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Hazardous solid wastes generated in the cleanup of air and water.

Air and water pollution control programs sometimes result in production of solid wastes that are difficult to manage. The sludges from sewage treatment plants and flue gas scrubbers are two examples. In many coastal communities, there is no alternative to ocean dumpling of sewage sludges for the foreseeable future. The use of sludges as soil conditioners, their conversion to fuels by pyrolysis, and other alternatives are frequently mentioned options, but they have not been demonstrated to be practical on a large scale. The Federal requirement that ocean dumping be terminated by 1981 presents the large seaboard population centers with a dilemma, due to the absence of economically feasible alternative methods of disposal. Another major solid waste problem is arising from the Federal policy that requires flue gas desulfurization on practically all power plants. This policy, designed to reduce sulfur oxide emissions, will require that vast quantities of sludge be stored. Their environmental impact is as yet not fully evaluated. Commercial use of the sulfur or sulfates produced in these processes may be possible, but its practicability on a large scale remains to be demonstrated.

Air Pollution↗

Hazardous waste management; Environmental Protection Agency. Final rule.

The Resource Conservation and Recovery Act, as amended, provides for the development and implementation of a comprehensive program to protect human health and the environment from the improper management of hazardous waste. A fundamental premise of the statute is that human health and the environment will best be protected by careful management of the transportation, treatment, storage, and disposal of hazardous waste, in accordance with standards developed under the Act. In today's Federal Register, the Environmental Protection Agency is publishing several documents setting in motion a series of events which will culminate in full implementation of the hazardous waste control program. This document sets forth definitions of words and phrases which appear in the subsequent Parts as well as general guidance for the use of these regulations and provisions which are generally applicable to all Parts.

Environmental Health↗

[Disposal of carcasses and rendering in the waste management program 1975 of the Federal Republic of Germany and hints for the practice of supervision by state veterinarians and operational self-control in rendering plants (author's transl)].

In the Waste Management Program 1975 of the German Federal Government the problems of disposal of animal carcasses and rendering were specially emphasized in the working group "Animal Residues". Besides a description of the entire situation, the reasons and the problems, measures for solving the problems are concurrently listed. For the practical supervision of rendering plants by the state veterinary officer and the operational self-control in such plants a questionnaire was prepared on the basis of the law in force, which can be used as a checklist.

Abattoirs↗

Novel and innovative pyrolysis and gasification technologies for energy efficient and environmentally sound MSW disposal.

Within the context of European Union (EU) energy policy and sustainibility in waste management, recent EU regulations demand energy efficient and environmentally sound disposal methods of Municipal Solid Waste (MSW). Currently, landfill with its many drawbacks is the preferred option in the EU and many other industrialised countries. Within the waste management hierarchy thermal disposal especially incineration is a viable and proven alternative. But, the dominating method, mass-burn grate incineration has drawbacks as well particularly hazardous emissions and harmful process residues. In recent years, pyrolysis and gasification technologies have emerged to address these issues and improve the energy output. To keep the many players in the field comprehensively informed and up-to-date, novel and innovative technology approaches emphasising European developments are reviewed.

Conservation of Energy Resources↗

Oceanographic studies off Beypore Port, west coast of India to locate a dredge dumping site.

This study presents the salient results of the oceanographic investigations carried out along the west coast of India to locate a dumping site for the dredged material generated from the capital of the proposed development of the all weather port. Based on the results of movement of disposed material obtained from a 2 dimensional coastal circulation model and considering the possibility of having a navigational channel later on in line with the port, a dumping site is recommended at the 15 m water depth contour with coordinates: Latitude 11 degrees 07.00'; Longitude 75 degrees 45.60', where the environmental impacts on the ecosystem due to dumping operations is considered to be minimum.

Animals↗

A decision tree for selecting the most cost-effective waste disposal strategy in foodservice operations.

