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At least 109 records · Page 6Linked to original sources

A sick house syndrome, possibly resulting from a landfill geologic effluvia.

A novel indoor air quality investigation was associated with carbon dioxide and methane accumulation, presumably from effluvia from geologic sources. Each of 6 workers in an office building complained of respiratory symptoms, and of difficulty with memory and concentration in the workplace, a tightly-sealed structure under negative pressure. No single contaminant was identified to explain the clinical syndromes. No detectable levels of carbon monoxide, methyl ethyl ketone, formaldehyde, ozone, carbon disulfide, nitric oxide, ethylene oxide, ammonia, aldehydes, trichloroethylene or similar chlorinated compounds were found. Carbon dioxide and methane were both present at above ambient outdoor air concentrations. Carbon dioxide was documented to accumulate over a weekend with no occupants in the building, suggesting a geologic source.

Adult↗

Surficial geology of the Chicxulub impact crater, Yucatan, Mexico.

The Chicxulub impact crater in northwestern Yucatan, Mexico is the primary candidate for the proposed impact that caused mass extinctions at the end of the Cretaceous Period. The crater is buried by up to a kilometer of Tertiary sediment and the most prominent surface expression is a ring of sink holes, known locally as cenotes, mapped with Landsat imagery. This 165 +/- 5 km diameter Cenote Ring demarcates a boundary between unfractured limestones inside the ring, and fractured limestones outside. The boundary forms a barrier to lateral ground water migration, resulting in increased flows, dissolution, and collapse thus forming the cenotes. The subsurface geology indicates that the fracturing that created the Cenote Ring is related to slumping in the rim of the buried crater, differential thicknesses in the rocks overlying the crater, or solution collapse within porous impact deposits. The Cenote Ring provides the most accurate position of the Chicxulub crater's center, and the associated faults, fractures, and stratigraphy indicate that the crater may be approximately 240 km in diameter.

Earth, Planet↗

Geological characterization of the Prestige sinking area.

The tanker Prestige sank off NW Iberia on the 19th November 2002. The stern and bow of the Prestige wreck are located on the southwestern edge of the Galicia Bank, at 3565 m and 3830 m water depths, respectively. This bank is a structural high controlled by major faults with predominant N-S, NNE-SSW, and NNW-SEE trends. It is characterized by moderate to low seismic activity. The faults have controlled the local depositional architecture, deforming, fracturing, relocating and distributing sediments since the Valangian (early Cretaceous). The Prestige sinking area corresponds to an asymmetric half-graben structure with a N-S trend, which conditions the present-day morphology. The faulted flank outcrops and its activity and erosion have favoured the occurrence of mass-movements (slumps, slump debris, mass-flows and turbidity currents), building valleys and depositional lobes. Nearsurface sediments comprise mostly terrigenous and biogenous turbiditic muds and sands with a minor presence of hemipelagic muds, except on the fault scarp where pelagites predominate. Potential geological hazards resulting from tectonic and sedimentary processes affect almost the entire Prestige sinking area.

Atlantic Ocean↗

Microbial respiration and diffusive transport of O2, 16O2, and 18O15O in unsaturated soils and geologic sediments.

Molecular oxygen (O2) in unsaturated geologic sediments plays an important role in soil respiration, biodegradation of organic contaminants, metal oxidation, and global oxygen and carbon cycling, yet little is known about oxygen isotope fractionation during the consumption and transport of O2 in unsaturated zones. We used a laboratory kinetic cell technique to quantify isotope fractionation due to respiration and a numerical model to quantify both consumptive and diffusive fractionation of O2 isotopes at a field site comprised of unsaturated lacustrine sandy materials. The combined use of laboratory-based kinetic cell experiments and field-based isotope transport modeling provided an effective tool to characterize microbial respiration in unsaturated media. Based on results from the closed-system kinetic cells, O2 consumption and isotope fractionation were attributed to the alternative cyanide-resistant respiration pathway. At the field site, the modeled depth profiles for O2 and delta18O matched the measured in situ data and confirmed that the consumption of O2 was via the alternative respiration pathway. If the cyanide-resistant respiration pathway is indeed widespread in soils, its high oxygen isotope enrichment factor could help to explain the discrepancy between the predicted present-day Dole effect (+20.8/1000) and the observed Dole effect (+23.5/1000). Thus, further soil O2 isotope studies are needed to better characterize and model the fractionation of oxygen isotopes during subsurface respiration and the potential impact on the isotopic content of atmospheric O2.

