Ice on the Moon boosts hopes for future lunar missions.
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HCN and chromophore formation on Jupiter.
The formation of HCN and chromophores are two of the major unsolved problems of the atmospheric chemistry of Jupiter. The question to be dealt with is the same in each case: how can these unsaturated organic compounds be formed in the highly reducing atmosphere (89% H2) present on Jupiter? The photolysis of ammonia/acetylene mixtures provides an answer to this question. Here we report the formation of both HCN and chromophores along with experimental data which support the premise that this photochemical process provides a route for the formation of both substances. It is not clear whether significant amounts of HCN are also formed by lightning on Jupiter.
Acetylene↗
Optical efficiencies of lightning in planetary atmospheres.
Spacecraft observations show that the presence of lightning activity is not confined to the terrestrial atmosphere, but is also found in the atmospheres of Venus, Jupiter and Saturn. Lightning activity may also occur in Titan's thick atmosphere. Calculations show that lightning produces a significant fraction of the nitric oxide that reacts with the ozone and chlorine compounds in the terrestrial stratosphere. In the atmosphere of the primordial Earth, lightning could have been the major source of many of the molecules required for the formation of life. To determine the effects of lightning activity in the atmospheres of other planets from spacecraft images requires a knowledge of the optical properties of the lightning discharge. Here we report the first simulations of lightning in planetary atmospheres by laser-induced plasmas. These simulations show that the fraction of the energy in lightning discharge channels that is radiated in the visible spectrum is similar for Earth, Venus and Titan, but quite different for Jupiter. One implication of our results is that the amount of trace gases produced by lightning in the jovian atmosphere must be larger than previously estimated.
Astronomy↗
High-temperature shock formation of N2 and organics on primordial Titan.
Titan's atmosphere is composed primarily of N2 with a little methane and other organic molecules. But theoretical models suggest that the initial form of nitrogen in Titan's atmosphere may have been NH3. We have investigated the possible importance of strong shocks produced during high-velocity impacts accompanying the late states of accretion as a method for converting NH3 to N2. To simulate the effects of an impact in Titan's atmosphere we have used the focused beam of a high-power laser, a method that has been shown to simulate shock phenomena. For mixtures of 10%, 50% and 90% NH3 (balance CH4) we obtained yields of 0.25, 1, and 6 x 10(17) molecules of N2 per joule, respectively. We also find that the yield of HCN is comparable to that for N2. In addition, several other hydrocarbons are produced, many with yields in excess of theoretical high-temperature-equilibrium models. The above yields, when combined with models of the satellite's accretion, result in a total N2 production comparable to that present in Titan's atmosphere and putative ocean.
Ammonia↗
The nature and origin of interstellar diamond.
Microscopic diamond was recently discovered in oxidized acid residues from several carbonaceous chondrite meteorites (for example, the C delta component of the Allende meteorite). Some of the reported properties of C delta seem in conflict with those expected of diamond. Here we present high spatial resolution analytical data which may help to explain such results. The C delta diamond is an extremely fine-grained (0.5-10 nm) single-phase material, but surface and interfacial carbon atoms, which may comprise as much as 25% of the total, impart an 'amorphous' character to some spectral data. These data support the proposed high-pressure conversion of amorphous carbon and graphite into diamonds due to grain-grain collisions in the interstellar medium although a low-pressure mechanism of formation cannot be ruled out.
Carbon↗
The rocky road to panspermia.
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Atmosphere↗
Impact erosion of the primordial atmosphere of Mars.
Abundant geomorphic evidence for fluvial processes on the surface of Mars suggests that during the era of heavy bombardment, Mars's atmospheric pressure was high enough for liquid water to flow on the surface. Many authors have proposed mechanisms by which Mars could have lost (or sequestered) an earlier, thicker atmosphere but none of these proposals has gained general acceptance. Here we examine the process of atmospheric erosion by impacts and show that it may account for an early episode of atmosphere loss from Mars. On the basis of this model, the primordial atmospheric pressure on Mars must have been in the vicinity of 1 bar, barring other sources or sinks of CO2. Current impact fluxes are too small to erode significantly the present martian atmosphere.
Atmosphere↗
Pre-biotic organic matter from comets and asteroids.