The purposes of this study were to determine costs of disposal strategies for wastes generated in foodservice operations and to develop a decision tree to determine the most cost-effective disposal strategy for foodservice operations. Four cases, including the central food processing center (CFPC) in a school district, a continuing-care retirement center (CCRC), a university dining center (UDC), and a commercial chain restaurant (CCR), were studied to determine the most cost-effective disposal strategy. Annual costs for the current and projected strategies were determined for each case. Results of waste characterization studies and stopwatch studies, interviews with foodservice directors, and water flow and electrical requirements from manufacturers' specifications were used to determine cost incurred. The annual percentage increases for labor, fees, and services were used to reflect an inflated economic condition for the ensuing 10 years of the study period. The Net Present Worth method was used to compare costs of strategies, and the multiparameter sensitivity analysis was conducted to examine the tolerance of the chosen strategy. The most cost-effective strategy differed among foodservice operations because of the composition of food and packaging wastes, the quantity of recyclable materials, the waste-hauling charges, labor costs, start-up costs, and inflation rate. For example, the use of a garbage disposal for food waste and landfills and recycling for packaging waste were the most cost-effective strategies for the CCRC. A decision tree was developed to illustrate the decision-making process that occurs when conducting cost analysis and subsequent decisions. Dietetics practitioners can use the decision tree when evaluating the results of the cost analysis.

Cost-Benefit Analysis↗

Future trends which will influence waste disposal.

The disposal and management of solid wastes are ancient problems. The evolution of practices naturally changed as populations grew and sites for disposal became less acceptable. The central search was for easy disposal at minimum costs. The methods changed from indiscriminate dumping to sanitary landfill, feeding to swine, reduction, incineration, and various forms of re-use and recycling. Virtually all procedures have disabilities and rising costs. Many methods once abandoned are being rediscovered. Promises for so-called innovations outstrip accomplishments. Markets for salvage vary widely or disappear completely. The search for conserving materials and energy at minimum cost must go on forever.

Animal Feed↗

Technoeconomic and environmental assessment of industrial organotin compounds.

Current uses of organotins include heat stabilizers for polyvinyl chloride (PVC), catalysts for polyurethane foam and silicone rubber, biocides, and animal health products. Domestic production consumption in 1982 is about 28 million pounds, and overall growth is estimated at 7 percent per year. Physical properties of organotins, including solubility in water, octanol-water partition coefficients, and Freundlich adsorption isotherm constants, are not well characterized. Analytical methods for tin in environmental and biological matrices involve concentration, separation, and identification by chromatography, spectrometry, and spectroscopy. Environmental fate and effects of organotins are not well understood. Degradation reactions may yield a complex set of products, including inorganic tin oxide. The effects of exposure of workers and release of organotins to the environment at point sources have been documented. Nonpoint sources of environmental exposure include discard and sanitary landfill disposal of plastics and direct release of biocides to aquatic or marine environments. Other dissipative uses of organotins which pose potential human risk include PVC food wrapping and bottles and rigid potable water pipe. The long term health effects of low level exposure to organotins are not known. Toxic metal cycling in the environment, including biomethylation of inorganic tin by naturally occurring bacteria, is of rising concern.

Chemical Phenomena↗

Reduction of metal leaching in brown coal fly ash using geopolymers.

Current regulations classify fly ash as a prescribed waste and prohibit its disposal in regular landfill. Treatment of the fly ash can reduce the leach rate of metals, and allow it to be disposed in less prescribed landfill. A geopolymer matrix was investigated as a potential stabilisation method for brown coal fly ash. Precipitator fly ash was obtained from electrostatic precipitators and leached fly ash was collected from ash disposal ponds, and leaching tests were conducted on both types of geopolymer stabilised fly ashes. The ratio of fly ash to geopolymer was varied to determine the effects of different compositions on leaching rates. Fourteen metals and heavy metals were targeted during the leaching tests and the results indicate that a geopolymer is effective at reducing the leach rates of many metals from the fly ash, such as calcium, arsenic, selenium, strontium and barium. The major element leachate concentrations obtained from leached fly ash were in general lower than that of precipitator fly ash. Conversely, heavy metal leachate concentrations were lower in precipitator fly ash than leached pond fly ash. The maximum addition of fly ash to this geopolymer was found to be 60wt% for fly ash obtained from the electrostatic precipitators and 70wt% for fly ash obtained from ash disposal ponds. The formation of geopolymer in the presence of fly ash was studied using 29Si MAS-NMR and showed that a geopolymer matrix was formed. X-ray diffraction (XRD) analysis and scanning electron microscopy (SEM) imaging showed the interaction of the fly ash with the geopolymer, which was related to the leachate data and also the maximum percentage fly ash addition.