Biodegradation, Environmental↗

Completeness of the geological record.

The completeness of a sedimentary section of known timespan may be assessed qualitatively by comparing its thickness with the average accumulation for that timespan. Average accumulations may be estimated from sediment volume and continental area data. Quantitative completeness estimation methods based on data compiled from the geological literature have been proposed, but we argue that the literature data are significantly biased and cannot support such methods. Interestingly, however, a comparison of the literature data and accumulation averages computed from sediment volume data suggests that the thickest known sections may be extremely complete.

Earth, Planet↗

Evolutionary biology and chemical geology: a timely marriage.

For more than 150 years natural selection has been perceived to be the overwhelming force in evolution. Only in recent decades have we obtained new insights into environmental and physicochemical factors that participate with selection in a synergic way. Far from denying Darwin's theory, such neglected factors put order to the bewildering range of genotypes and morphologies found in living organisms and, more importantly, they place evolution in a planetary context where biology, geology, and chemistry can easily be integrated.

Animals↗

Radon hazards, geology, and exposure of cave users: a case study and some theoretical perspectives.

The concerns over the risks to human health from radon in underground caves are poorly documented, unlike in workplace or domestic environments where exposures are relatively well known. In U.K. caves, radon has been identified as occurring at elevated levels; but with the exception of major show caves, its impact and risk to the many groups who use the caves have thus far received inadequate attention. This paper presents a survey performed in a relatively "low-risk" geographical area of the United Kingdom and quantifies the risk of exposure in this cave environment. Radon levels up to 12,552 Bq m(-3) were measured: Such concentrations are very high but are likely to underestimate the levels in many other parts of the cave system, for reasons associated with cave architecture and meteorology. This study confirms previous workers' conclusions that long-term users of deep caves, as opposed to rock shelters, are at risk. Annual doses to certain groups of cave users have been calculated to be as high as 120 mSv, a very high value. The study also demonstrates that there is variation both within and between caves as a result of subtleties of the bedrock geology, fault patterns, and weathering. This paper sets out a theoretical model.

Geological Phenomena↗

Prebiotic nucleotide synthesis-demonstration of a geologically plausible pathway.

Mineral phosphate (apatite) is activated for the synthesis of nucleotides when dilute solutions containing nucleoside and ammonium oxalate are evaporated in its presence. A natural, igneous fluorapatite was found to be even more effective in nucleotide synthesis than the more soluble hydroxylapatite. The phosphorylation is considerably more efficient if urea of cyanamide is also present. Hydrolysis of solutions of cyanogen to form oxalate and urea among other products is a spontaneous process that provides a geologically plausible model for necleotide synthesis on the primitive earth.

Apatites↗

Historical and geological evidence for seismic origin of newly recognized landslides in southeastern Sicily, and its significance in terms of hazard.

Old, large, and dormant landslides were unexpectedly found in southeastern Sicily, a territory of known seismicity but commonly considered as landslide-free or almost so. Purposely undertaken investigations revealed that: (1) these landslides are scarcely compatible with the local geoclimatic environment; (2) they usually show low-angle basal shear surfaces, despite the fact that the properties of the forming material are generally good; (3) they fulfill the known relationships between earthquake magnitude and epicenter-landslide distance; (4) sources coeval with high-energy historical earthquakes occurred in 1169, 1542 and 1693 testify to the occurrence of earthquake-triggered landsliding; and (5) documentary material (presented here for the first time) correlates with certainty a specific landslide to the 1693 earthquake. This geological and historical evidence, accompanied by the absence of contrasting elements, leads us to conclude that these landslides are earthquake-triggered. Because of their typological and geometrical characteristics, nearly all landslides can be reactivated, which has serious implications in terms of hazard, particularly with respect to lines of communication. Obviously, every action aimed at preventing or mitigating risks must start from the awareness of the causative processes, a condition substantially unsatisfied at the moment in SE Sicily. The paper concludes by emphasizing the opportunity not to trust excessively beliefs that, although shared, have never been really checked.

Data Collection↗

Determination of alpha-dialkylamino acids and their enantiomers in geological samples by high-performance liquid chromatography after derivatization with a chiral adduct of o-phthaldialdehyde.