Several authors have suggested that comets or carbonaceous asteroids contributed large amounts of organic matter to the primitive Earth, and thus possibly played a vital role in the origin of life. But organic matter cannot survive the extremely high temperatures (>10(4) K) reached on impact, which atomize the projectile and break all chemical bonds. Only fragments small enough to be gently decelerated by the atmosphere--principally meteors of 10(-12)-10(-6) g--can deliver their organic matter intact. The amount of such 'soft-landed' organic carbon can be estimated from data for the infall rate of meteoritic matter. At present rates, only approximately 0.006 g cm-2 intact organic carbon would accumulate in 10(8) yr, but at the higher rates of approximately 4 x 10(9) yr ago, about 20 g cm-2 may have accumulated in the few hundred million years between the last cataclysmic impact and the beginning of life. It may have included some biologically important compounds that did not form by abiotic synthesis on Earth.
Atmosphere↗
Amino-acid synthesis in carbonaceous meteorites by aqueous alteration of polycyclic aromatic hydrocarbons
It has been suggested that amino acids and other organic compounds found in carbonaceous meteorites formed by aqueous alteration in the meteorite parent bodies. Observations of carbonaceous material in interstellar grains and interplanetary dust particles indicate that condensed organic compounds may have been present in meteorite parent bodies at the time of aqueous alteration. One group of compounds thought to be representative of this carbonaceous material is the polycyclic aromatic hydrocarbons (PAHs). Recently it was proposed that PAHs condense on SiC grains in the molecular envelopes of carbon-rich red-giant stars, which would allow for their subsequent incorporation into meteorite parent bodies during accretion. This incorporation mechanism is supported by the identification of SiC grains in carbonaceous chondrites. The possibility therefore exists that PAHs, and/or other condensed organic compounds, represent the starting material for aqueous alteration which leads to the formation of amino acids and other water-soluble organic compounds. Here we present calculations of the distribution of aqueous organic compounds in metastable equilibrium with representative PAHs as functions of the fugacities of O2, CO2 and NH3. The results reported here for pyrene and fluoranthene, two PAHs with different structures but the same stoichiometry, differ greatly but indicate that the formation of amino and carboxylic acids is energetically favourable at probable parent-body alteration conditions. The actual reaction mechanisms involved could be revealed by consideration of isotope data for PAHs, amino acids, other organic compounds and carbonates in carbonaceous chondrites.
Amino Acids↗
The interstellar chemistry of PAH cations.
Diffuse interstellar bands (DIBs) are mysterious absorption lines in the optical spectra of stars, and have been known for 75 years. Although it is widely believed that they arise from gas-phase organic molecules (rather than from dust grains) in the interstellar medium, no consensus has been reached regarding their precise cause. The realization that many emission features in astronomical infrared spectra probably arise from polycyclic aromatic hydrocarbons (PAHs), which may themselves be very abundant in the interstellar medium, has led to the suggestion that ionized PAHs might be the source of the DIBs. Laboratory investigations have revealed that small, positively charged PAHs in matrices have absorption features that bear some resemblance to DIBs, but no clear identification of any DIB with any specific PAH cation has yet been made. Here we report a laboratory study of the chemical reactivity of PAH cations (C6H6+, C10H8+ and C16H10+) in the gas phase. We find that these PAH cations are very reactive, and are therefore unlikely to survive in high abundances in the interstellar medium. Rather, such molecules will react rapidly with hydrogen, and we therefore suggest that the resulting protonated PAH cations (and species derived from them) should become the focus of future searches for a correspondence between molecular absorption features and the DIBs.
Cations↗
Evidence for a subsurface ocean on Europa.
Ground-based spectroscopy of Jupiter's moon Europa, combined with gravity data, suggests that the satellite has an icy crust roughly 150 km thick and a rocky interior. In addition, images obtained by the Voyager spacecraft revealed that Europa's surface is crossed by numerous intersecting ridges and dark bands (called lineae) and is sparsely cratered, indicating that the terrain is probably significantly younger than that of Ganymede and Callisto. It has been suggested that Europa's thin outer ice shell might be separated from the moon's silicate interior by a liquid water layer, delayed or prevented from freezing by tidal heating; in this model, the lineae could be explained by repetitive tidal deformation of the outer ice shell. However, observational confirmation of a subsurface ocean was largely frustrated by the low resolution (>2 km per pixel) of the Voyager images. Here we present high-resolution (54 m per pixel) Galileo spacecraft images of Europa, in which we find evidence for mobile 'icebergs'. The detailed morphology of the terrain strongly supports the presence of liquid water at shallow depths below the surface, either today or at some time in the past. Moreover, lower-resolution observations of much larger regions suggest that the phenomena reported here are widespread.
