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PubMed2006

Biodiesel production using anionic ion-exchange resin as heterogeneous catalyst.

The transesterification reactions of triolein with ethanol using various ion-exchange resin catalysts were conducted to produce ethyl oleate as a biodiesel. The anion-exchange resins exhibited much higher catalytic activities than the cation-exchange resin. The anion-exchange resin with a lower cross-linking density and a smaller particle size gave a high reaction rate as well as a high conversion. By combining the three-step regeneration method, the resin could be repeatedly used for the batch transesterification without any loss in the catalytic activity. A continuous transesterification reaction was carried out using an expanded bed reactor packed with the most active resin. The reactor system permitted the continuous production of ethyl oleate with a high conversion.

Anions↗
PubMed2005

Degradation of aqueous carbon tetrachloride by nanoscale zerovalent copper on a cation resin.

Nanoscale zerovalent copper supported on a cation resin was successfully synthesized to enhance the removal of carbon tetrachloride (CCl(4)) from contaminated water. The use of the cation resin as a support prevents the reduction of surface area due to agglomeration of nanoscale zerovalent copper particles. Moreover, the cation resin recycles the copper ions resulting from the reaction between CCl(4) and Cu(0) by simultaneous ion exchange. The decline in the amount of CCl(4) in aqueous solution results from the combined effects of degradation by nanoscale zerovalent copper and sorption by the cation resin; thus the amount of CCl(4) both in aqueous solution and sorbed onto the resin were measured. The pseudo-first-order rate constant normalized by the surface-area and the mass concentration of nanoscale zerovalent copper (k(SA)) was 2.1+/-0.1 x 10(-2)lh(-1)m(-2), approximately twenty times that of commercial powdered zerovalent copper (0.04 mm). Due to the exchange between Cu(2+) and the strongly acidic ions (H(+) or Na(+)), the pH was between 3 and 4 in unbuffered solution and Cu(2+) at the concentration of less than 0.1 mg l(-1) was measured after the dechlorination reaction. In the above-ground application, resin as a support would facilitate the development of a process that could be designed for convenient emplacement and regeneration of porous reductive medium.

Adsorption↗
PubMed2006

Resin characterization by electro-acoustic measurements.

The electro-acoustic effects, namely the ion vibration potential (IVP) and the colloidal vibration current (CVI), colloidal vibration potential (CVP) first described by P. Debye [P. Debye, J. Chem. Phys. 1 (1933) 13], are a result of charge separation of bound or free ions at different degrees by ultrasonic waves. Today commercial instruments are available to investigate liquid homogeneous and heterogeneous systems. In the present paper the application of this technique for the characterization of salts, protein solutions and resins for biochromatography is shown and valuable information about resins can be derived in a short time. Various resins were investigated with the following results: (1) the CVI magnitude is dependent of several parameters (such as particle size distribution, volume fraction, density difference); (2) the CVI is influenced by the surface modification of the resins. Polymeric modifications decrease the value of CVI. The CVI is generally lower for high capacity resins; (3) the measurement of the electro-acoustic effects can be used to detect small changes in resins. The CVI is dependent of the amount of adsorbed protein in "native" and denatured state.

Acoustics↗
PubMed2006

Tensile bond strength of dual curing resin-based cements to commercially pure titanium.

OBJECTIVES: The aim of this study was to evaluate the tensile bond strength of dual curing luting resin cements to commercially pure titanium at 10 min and 24h after removal of the oxide layer. METHODS: One hundred and twenty titanium discs were obtained by casting and polishing with silicon carbide papers. The titanium discs were sandblasted with 50 microm aluminum oxide, ultrasonic cleaned and bonded in pairs with the resin-based cements Panavia F and Rely X ARC at 10 min and 24h after the sandblasting. The tensile test was performed with a crosshead speed of 0.5mm/min in an Instron Universal testing machine. RESULTS: The Rely X ARC reached the highest tensile strength value at 24h after sandblasting (18.27 MPa), but there was no statistically significant difference between the two dual curing resin cements for both times tested. All specimens showed a mixture of cohesive fracture in the resin cement and adhesive failure. However, the predominant failure mode for Panavia F was cohesive in resin cement, and the Rely X ARC exhibited a greater proportion of specimens with adhesive failure between the alloy and resin luting cement at 10 min and 24h. SIGNIFICANCE: Both cements had, statistically, the same tensile bond strength. But in the fracture mode analysis, the adhesive predominant fracture mode of Rely X ARC cement indicates a premature clinical adhesive failure. On the other hand, the cohesive predominant fracture mode of Panavia F indicates a longer clinical adhesive bond with titanium.

