser welding on bond of porcelain fused to cast pure titanium. METHODS: Twenty cast titanium plates were divided into two groups: laser welded group and control group. The low-fusing porcelain was fused to the laser welded cast pure titanium plates at fusion zone. The bond strength of the porcelain to laser welded cast pure titanium was measured by the three-point bending test. The interface of titanium and porcelain was investigated by scanning electron microscopy (SEM) and energy depressive X-ray detector (EDX). The non-welded titanium plates were used as comparison. RESULTS: No significant difference of the bond strength was found between laser-welded samples [(46.85 +/- 0.76) MPa] and the controls [(41.71 +/- 0.55) MPa] (P > 0.05). The SEM displayed the interface presented similar irregularities with a predominance. The titanium diffused to low-fusing porcelain, while silicon and aluminum diffused to titanium basement. CONCLUSIONS: Laser welding does not affect low-fusing porcelain fused to pure titanium.

Dental Casting Technique↗

Lung cancer risk and welding: results from a case-control study in Germany.

In a case-control study, 839 male hospital-based cases of primary lung cancer and the same number of population-based controls--matched by sex, age, and region of residence--were personally interviewed for their job and smoking histories. The study allows to quantify occupational asbestos exposure that was thought to be a welding-associated risk: 6% of cases and 2% of controls were classified into the occupational category "welders or burners# (odds ratio [OR] = 2.65). This OR was reduced to 1.93 (95% confidence limit [CL]: 1.03-3.61) after adjustment for smoking and asbestos. In contrast, a history of welding in general for at least a half-year is 28% among cases and 23% among controls, yielding an OR of 1.25 (95% CL: 0.94-1.65) after adjustment for both confounders. The OR of welding for more than 6,000 hr is 1.45 (95% CL = 1.04-2.02), reduced to 1.10 after adjustment for smoking and asbestos. Oxyacetylene welding for more than 6,000 hr lifelong is associated with an OR of 1.86 (95% CL = 1.01-3.43) reduced to 1.46 (n.s.) after adjustment for smoking and asbestos. The risk of oxyacetylene welding seems to be highest for oat cell carcinoma with an adjusted OR for ever-exposure of 1.46 (95% CL = 0.69-3.10). Therefore, the present study supports the hypothesis that some, but not all, of the excess risk of welders observed in the literature may be due to a history of cigarette smoking and occupational asbestos exposure. The elevated risk for the subgroup of employees in the aircraft industry reported for the midterm evaluation of the study still prevails, though no longer statistically significant. However, employees in this industry who ever welded show an OR of 2.29 (95% CL = 1.19-4.42) after adjustment for smoking and asbestos.

Adult↗