Carbon↗

A multiattribute utility analysis of alternative sites for the disposal of nuclear waste.

Five potential sites nominated for the Nation's first geologic repository for disposing of nuclear waste are evaluated using multiattribute utility analysis. The analysis was designed to aid the Department of Energy in its selection of 3 sites for characterization, a detailed data-gathering process that will involve the construction of exploratory shafts for underground testing and that may cost as much as $1 billion per site. The analysis produced insights into the relative advantages and disadvantages of the nominated sites and clarified current uncertainties regarding repository performance.

Decision Making↗

Sources and fate of polychlorinated dibenzodioxins, dibenzofurans and related compounds in human environments.

Several of the major incidents resulting in potential human exposures to polychlorinated dibenzodioxins (PCDDs) and/or polychlorinated dibenzofurans (PCDFs), polychlorinated biphenyls (PCBs) and related compounds which have occurred in the U.S. in recent periods have resulted from improper disposal of hazardous chemical wastes. Prominent examples of such environmental contamination episodes are the Love Canal, into which ton quantities of chlorinated organic compounds containing substantial concentrations of 2,3,7,8-tetrachlorodibenzo-p-dioxin (TCDD) were deposited; numerous sites in the State of Missouri which were contaminated by the dumping of chlorinated organic wastes containing various PCDDs and possibly PCDFs, and PCBs; and the environs of a 2,4-D/2,4,5-T manufacturing plant site in Arkansas, which were contaminated with PCDDs. Environmental assessments of such sites have revealed extensive contamination of soils, waterways, fish and other biological species with these toxic compounds, which in turn could lead to human exposures. Other recently identified sources of PCDDs, PCDFs and related compounds in human environments include stack effluents from municipal refuse incineration, and fires and explosions involving electrical devices containing PCBs and polychlorinated benzenes. Data obtained in assessments of such incidents are presented, and the implications of these findings with respect to the distribution and persistence of PCDDs, PCDFs and related chemicals in the environment and possible effects on humans are discussed.

Accidents↗

[Parameters of physical and mental development of children and adolescents residing near enterprise for radioactive waste processing and stationary storage].

Operation of enterprise for radioactive waste processing and disposal does not influence negatively physical and mental development of children and adolescents residing in the area under observation. In some parameters, physical and mental development of children and adolescents residing in the area under observation surpasses that in reference area--that could be due to social and economic peculiarities.

Adolescent↗

[On the development of carcasses disposal in Israel paying particular attention to the industrial slaughtering of poultry (author's transl)].

Although a regulation has been in force in Israel since 1930 which committed the communities to provide for knackers' yards, until some years ago packs of jackals took care of the carcass disposal. Owing to the increase of large slaughter houses for fowl some rendering plants were also erected, which however, eliminated only the waste from these plants. For this reason the government decided to build rendering plants on the European pattern and to legislate pertinent veterinary acts. In Israel 20,000 tons fish-meal is imported annually, worth millions of dollars for feeding purposes, while no attention is as yet being paid to the processing of the national raw materials.

Abattoirs↗

Biogas production from crop residues on a farm-scale level in Sweden: scale, choice of substrate and utilisation rate most important parameters for financial feasibility.

Anaerobic digestion would enable the energy potential of agricultural crop residues such as ley crops and sugar beet tops to be harnessed in Sweden. In the present study, the financial prospects of single-stage fed-batch high-solids digestion on three different scales, 51, 67, and 201 kW, were calculated on the basis of experimental results and observations. In addition to scale, the effects of methane yield and fertiliser recovery (compared to green manuring) was investigated by testing different substrate mixtures. The biogas was disposed as heat, combined heat and power, or as vehicle fuel. Besides the positive effect of scale, the results indicate the importance of choosing substrates with a high methane yield and high nitrogen content, and the necessity of fully utilising both the capacity of the equipment installed and the energy carriers produced. Net unit costs of 5.3 and 8.1 ct/kWh were achieved (201 kW), heat and vehicle fuel, respectively.

Anaerobiosis↗

Effects of limestone addition and sintering on heavy metal leaching from hazardous waste incineration slag.