Adhesiveness↗
PubMed2006

A new kinetic model for the photopolymerization shrinkage-strain of dental composites and resin-monomers.

OBJECTIVES: The aim of the study was to develop a new kinetic model for the shrinkage-strain rates of dental resin composites. The effect of filler content on the shrinkage-strain kinetics and degree of conversion of dental composites was also investigated. METHODS: A resin matrix containing 65 wt.% Bis-GMA and 35 wt.% TEGDMA was prepared. 0.5 wt.% camphorquinone and 0.5 wt.% dimethyl aminoethyl methacrylate were dissolved in the resin as photo-initiator system. Silanized glass fillers were added in different percentages to the resin-monomers. The shrinkage-strain of the specimens photopolymerized at circa 550 mW/cm2 was measured using the bonded-disc technique at 23, 37 and 45 degrees C for the matrix monomers and 23 degrees C for the composites. Initial shrinkage-strain rates were obtained by numerical differentiation of shrinkage-strain data with respect to time. Degree-of-conversion of the composites containing different filler contents was measured using FTIR spectroscopy. RESULTS: A new kinetic model was developed for the shrinkage-strain rate using the autocatalytic model of Kamal [Kamal MR, Sourour S. Kinetic and thermal characterization of thermoset cure. Polym Eng Sci 1973;13(1):59-64], which is used to describe the reaction kinetics of thermoset resins. The model predictions were in good agreement with the experimental data. The results also showed a linear correlation between the shrinkage-strain (and shrinkage-strain rate) and filler-volume fraction. The filler fraction did not affect the degree-of-conversion of the composites. SIGNIFICANCE: The rate of polymerization, determined via the shrinkage, being invariant with filler-fraction, suggests that only a relatively high filler-surface area, as may be obtained with nano-fillers, will affect the network-forming kinetics of the resin matrix.

Bisphenol A-Glycidyl Methacrylate↗
PubMed2007

Wear of composite resin veneering materials and enamel in a chewing simulator.

OBJECTIVES: The purpose of this in vitro study was to evaluate the wear of six composite resins for the veneering of crowns compared with the wear of human and bovine enamel, tested in a dual-axis chewing simulator. METHODS: Eight specimens of six different composite resins (Targis I+II, Solidex, BelleglassHP, Estenia, Solidex) and of human and bovine enamel were prepared. Steatite ceramic balls served as antagonistic specimens. Specimens were dynamically loaded in a dual-axis chewing simulator with 49 N up to 1,200,000 loading cycles with additional thermal cycling between 5 and 55 degrees C. After 120,000, 240,000, 480,000, 840,000 and 1,200,000 loading cycles, an impression of the specimens' surface and the antagonistic specimen was taken using a polyvinylsiloxane impression material. The substance loss at the surface was measured with computer-aided laser profilometry. Data were analyzed using ANOVA and the Tukey test. RESULTS: The wear of the ultra fine compact filled composite resins Solidex and BelleglassHP was not statistically significantly different from that of human enamel. The other composite resins and bovine enamel showed a wear statistically significantly higher than human enamel. SIGNIFICANCE: Comparing six composite resins for the veneering of crowns, ultra fine compact filled composite resins BelleGlassHP and Solidex showed a wear not significantly different from the wear of human and bovine enamel.