Extraterrestrial Environment↗
Geological evidence for solid-state convection in Europa's ice shell.
The ice-rich surface of the jovian satellite Europa is sparsely cratered, suggesting that this moon might be geologically active today. Moreover, models of the satellite's interior indicate that tidal interactions with Jupiter might produce enough heat to maintain a subsurface liquid water layer. But the mechanisms of interior heat loss and resurfacing are currently unclear, as is the question of whether Europa has (or had at one time) a liquid water ocean. Here we report on the morphology and geological interpretation of distinct surface features-pits, domes and spots-discovered in high-resolution images of Europa obtained by the Galileo spacecraft. The features are interpreted as the surface manifestation of diapirs, relatively warm localized ice masses that have risen buoyantly through the subsurface. We find that the formation of the features can be explained by thermally induced solid-state convection within an ice shell, possibly overlying a liquid water layer. Our results are consistent with the possibility that Europa has a liquid water ocean beneath a surface layer of ice, but further tests and observations are needed to demonstrate this conclusively.
Extraterrestrial Environment↗
Energy for microbial life on Europa.
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Carbon Dioxide↗
Supernova explosions in the Universe.
During the lifetime of our Milky Way galaxy, there have been something like 100 million supernova explosions, which have enriched the Galaxy with the oxygen we breathe, the iron in our cars, the calcium in our bones and the silicon in the rocks beneath our feet. These exploding stars also influence the birth of new stars and are the source of the energetic cosmic rays that irradiate us on the Earth. The prodigious amount of energy (approximately 10(51), or approximately 2.5 x 10(28) megatonnes of TNT equivalent) and momentum associated with each supernova may even have helped to shape galaxies as they formed in the early Universe. Supernovae are now being used to measure the geometry of the Universe, and have recently been implicated in the decades-old mystery of the origin of the gamma-ray bursts. Together with major conceptual advances in our theoretical understanding of supernovae, these developments have made supernovae the centre of attention in astrophysics.
Astronomical Phenomena↗
Formation of molecular gas in the tidal debris of violent galaxy-galaxy interactions.
In many gravitational interactions between galaxies, gas and stars that have been torn from the precursor galaxies can collect in tidal 'tails'. Star formation begins anew in some of these regions, producing tidal dwarf galaxies. Observations of these new galaxies provides insight into processes relevant to galaxy formation more generally, because the timescale of the interaction is well defined. But tracking the star formation process has hitherto been difficult because the tidal dwarf galaxies with young stars showed no evidence of the molecular gas out of which those young stars formed. Here we report the discovery of molecular hydrogen (traced by carbon monoxide emission) in two tidal dwarf galaxies. In both cases, the concentration of molecular gas peaks at the same location as the maximum in atomic-hydrogen density, unlike the situation in most gas-rich galaxies. We infer from this that the molecular gas formed from the atomic hydrogen, rather than being torn in molecular form from the interacting galaxies. Star formation in the tidal dwarf galaxies therefore appears to mimic the process in normal spiral galaxies like our own.
Astronomical Phenomena↗
Brimstone on mars.
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Extraterrestrial Environment↗
Discovery of calcium in Mercury's atmosphere.
The composition and evolutionary history of Mercury's crust are not well determined. The planet as a whole has been predicted to have a refractory, anhydrous composition: rich in Ca, Al, Mg and Fe, but poor in Na, K, OH, and S. Its atmosphere is believed to be derived in large part from the surface materials. A combination of effects that include impact vaporization (from infalling material), volatile evaporation, photon-stimulated desorption and sputtering releases material from the surface to form the atmosphere. Sodium and potassium have already been observed in Mercury's atmosphere, with abundances that require a volatile-rich crust. The sodium probably results from photon-stimulated desorption, and has a temperature of 1,500 K (ref. 10). Here we report the discovery of calcium in the atmosphere near Mercury's poles. The column density is very low and the temperature is apparently very high (12,000 K). The localized distribution and high temperature, if confirmed, suggest that the atmospheric calcium may arise from surface sputtering by ions, which enter Mercury's auroral zone. The low abundance of atmospheric Ca may indicate that the regolith is rarefied in calcium.
Atmosphere↗