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PubMed1998

Transient clouds in Titan's lower atmosphere.

The 1980 encounter by the Voyager 1 spacecraft with Titan, Saturn's largest moon, revealed the presence of a thick atmosphere containing nitrogen and methane (1.4 and approximately 0.05 bar, respectively). Methane was found to be nearly saturated at Titan's tropopause, which, with other considerations, led to the hypothesis that Titan might experience a methane analogue of Earth's vigorous hydrological cycle, with clouds, rain and seas. Yet recent analyses of Voyager data indicate large areas of super-saturated methane, more indicative of dry and stagnant conditions. A resolution to this apparent contradiction requires observations of Titan's lower atmosphere, which was hidden from the Voyager cameras by the photochemical haze (or smog) in Titan's stratosphere. Here we report near-infrared spectroscopic observations of Titan within four narrow spectral windows where the moon's atmosphere is ostensibly transparent. We detect pronounced flux enhancements that indicate the presence of reflective methane condensation clouds in the troposphere. These clouds occur at a relatively low altitude (15+/-10 km), at low latitudes, and appear to cover approximately 9 per cent of Titan's disk.

Atmosphere↗
PubMed1998

Heavy-element enrichment in low-density regions of the intergalactic medium.

Models for the composition of the diffuse intergalactic medium predict that low-density intergalactic gas at high redshift should be very poor in heavy elements. This is because locations of early star formation (and thus of heavy-element synthesis) and of gas delivery from such stars are located preferentially within higher-density regions of the intergalactic gas. Here we present a method for analysing carbon and oxygen absorption lines in quasar spectra that allows us to probe the heavy-element abundances at a redshift of three within low-density regions of intergalactic gas. We find that the ratio of triply ionized carbon to neutral hydrogen is roughly constant over a wide range of densities, and that, even as the density approaches zero, the ratio remains high. This unexpected enrichment of low-density gas in heavy elements suggests that early generations of small galaxies might be much more efficient at ejecting heavy elements into the intergalactic medium than has previously been thought.

Astronomical Phenomena↗
PubMed1998

Production of O2 on icy satellites by electronic excitation of low-temperature water ice.

The signature of condensed molecular oxygen has been reported in recent optical-reflectance measurements of the jovian moon Ganymede, and a tenuous oxygen atmosphere has been observed on Europa. The surfaces of these moons contain large amounts of water ice, and it is thought that O2 is formed by the sputtering of ice by energetic particles from the jovian magnetosphere. Understanding how O2 might be formed from low-temperature ice is crucial for theoretical and experimental simulations of the surfaces and atmospheres of icy bodies in the Solar System. Here we report laboratory measurements of the threshold energy, cross-section and temperature dependence of O2 production by electronic excitation of ice in vacuum, following electron-beam irradiation. Molecular oxygen is formed by direct excitation and dissociation of a stable precursor molecule, rather than (as has been previously thought) by diffusion and chemical recombination of precursor fragments. The large cross-section for O2 production suggests that electronic excitation plays an important part in the formation of O2 on Ganymede and Europa.

Cold Temperature↗
PubMed1998

Reflected infrared spectrum of a massive protostar in Orion.

The infrared source IRc2 in the star-forming region Orion-KL is generally believed to contain a massive and very young star. Its nature and evolutionary status, however, are difficult to determine because it is hidden from direct view by a dense disklike envelope of gas and dust. Here we report observations of infrared radiation (at a wavelength of about 2 microm) that has escaped the surrounding dust in the polar direction, perpendicular to the plane of the disk, and then been reflected towards us by dust farther away from the star. The reflected spectrum contains absorption lines of neutral metallic atoms and carbon monoxide, which we interpret as indicating a source temperature of about 4,500 K. But, given the luminosity of the source, its radius must be at least 300 solar radii-too large to be attained with the modest gas-accretion rates in existing theories of massive-star formation. Whether the infrared radiation is coming from the protostar itself or the self-luminous accretion disk around it, the accretion rate must be around (5-15) x 10(-3) solar masses per year, at least two orders of magnitude greater than is commonly assumed in models of star formation.

Astronomical Phenomena↗
PubMedDate not supplied

Carbon isotope composition of low molecular weight hydrocarbons and monocarboxylic acids from Murchison meteorite.

The origin of the organic matter in carbonaceous meteorites remains controversial despite extensive study over the past 20 yr. Motivated by the expectation that the patterns of isotopic variation with molecular structure among the organic compounds would contain important clues to their origin, we have measured the carbon isotopic compositions for individual hydrocarbons and monocarboxylic acids from Murchison meteorite, a C2 carbonaceous chondrite which fell in Australia in 1969. With few exceptions, notably benzene, the volatile products are substantially isotopically heavier than their terrestrial counterparts, signifying their extraterrestrial origin. For both classes of compounds, the ratio of 13C to 12C decreases with increasing carbon number in a roughly parallel manner, and each carboxylic acid exhibits a higher isotopic ratio than the hydrocarbon containing the same number of carbon atoms. These trends are consistent with the kinetically controlled synthesis of higher homologues from lower ones. The results suggest the possibility that the production mechanisms for hydrocarbons and carboxylic acids may be similar; they also impose constraints on the identity of the reactant species.

