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Nitrogen isotope abundances in the recent solar wind.

Although lunar crystalline rocks are essentially devoid of nitrogen, the same is not true of the lunar regolith. The nitrogen contents of individual regolith samples (which can be as high as 0.012% by mass) correlate strongly with abundances of noble gases known to be implanted in the lunar surface by solar radiation, indicating that lunar regolith nitrogen is also predominantly of solar origin. The large variability in 15N/14N ratios measured in different regolith samples may thus reflect long-term changes in the isotopic composition of the solar radiation. But attempts to explain these variations have been hampered by the lack of any firm constraint on 15N/14N in the present solar wind. Here we report measurements of nitrogen isotopes from two lunar samples that have had simple (and relatively recent) exposure histories. We find that nitrogen implanted in the lunar surface during the past 10(5) to 5 x 10(7) years has a 15N/14N ratio approximately 40% higher than that in the terrestrial atmosphere, which is substantially lower than most previous estimates. This isotopic signature probably represents the best measure of 15N/14N in the present-day solar wind.

Extraterrestrial Environment↗

Constraints on the origin of the Moon's atmosphere from observations during a lunar eclipse.

The properties of the Moon's rarefied atmosphere, which can be traced through observations of sodium and potassium, provide important insights into the formation and maintenance of atmospheres on other primitive Solar System bodies. The lunar atmosphere is believed to be composed of atoms from the surface rocks and soil, which might have been sputtered by micrometeorites, by ions in the solar wind, or by photons. It might also form by the evaporation of atoms from the hot, illuminated surface. Here we report the detection of sodium emission from the Moon's atmosphere during a total lunar eclipse (which occurs when the Moon is full). The sodium atmosphere is considerably more extended at full Moon than expected--it extends to at least nine lunar radii--and its brightness distribution is incompatible with sources involving either solar-wind or micrometeorite sputtering. This leaves photon sputtering or thermal desorption as the preferred explanations for the lunar atmosphere, and suggests that sunlight might also be responsible for the transient atmospheres of other primitive bodies (such as Mercury).

Extraterrestrial Environment↗

A geochemical model for the formation of hydrothermal carbonates on Mars.

It is often argued that substantially more carbon dioxide and water were degassed from the martian interior than can be found at present in the atmosphere, polar caps and regolith. Calculations have shown that atmospheric escape cannot account for all of the missing volatiles. Suggestions that carbon dioxide is stored as marine or lacustrine deposits, are challenged by Earth-based and spacecraft remote-sensing data. Moreover, recent modelling of the martian atmosphere suggests that rainfall or open bodies of water are in any case unlikely to have persisted for extended periods of time. Hydrothermal carbonates therefore provide a possible solution to this dilemma. Using an accessible terrestrial system (Iceland) as a guide to the underlying processes, and a host rock composition inferred from the least-altered martian meteorite, we present a geochemical model for the formation of carbonates in possible martian hydrothermal systems. Our results suggest that an extensive reservoir of carbonate minerals--equivalent to an atmospheric pressure of carbon dioxide of at least one bar--could have been sequestered beneath the surface by widespread hydrothermal activity in the martian past.

Carbon Dioxide↗

Generation of lightning in Jupiter's water cloud.

Lightning is a familiar feature of storms on the Earth, and has also been seen on Jupiter and inferred indirectly to occur on Venus and Neptune. On Jupiter, lightning may be important as a source of energy to drive chemical reactions in the atmosphere, perhaps determining the abundances of molecules such as CO, HCN and C2H2. Lightning may be generated in Jupiter's water clouds by a mechanism similar to that which operates in terrestrial thunderstorms. Here we investigate the development of lightning by modelling the thunderstorm separation of electrical charge on precipitating ice particles at varying depths in Jupiter's atmosphere. We find that lightning can indeed be generated in the jovian water clouds, and that--in agreement with estimates from the analysis of Voyager images--it is most likely to occur at the 3- or 4-bar pressure level. Our model also predicts that a condensed-water abundance in the range of at least 1-2 g m-3 is required for lightning to occur in jovian thunderstorms--a prediction that may be tested when the Galileo probe arrives at Jupiter on 7 December 1995.