Animals↗
PubMed2006

Buffer salt effect on pH in the interior of an anion exchange resin.

The internal pH of Q Sepharose Fast Flow anion exchange resin in equilibrium with a bis-tris acetate buffer solution is investigated as a function of buffer salt concentration. Direct evidence of a resin phase pH shift is presented. At low buffer salt concentrations of 20 mM NaCl the resin phase pH is found to be as much as 1.1 pH units greater than that of the buffer phase, approaching to within 0.1 units of the buffer phase at salt concentrations greater than 250 mM. An ideal model with no adjustable parameters based on the Boltzmann distribution and the electroneutrality condition provides excellent agreement with experimental observations. The model assumes that small ions do not bind to the resin fixed charge sites and the agreement between the model predictions and observed resin internal pH suggests that strong electrolytes do not form ion pairs with the resin fixed charge sites.

Adsorption↗
PubMed2004

Determinants of in vitro gap formation of resin composites.

OBJECTIVES: To investigate whether polymerization shrinkage, flow, modulus, and bond strength influence marginal gap formation of resin composite restorations in vitro. METHODS: Eleven proprietary resin composites were studied. Shrinkage was measured by the 'bonded-disk method' (n=3). Flow was measured as the diameter of a constant volume of resin composite to which a load of 20 N had been applied for 60 s (n=3). Modulus was measured in 3-point bending (n=6). Bond strength mediated to human dentin by an adhesive system was measured in shear (n=6). Gap formation was measured in a light microscope along the margins of all-dentin, butt-joint cavities restored with the adhesive system and each resin composite and expressed as the widest gap in percent of the cavity diameter (n=6). RESULTS: Significant differences were found between the resin composites regarding all determined properties. A significant linear correlation was found between flow and gap formation (r=-0.68, P<0.025). Three-dimensional regression analysis showed a significant correlation between polymerization shrinkage (X(1)), flow (X(2)), and gap formation (r=0.79, P(1)<0.05, P(2)<0.005). The highest coefficient of correlation was found when the first part of the polymerization shrinkage (from 0 to 10 s) was disregarded (r=0.90, P(1)<0.005, P(2)<0.0005). CONCLUSIONS: With the adhesive system used, polymerization shrinkage and flow were found to be significant determinants of gap formation around resin composite restorations in vitro.

Analysis of Variance↗
PubMed2007

Resin strengthening of dental ceramics- the impact of surface texture and silane.

OBJECTIVES: To examine the effect of porcelain surface texture achieved utilising three clinically relevant surface preparation methods prior to silane and unfilled resin application on the flexure strength of a low fusing feldspathic porcelain. MATERIALS AND METHODS: Five hundred and forty dentine disc-shaped specimens (15.0mm diameter and 0.9mm thickness) were condensed, fired and allocated to 18 groups. Six groups were stored as-fired, six were alumina abraded and six were acid-etched. Samples were coated with silane, unfilled resin or both prior to bi-axial flexure testing. Group means were compared utilising a three factor design general linear model and post hoc all paired Tukey tests at P<0.05. Weibull analysis was employed to examine the reliability of the strength data. Profilometry was used to characterise the surface texture of the specimen surfaces. RESULTS: Alumina abraded and acid-etched specimens had significantly lower flexure strengths than the as-fired specimens. A significant difference between the degree of strengthening observed following unfilled resin application on the three surface texture investigated was observed (P<0.001). Silane application prior to resin coating resulted in no further significant increases in the mean bi-axial flexure strengths of the three surface textures. The as-fired surfaces had a low frequency of irregular amplitude defects, alumina abraded surfaces had an increased frequency of regular amplitude defects whilst the acid-etched surface consisted of an increased frequency of irregular amplitude defects. CONCLUSION: The strengthening mechanism whilst dependent on surface texture was independent of defect severity. No significant strengthening occurred following silane priming suggesting that, for the unfilled resin utilised, the strengthening mechanism was not enhanced by improved resin-ceramic adhesion.