Carbon Dioxide↗
PubMed1984

A new interstellar molecule: tricarbon monoxide.

The cold dark interstellar Taurus Molecular Cloud One (TMC-1) is a rich source of acetylenic and polyacetylenic molecular species. As well as linear closed-shell molecules (H(C triple bond C)nCN) and symmetric rotors (CH3C triple bond CH, CH3C triple bond CCN), several radicals (C triple bond CH, C triple bond CCN, (C triple bond C2H) have also been identified, many of which had not been studied previously in the laboratory. Whether the observed abundances can be understood in terms of purely gas-phase ion-molecule chemical schemes, which produce reasonable agreement for the simplest polyatomic species, is unclear; alternative models involving the particulate interstellar grains as catalysts or sources have also been suggested. We now report the detection in TMC-1 of a new molecule, tricarbon monoxide (C3O), whose pure rotational spectrum has only very recently been studied in the laboratory. As C3O is the first known interstellar carbon chain molecule to contain oxygen, its existence places an important new constraint on chemical schemes for cold interstellar clouds. In fact, the observed abundance of tricarbon monoxide fits quite well into our model of galactochemistry.

Astronomical Phenomena↗
PubMed1998

Chemical processing in the coma as the source of cometary HNC.

The discovery of hydrogen isocyanide (HNC) in comet Hyakutake with an abundance (relative to hydrogen cyanide, HCN) similar to that seen in dense interstellar clouds raised the possibility that these molecules might be surviving interstellar material. The preservation of material from the Sun's parent molecular cloud would provide important constraints on the processes that took place in the protostellar nebula. But another possibility is that HNC is produced by photochemical processes in the coma, which means that its abundance could not be used as a direct constraint on conditions in the early Solar System. Here we show that the HNC/HCN ratio determined for comet Hale-Bopp varied with heliocentric distance in a way that matches the predictions of models of gas-phase chemical production of HNC in the coma, but cannot be explained if the HNC molecules were coming from the comet's nucleus. We conclude that HNC forms mainly by chemical reactions in the coma, and that such reactions need to be considered when attempting to deduce the composition of the nucleus from observations of the coma.

Cyanates↗
PubMedDate not supplied

Discovery of Jupiter's 'gossamer' ring.

Jupiter's ring system has previously been described as being composed of a 'bright' narrow ring and an interior, vertically-extended halo. The one image which reveals this morphology most clearly is Voyager 2's parting shot of the Jupiter system, a wide-angle (WA) view of the ring ansa in forward-scattered light (FDS 20693.02). The bright ring is plainly visible, and the halo appears after slight contrast enhancement. By further enhancement of this image we have discovered an additional ring, which is far fainter than either of the (already faint) components previously identified, extending to a radius of 210,000 km.

Astronomical Phenomena↗
PubMed1985

Recent progress and future plans on the search for extraterrestrial intelligence.

The possibility of life in other parts of the Universe has long occupied the human mind, but actual searches only began in 1960 with Project OZMA conducted by Frank Drake. In the past 25 years, we have made impressive progress, and this new field has gained broad scientific recognition including the support of the US and the Soviet National Academies, and the endorsement of the International Astronomical Union.

Astronomy↗
PubMedDate not supplied

D to H ratio and the origin and evolution of Titan's atmosphere.

A value of 1.7 x 10(-3) has been reported for the ratio of CH3D to CH4 in the stratosphere of the saturnian moon Titan. A lower value of 6 x 10(-4) for this ratio in the deeper part of Titan's atmosphere was reported by de Bergh et al. For comparison we note that the CH3D to CH4 ratio on Saturn and Jupiter is 8.7 x 10(-5) and 6.7 x 10(-5), respectively. We estimate the uncertainties in all these observations and data reduction to be about a factor of 2. Despite these uncertainties it appears that Titan's atmosphere is enriched in deuterium by a factor of > or = 3 relative to Jupiter and Saturn. Potential causative factors examined here for this enrichment are condensation to form tropospheric methane clouds, fractionation occurring over a hypothetical CH4-C2H6 ocean and between the ocean and the clathrate crust beneath, fractionation which occurred during the formation of Titan and fractionation occurring as a result of the evolution of Titan's atmosphere. We conclude that the greater part of the observed fractionation is probably derived from the formation of Titan and the subsequent evolution of Titan's atmosphere driven by photochemistry.

Deuterium↗
PubMed1986

Deuterium in the outer Solar System: evidence for two distinct reservoirs.

We have just completed a series of determinations of the CH3D/CH4 ratio in the atmospheres of Saturn, Titan and Uranus. These results, coupled with the work of other investigators, suggest that the Solar System contains at least two distinctly different primordial reservoirs of deuterium: that contained in gaseous hydrogen and that contained in the volatiles which have been maintained at low temperatures or isolated from hydrogen; for example, trapped in cold, solid material. Both of these reservoirs were established before the formation of the Solar System.

Atmosphere↗