Electricity↗

Life on Mars?

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Extraterrestrial Environment↗

Substantial outgassing of CO from comet Hale-Bopp at large heliocentric distance.

When comet C/1995 O1 (Hale-Boop) was discovered, at a distance of seven astronomical units from the sun, it was more than one hundred times brighter than comet Halley at the same distance. A comet's brightness is derived from the reflection of sunlight from dust grains driven away from the nucleus by the sublimation of volatile ices. Near the sun, sublimation of water ice (a main constituent of comet nuclei) is the source of cometary activity; but at its current heliocentric distance, Hale-Boop is too cold for this process to operate. Other comets have shown activity at large distances, and in the case of comet Schwassmann-Wachmann 1, carbon monoxide has been detected in quantities sufficient to generate its observed coma. Here we report the detection of CO emission from Hale-Boop, at levels indicating a very large rate of outgassing. Several other volatile species were searched for, but not detected. Sublimation of CO therefore appears to be responsible for the present activity of this comet, and we anticipate that future observations will reveal the onset of sublimation of other volatile species as the comet continues its present journey towards the sun.

Carbon Monoxide↗

Infrared emission spectra of candidate interstellar aromatic molecules.

Interstellar dust is responsible, through surface reactions, for the creation of molecular hydrogen, the main component of the interstellar clouds in which new stars form. Intermediate between small, gas-phase molecules and dust are the polycyclic aromatic hydrocarbons (PAHs). Such molecules could account for 2-30% of the carbon in the Galaxy, and may provide nucleation sites for the formation of carbonaceous dust. Although PAHs have been proposed as the sources of the unidentified infrared emission bands that are observed in the spectra of a variety of interstellar sources, the emission characteristics of such molecules are still poorly understood. Here we report laboratory emission spectra of several representative PAHs, obtained in conditions approximating those of the interstellar medium, and measured over the entire spectral region spanned by the unidentified infrared bands. We find that neutral PAHs of small and moderate size can at best make only a minor contribution to these emission bands. Cations of these molecules, as well as much larger PAHs and their cations, remain viable candidates for the sources of these bands.

Extraterrestrial Environment↗

A galactic chimney in the Perseus arm of the Milky Way.

Galaxies are surrounded by large haloes of hot gas which must be replenished as the gas cools. This has led to the concept of galactic 'chimneys'--cavities in the interstellar medium, created by multiple supernova explosions, that can act as conduits for the efficient transport of hot gas from a galaxy's disk to its halo. Here we present a high-resolution map of atomic hydrogen in the Perseus arm of our galaxy, which shows clear evidence for the existence of such a chimney. This chimney appears to have been formed by the energetic winds from a cluster of young massive stars, and may currently have reached the stage of bowing out into the halo.

Astronomical Phenomena↗

Cosmological baryon density derived from the deuterium abundance at redshift z = 3.57.

The primordial ratio of deuterium to hydrogen nuclei (D/H), created as a result of the Big Bang, provides the most sensitive measure of the cosmological density of baryons. Measurements of the D/H ratio in the interstellar medium of our Galaxy place a strict lower limit on the primordial ratio, because processing of gas by stars reduces the abundance of deuterium relative to hydrogen. Absorption of radiation from distant quasars by intervening clouds of gas offers a means of probing D/H ratios at large redshifts, where the effects of stellar processing should be negligible. Measurements on one absorption system have indicated an extremely high primordial abundance ratio of 24 x 10(-5). Here we report a measurement of the D/H ratio in another high-redshift absorption system, and obtain a value that is an order of magnitude lower than that reported previously. The measured ratio of 2.3 x 10(-5) is consistent with that in the interstellar medium (after allowing for Galactic chemical evolution), and indicates that the absorption spectra on which the earlier estimates are based may have been subject to strong contamination. We calculate a baryon density that is 5% of the critical density required to close the Universe.

Astronomical Phenomena↗