Acid Etching, Dental↗
PubMed2005

Kinetics study on separation of cadmium from tellurium in acidic solution media using ion-exchange resins.

The feasibility of using ion-exchange resins to separate cadmium from tellurium in acidic solutions of the two metals was investigated. We studied the competitive adsorption of cadmium and tellurium in such resins under varying acid strengths and contact time. We found that low sulfuric acid strength (i.e., 0.5 M) was most effective in removing cadmium from solutions. Different ion-exchange resins were tested for their affinity for cadmium and tellurium ions. In the selected systems, the ion-exchange rate of cadmium was rapid in the first 20 min, and reached equilibrium within 2 h. The Lagergren first-order model described the kinetic data with high coefficient of determination and correlation values. At room temperatures the ion-exchange for cadmium onto the resin followed the Freundlich isotherm model. The maximum removal of cadmium obtained from batch studies using resin A was 91%. Column studies with the same resin showed a removal of cadmium of 99.99% or higher.

Adsorption↗
PubMed2006

Adsorption of MTBE from contaminated water by carbonaceous resins and mordenite zeolite.

Equilibrium and kinetic adsorption of methyl tert-butyl ether (MTBE) onto two carbonaceous resins and one zeolite was elucidated in this study. The Freundlich isotherm is adequate for describing the adsorption equilibrium of MTBE onto all the tested adsorbents in deionized water and natural waters. The resins of Ambersorb 563 and 572 have the highest adsorption capacity and almost twice the capacity of mordenite in deionized water. A different extent of NOM competition with MTBE was found for the carbonaceous resins in natural waters. For mordenite, no competitive adsorption was observed in natural water. The ideal adsorbed solution theory combined with equivalent background compound (IAST-EBC) model successfully described and predicted the adsorption of MTBE onto the carbonaceous resins in natural waters. The pore diffusion and micropore diffusion model fit the experimental data fairly well and successfully predicted the transport of MTBE within the adsorbent under different operating conditions. The small tortuosity factor between 1.2 and 2.3 of the resins for the diffusion of MTBE was observed, indicating a superior transport property for the carbonaceous resins in natural waters. The intracrystalline diffusivity of MTBE in natural water was much slower than that in deionized water, only 1/10 in STL and 1/3 in FS natural water, since the aperture entrances of mordenite was appreciably hindered by NOM.

Adsorption↗
PubMed2005

Concentration of polychlorinated biphenyls (PCBs) in beached resin pellets: variability among individual particles and regional differences.

Concentrations of polychlorinated biphenyls (PCBs) in beached resin pellets were examined to reveal variability between individual particles and differences among beaches. Fifty-five resin pellets from a beach in Tokyo were individually analyzed for PCBs, and showed concentrations ranging from <28 to 2,300 ng/g. This indicates that concentrations are highly variable between particles. Among several characters, discoloration (e.g., yellowing) had a positive relationship with PCB concentration: discolored pellets contained more PCBs than others on most of the beaches sampled. Given the color-selective ingestion of food by some organisms, this may be ecotoxicologically important. Measurements of samples from 47 beaches in Japan showed regional differences in PCB concentrations in resin pellets consistent with those in mussels. Sporadic high concentrations of PCBs were also found in pellets from remote islands, suggesting that resin pellets could be the dominant route of exposure to the contaminants at remote sites. The similarity of PCB concentrations between resin pellets and mussels suggests a potential use of resin pellets to monitor pollution in seawater.

Bathing Beaches↗
PubMed2004

Effect of chemical disinfectants on the transverse strength of heat-polymerized acrylic resins submitted to mechanical and chemical polishing.

