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At least 109 records · Page 6Linked to original sources

Determination of odor active aroma compounds in freshly cut leek (Allium ampeloprasum Var. bulga) and in long-term stored frozen unblanched and blanched leek slices by gas chromatography olfactometry analysis.

The odor active compounds in freshly cut leek slices and in blanched and unblanched leek slices stored for 12 months were investigated by a detection frequency method. Fifteen judges were evaluating the three samples randomized. The most important aroma compounds in the freshly cut leek slices were dipropyl disulfide, methyl propenyl disulfide, pentanal, decanal, and propyl propenyl disulfide in order of priority. When stored frozen and unblanched for 12 months, the aroma composition changed and the most important compounds became pentanal, decanal, 2,5-dimethyl furan, unknown compound I, and dipropyl disulfide. Blanching before freezing prevented to some degree these changes but also reduced the perceived intensity of the aroma compounds. The most important aroma compounds in the blanched sample were dipropyl disulfide, unknown compound I, pentanal, 2,5-dimethyl furan, and propyl propenyl disulfide.

Allium↗

Solid-phase microextraction and gas chromatography olfactometry analysis of successively diluted samples. A new approach of the aroma extract dilution analysis applied to the characterization of wine aroma.

The relationship between the composition and the aroma of the wine can be established by using gas chromatography with olfactometric detection (sniffing or GCO), which combines the chromatographic response with the human nose response. To evaluate the contribution of the odor compounds in wine aroma, we designed a new approach of the aroma extract dilution analysis (AEDA) that lies in the GCO analysis of serially diluted wine samples using headspace solid-phase microextraction (HS-SPME) as the extraction technique. The fiber coating used was Flex divinyl-carboxen-polydimethylsiloxane. The method developed was applied to determine the aromatic composition of a red Grenache wine from Priorat (Spain). The method allows 38 important odorants to be determined in the AEDA study, 30 of them precisely identified. These results are similar to those reported by other studies related to this variety of wine. HS-SPME is a suitable technique to obtain representative extracts of wine aroma with several advantages such as simplicity, speediness, and little sample manipulation.

Chromatography, Gas↗

Odor intensity evaluation in gas chromatography-olfactometry by finger span method.

This paper describes the potential of evaluating odor intensities in a gas chromatographic effluent by cross-modality matching with the finger span (GC-O-FSCM). A simple prototype is described that allows the precise measurement and acquisition of the distance between the thumb and another finger during the analysis. The stimulation of panelists at the sniffing port with ethyl butyrate shows a log-log relation between peak height values obtained from finger span and stimulus concentrations. It also shows that all panelists are able to perform this task but with different precision, which is used to select them. A triplicate evaluation by GC-O-FSCM of the intensity of flavor constituents in synthetic solutions shows that a four-member panel is perfectly able to determine most of the characteristics of the solutions and to create a finger span multidimensional space highly correlated with the theoretical intensity space.

Adult↗

Comparison of the most odor-active compounds in fresh and dried hop cones (Humulus lupulus L. variety spalter select) based on GC-olfactometry and odor dilution techniques.

Application of aroma extract dilution analysis on the volatiles obtained from dried cones of Spalter Select hops grown in the German hop-growing area of Hallertau revealed 23 odorants in the flavor dilution (FD) factor range of 16-4096, 20 of which could be identified. On the basis of high FD factors, trans-4, 5-epoxy-(E)-2-decenal, linalool, and myrcene were identified as the most potent odorants, followed by ethyl 2-methylpropanoate, methyl 2-methylbutanoate, (Z)-1,5-octadien-3-one, nonanal, (E,Z)-1,3, 5-undecatriene, 1,3(E),5(Z),9-undecatetraene, propyl 2-methylbutanoate, 4-ethenyl-2-methoxyphenol, and 1-octen-3-one. Ten of the high-impact hop aroma compounds had previously not been identified as hop constituents and, in particular, 1,3(E),5(Z), 9-undecatetraene has not yet been reported as a food odorant. In an extract obtained from fresh hops, in addition to the odorants found in dry hops, (Z)-3-hexenal was characterized as a further key odorant rendering an additional green aroma note to the fresh material.