Hazardous waste incineration (HWI) in rotary kilns and the disposal of the residual slag on landfills play an important role in German waste treatment. In order to save disposal costs the elution behaviour of HWI-slag should be further optimised. Quality-improved slag may be disposed off on cheaper landfill sites still applying to landfill regulations. In a new process-integrated approach hazardous waste is mixed with limestone, which initiates chemical reactions with heavy metals in the rotary kiln yielding new compounds of different solubility. In this work HWI-slag/limestone mixtures are thermally treated and then examined by elution tests. Experimental data indicate that the heavy metals pertinent to landfill class assignment of a HWI-slag share a solubility minimum at a CaO-content of about 15%. Such improved HWI-slags are allowed to be disposed off on cheaper landfill sites. Furthermore, a new combination of thermodynamic calculation methods is applied to predict heavy metal solubility for different process conditions. Used models hold the opportunity to explain the tendencies of heavy metal leaching and propose plausible chemical reactions. With it, a new tool to examine the impact of temperature treatment and slag composition on heavy metal elution from HWI-slag is presented.

Calcium Carbonate↗

Immobilization and geological disposal of nuclear fuel waste.

The Canadian Nuclear Fuel Waste Management Program is developing methods for the safe disposal of both used nuclear fuel and fuel recycle waste. The disposal strategy is based on interim storage of the used fuel, immobilization of either used fuel or recycle waste, and disposal, deep in a stable geological formation in the Canadian Shield. The disposal concept proposes a multibarrier system to inhibit the release of the radioactive waste from the disposal vault. The principal components of the multibarrier system are (i) the waste form in which the radionuclides are immobilized, (ii) engineered barriers including high integrity containers, buffers and backfills designed to retard the movement of groundwaters in the disposal vault, and (iii) the natural barrier provided by the massive geological formation itself. The research programs to investigate this concept are discussed briefly. Several different waste forms are being developed for the immobilization of high-level fuel recycle waste, including glass, glass-ceramics and crystalline materials. Dissolution of these materials in groundwater is the only likely scenario that could lead to radionuclide release. The factors that influence the aqueous dissolution behaviour of these materials are reviewed.

Ceramics↗

[Factors contributing to endemic cholera in Douala, Cameroon].

Cholera has been endemic in Douala, Cameroon since 1971. A number of environmental factors favourize the survival of the Vibrio in Douala including location at the mouth of Wouri delta on the Atlantic Ocean, sandy clay soil, shallow dirty polluted foul-smelling groundwater, presence of vast expanses of swamp, streams/drainage ditches infested with algae, and high temperatures with low rainfall and drought during certain periods of the year. Most outbreaks have started in Bepanda, a slum area built on a garbage dump in a swampy zone fed by drainage ditches carrying the faecal pollution from neighbouring upstream districts. It is a densely overcrowded area of uncontrolled urbanization generated by the influx of poor city new-comers who live without adequate access to clean water or basic sanitary facilities. The most affected areas are those resulting from recent unregulated urban sprawl in polluted swamp zones or garbage dumps. Since access to the public water system is inadequate with only 65000 persons connected for 3 million inhabitants, dwellers in most areas must take water from the 70000 urban wells (estimated in 2004) that are often not more than 1.5 m deep. Sewage facilities are insufficient to provide complete evacuation of solid and liquid waste. The network of rivers, streams and man-made ditches waste are poorly maintained and often overflow during the rainy season. The contents of latrines are often discharged directly into the environment. Social factors such as the reformation of urban tribes and persistence of traditional attitudes toward waste disposal and water use have not only led to high-risk behaviour but also created barriers to sanitation and hygiene education. With an inadequate sanitation inspection system, a large but purely accessible public health system and a highly disorganized private health sector exists, effective preventive measures are difficult to implement. The combination of these factors probably account for the endemicity of cholera in Douala.

Cameroon↗

Stabilization/solidification of waste ferrous sulphate from titanium dioxide production by fluidized bed combustion product.

A treatment procedure to allow the disposal of waste ferrous sulphate was developed. This waste contains sulphuric acid and originates from titanium dioxide production. The process is based on simultaneous neutralization and stabilization/solidification (S/S) of the waste by means of fluidized bed combustion product (FBC-P). The prepared stabilized waste specimens have a solid matrix and their batch leachates display practically neutral pH and also satisfactory conductivity values. The leachate composition is notable in its absence of toxic metals and even iron.

Coloring Agents↗