STATEMENT OF PROBLEM: Immersion in chemical solutions used for cleansing and disinfecting prostheses can decrease the strength of denture base resins, making them more prone to fracture during use. PURPOSE: The purpose of this study was to assess the effect of immersion in different chemical disinfectants for varying time periods on the transverse strength of 3 mechanically or chemically polished heat-polymerized acrylic resins. MATERIAL AND METHODS: A total of 630 rectangular specimens (65 x 10 x 3 mm), 210 per resin (Classico, Lucitone 550, and QC-20), were fabricated. One side of each specimen was not polished and the other was either mechanically (n=300) or chemically (n=300) polished, and immersed for 10, 20, 30, 45, or 60 minutes in either 1%, 2.5%, or 5.25% sodium hypochlorite or 2% glutaraldehyde. Mechanically polished (n=15) and chemically polished (n=15) control specimens were immersed only in distilled water. The transverse strength (N/mm 2 ) was tested for failure in a universal testing machine, at a crosshead speed of 5 mm/min. Data were statistically analyzed using 2-way ANOVA and Student t test. Multiple comparisons were performed using Tukey and Scheffe tests (alpha=.05). RESULTS: There was significant difference (P < .01) between types of polishing, with chemical polishing resulting in lower transverse strength. ANOVA identified significant differences (P < .01) in strength between mechanically polished Lucitone 550 and QC-20, and among all 3 chemically polished resins. No significant differences were observed between resins submitted to both types of polishing or between different immersion periods (10 to 60 minutes), disinfectants, or interaction. CONCLUSIONS: Lucitone 550 resin presented the greatest transverse strength values with both types of polishing. Among the mechanically and chemically polished specimens, transverse strength was not affected after immersion in the disinfectants for the immersion periods tested (10 to 60 minutes). Chemically polished control and experimental (immersed in all solutions) QC-20 specimens showed significant differences in transverse strength values.

Acrylic Resins↗
PubMed2006

Influence of acrylic resin polymerization methods and saliva on the adherence of four Candida species.

STATEMENT OF PROBLEM: There is limited information on the role of polymerization methods and saliva on the adherence of pathogenic Candida species, with the exception of the adherence of Candida albicans to acrylic resins and the relation of this to surface roughness and surface free energy, which appear to play a major role in the initial phases of microorganism adhesion. PURPOSE: This study evaluated the influence of polymerization methods and human whole saliva on the adherence of Candida species to acrylic resin surfaces. MATERIAL AND METHODS: Acrylic resin specimens (n=256) measuring 2.5 x 1.2 x 0.2 cm were heat (Classico) or microwave (OndaCryl) polymerized and evaluated for surface roughness using a profilometer, and for surface free energy by measuring the contact angle of a sessile drop of water. For the adherence assay, specimens of each acrylic resin were divided by lottery into 8 groups, according to whether they were exposed to human saliva or not (control), and to 1 of the 4 following suspensions: C albicans, Candida tropicalis, Candida dubliniensis, or Candida glabrata (1 to 5 x 10(6) cells/mL). Adhered yeasts were counted using an optical microscope at x400 magnification. Data were analyzed by 3-way ANOVA and the Tukey honestly significant difference test (alpha=.05). RESULTS: No statistical difference was found for roughness (P=.156), whereas higher surface free-energy values were found for the heat-polymerized acrylic resin (P=.0013). The overall adherence of Candida species was significantly decreased by human saliva (P<.001). CONCLUSION: Within the limitations of this study, saliva was capable of reducing the adherence of Candida species, whereas roughness and free energy did not influence the adherence rates. CLINICAL IMPLICATIONS: As growth on surfaces is a natural part of the Candida lifestyle, its colonization in denture users may be expected. The presence of human whole saliva, however, decreased the overall yeast adherence to the acrylic resin surface, whereas surface roughness and free energy did not interfere with the adherence of Candida species.

Acrylic Resins↗
PubMed2004

Raman spectroscopic analysis of a tembetá: a resin archaeological artefact in need of conservation.