Chromatography, Gas↗

Using olfactometry to measure intensity and threshold dilution ratio for evaluating swine odor.

Intensity and threshold dilution ratio are two important indices for odor control of swine buildings. Although odor threshold dilution ratio is a widely used index to describe an odor, it should be related to intensity to be more useful. A method was proposed to measure both indices simultaneously by using a dynamic forced-choice olfactometer. Four air samples were taken from each of four swine rooms including farrowing, finisher, gestation, and nursery. A panel of eight people was used to evaluate odor intensity. Odor threshold dilution ratios were calculated according to the American Society for Testing and Materials (ASTM) Standard Practice E679-91 to be 333, 424, 25, and 221 for samples collected from farrowing, finisher, gestation, and nursery rooms, respectively. After the samples were diluted 14.7 times, the odor intensities were evaluated to be 3.79, 3.46, 0.48, and 4.0 for the above-mentioned rooms, respectively. The data collected were used to develop a mathematical model.

Agriculture↗

Improvement of odor intensity measurement using dynamic olfactometry.

Odor intensity reveals a dose-effect relationship between inhaled odor and perceived odor sensation by the receptors, while odor concentration reflects the odor strength at the emission sources. The study reports significant improvements in experimental procedures in establishing the odor concentration-intensity (OCI) relationships using a newly developed digital olfactometer. The improvements in experimental procedures have been made to meet the requirements of both the VDI guideline 3882.1 and the European standard (EN13725). Several areas which could affect the reliability of the results have been identified in some similar studies. The latest digital olfactometer was calibrated automatically to ensure accurate and repeatable dilution ratios. Cross contamination has been eliminated through the instrument design and extensive cleaning procedures, making random presentation possible. Stringent panelist screening and continuous performance monitoring ensures consistent sensitivity of the panel. The extension of odor intensity category to temperature sensation gives a reference to assist judgments of perceived odor sensation. The DynaScent calculation method has simplified odor intensity calculation and can be applied to many odor samples. A total of 38 odor samples from three alumina refinery sites and two sewage treatment plants were collected for analysis. The results have confirmed the efficiency of the olfactometer. Distinct Odor Concentrations (DOCs) were calculated for each sample using both VDI and DynaScent methods. A student t test on two major odor types confirmed that there are no significant differences between two methods. The study has shown the DOCs for refinery odor and wastewater odor are in the range of 3.8-15.4 and 4.2-15.6 odor unit (OU)/m3 respectively. The study demonstrated that the improvements are critical in achieving reliable odor intensity measurement. This can lead to the setup of quantitative odor impact criteria for different industries and sites.

Air Pollutants↗

Modeling panel detection frequencies by queuing system theory: an application in gas chromatography olfactometry.

In continuous vigilance tasks, the number of coincident panel responses to stimuli provides an index of stimulus detectability. To determine whether this number is due to chance, panel noise levels have been approximated by the maximum coincidence level obtained in stimulus-free conditions. This study proposes an alternative method by which to assess noise levels, derived from queuing system theory (QST). Instead of critical coincidence levels, QST modeling estimates the duration of coinciding responses in the absence of stimuli. The proposed method has the advantage over previous approaches that it yields more reliable noise estimates and allows for statistical testing. The method was applied in an olfactory detection experiment using 16 panelists in stimulus-present and stimulus-free conditions. We propose that QST may be used as an alternative to signal detection theory for analyzing data from continuous vigilance tasks.

Adult↗

[A simple dispenser for liquid olfactometry].

A simple mechanical device for the dosage delivery of the chemical substance solutions to the animal chemoreceptors is suggested. This device is making chemical stimuli with abrupt fronts by means of stream switching of the control and test solutions.

Animals↗