The Raman spectroscopic analysis of a Brazilian tembetá, a lip-plug which signifies the attainment of manhood in tribal cultures, and dated to about 1600 years BP is reported. Tembetá are usually made of wood or stone but this lip-plug is very rare in that it is made of resin, which has been severely degraded in the burial environment; the brownish-red fragmented remains are in an extremely fragile condition and information about the chemical composition was required before urgent conservation was undertaken. Raman spectra excited at 1064 nm showed the presence of triterpenoid materials in the main body of the artefact, and indicated that the red-brown coating was not iron(III) oxide as suspected but rather degraded resin. Comparison with contemporary resins has facilitated the partial identification of the material in this important artefact as a triterpenoid-rich material, which is closely similar to the Pistacia species. A possible archaeological link to the Jatobá do Cerrado (Hymenaea stigonocarpa Mart.) resin has been excluded as the Raman spectra of this resin specimen and the tembetá do not match; indeed, the Jatobá do Cerrado resin specimen belongs to a diterpenoid-rich classification as befits its Hymenaea species.

Archaeology↗
PubMed1998

Photoelastic stress analysis in a pier retainer of an anterior resin-bonded fixed partial denture.

STATEMENT OF PROBLEM: A clinical situation may arise with 2 edentulous spaces and a single intact pier tooth. A dentist may restore these edentulous spaces with a long span resin-bonded fixed partial denture using the pier and the 2 terminal abutments for bonding. PURPOSE: This study analyzed the stresses induced in a pier retainer of an anterior resin-bonded fixed partial denture and determined the effect on a pier abutment. MATERIAL AND METHODS: Photoelastic materials were selected to represent the relative stiffness of 3- and 5-unit resin-bonded fixed partial dentures. The models were scaled to x2.5 to enhance visual analysis of the stress pattern. RESULTS: Isochromatic fringes indicated a stress magnitude at the proximolingual areas of the pontic in the 3-unit resin-bonded fixed partial denture. In the 5-unit resin-bonded prosthesis, the stress pattern appeared to involve the entire surface of the pier retainer. CONCLUSION: The use of pier abutments should be avoided and it is more favorable to use 3-unit resin-bonded fixed partial dentures.

Dental Abutments↗
PubMed1998

In vitro mechanical property comparison of four resins used for fabrication of provisional fixed restorations.

PURPOSE: This study recorded and compared the flexural elastic moduli and moduli of rupture of four materials (Provipont DC resin, Triad provisional restorative material, Jet acrylic resin, and a 50:50 mixture of Jet acrylic resin and orthodontic resin) used to make provisional restorations. MATERIAL AND METHODS: Thirty-nine identical 63 x 10 x 3 mm specimens were made from each of the four materials. After 24 hours, 30 days, and 60 days of water storage at 37 degrees C (13 specimens each), standard three-point bend tests were conducted on an Instron universal testing machine at a crosshead speed of 0.5 cm/minute. Stress strain curves were generated, and values for the flexural elastic moduli and moduli of rupture were calculated. Data were subjected to two-way and one-way analyses of variance (alpha = 0.05). RESULTS: Provipont DC resin exhibited significantly higher flexural elastic moduli and moduli of rupture values at the 24-hour test time. However, Provipont DC resin exhibited the greatest decrease in these values over time.

Acrylic Resins↗
PubMed1998

Comparison of a new autocuring temporary acrylic resin with some existing products.

STATEMENT OF PROBLEM: Some problems of the self-curing or autopolymerizing resins may include color instability and dimensional inaccuracy. PURPOSE: This study compared the color and dimensional stability of the new autopolymerizing resin Unifast II, which combines a new activator with some existing products. RESULTS: The change in color (delta E value) of Unifast II resin was less than that demonstrated for four autopolymerizing resins (Unifast, Curefast, ADFA, and MIKY). Unifast II did not exhibit color change when stored in conditions below 37 degrees C. Unifast II also had a significantly better fit than the other four autopolymerizing resins (p < 0.01). No significant differences in transverse strength were observed among Unifast II, Unifast, and ADFA, but the Unifast II autopolymerizing resin maintained its color stability and dimensional accuracy without sacrificing its transverse strength.

Acrylic Resins↗