Derivatization with o-phthaldialdehyde (OPA) and the chiral thiol N-acetyl-L-cysteine (NAC) is a convenient and sensitive technique for the HPLC detection and resolution of protein amino acid enantiomers. The kinetics of the reaction of OPA-NAC with alpha-dialkylamino acids was investigated. The fluorescence yield of alpha-dialkylamino acids was only about 10% of that of protein amino acids when the derivatization was carried out at room temperature for 1-2 min, which is the procedure generally used for protein amino acid analyses. The fluorescence yield of alpha-dialkylamino acids can be enhanced by up to ten-fold when the derivatization reaction time is increased to 15 min at room temperature. The OPA-NAC technique was optimized for the detection and enantiomeric resolution of alpha-dialkylamino acids in geological samples which contain a large excess of protein amino acids. The estimated detection limit for alpha-dialkylamino acids is 1-2 pmol, comparable to that for protein amino acids.

Acetylcysteine↗

Statistical prediction of terrestrial gamma radiation dose rate based on geological features and soil types in Kota Tinggi district, Malaysia.

A statistical prediction of terrestrial gamma radiation dose rate has been performed, covering the Kota Tinggi district of Peninsular Malaysia. The prediction has been based on geological features and soil types. The purpose of this study is to provide a methodology to statistically predict the gamma radiation dose rate with minimum surveying in an area. Results of statistical predictions using the hypothesis test were compared with the actual dose rate obtained by measurements.

Forecasting↗

Population structure and history of a phenotypically variable teiid lizard (Ameiva chrysolaema) from Hispaniola: the influence of a geologically complex island.

Ameiva chrysolaema is distributed across the island of Hispaniola in the West Indies. The species is restricted to dry lowlands between major mountain ranges and along the southern and eastern coasts. Phylogenetic and phylogeographic analyses of mtDNA sequence variation from 14 sampling localities identify at least three independent evolutionary lineages, separated from one another by major mountain ranges. Nested clade phylogeographic analysis (NCPA) suggests a complex history of population fragmentation, consistent with geological evidence of seawater incursions into the Azua and Enriquillo basins during the Pliocene/Pleistocene (approximately 1.6 mya). Significantly negative Fu's F(S) values and parameters of mismatch distributions suggest that formerly fragmented populations have recently expanded their ranges. Significantly large average population clade distances (APCD) for two sampling localities in the Azua basin suggest secondary contact at these localities of previously separated populations. The distribution of haplotypes among polymorphic populations of A. chrysolaema suggests that variation in dorsal pattern represents a polymorphism within evolutionary lineages. Ameiva leberi is ecologically indistinguishable from and syntopic with A. chrysolaema. Genetic data suggest that A. leberi is a junior synonym of A. chrysolaema.

Animals↗

Effect of geological processes on coal quality and utilization potential: review with examples from western Canada.

This review article compares the elemental and radionuclide concentrations in coals from western Canada, the vast majority of which are used for power generation in Alberta. The coals range in age from lower Cretaceous to middle Eocene, and in rank from subbituminous to high volatile bituminous. Some of the coals were deposited in deltaic lagoonal to marine settings while others formed under lacustrine conditions in intermontane graben settings or in alluvial plains. The role of source rock (provenance), depositional environment, tectonic regime and hydrologic conditions on elemental concentration and distribution will be discussed, with specific examples from western Canada. In addition, the effect of natural weathering, igneous intrusion and self-burning (spontaneous combustion) on the enrichment and/or depletion of elements will be presented. The emphasis throughout this review article will be on the fate of elements of environmental concern and interest (e.g. As, Ba, B, Cl, Co, Cr, Cu, Mn, Mo, Se, Th, U, V and Zn) and of radionuclides of the U and Th series upon coal utilization. This article is also intended for those not familiar with the geological or environmental sciences, particularly as related to fossil fuel utilization.

Alberta↗

PIXE study of Cuban quaternary paleoclimate geological samples and speleothems.

PIXE elemental analysis of sediments, speleothems, and other geological formations related to the karst of the Sierra de San Carlos is presented. The similarity of the elemental composition of the sediments studied, as well as the alluvial regime which created them, indicate their common origin at each location. The Sr/Ca concentration ratio of a stalactite indicates that the average atmospheric temperature 12,000 and 18,000 years B.P. was colder than that of 6000 years B.P.

Calcium↗

Quantitative modal determination of geological samples based on X-ray multielemental map acquisition.

Multielemental X-ray maps collected by a remote scanning system of the electron beam are processed by a dedicated software program performing accurate modal determination of geological samples. The classification of different mineral phases is based on elemental concentrations. The software program Petromod loads the maps into a database and computes a matrix consisting of numerical values proportional to the elemental concentrations. After an initial calibration, the program can perform the chemical composition calculated on the basis of a fixed number of oxygens for a selected area. In this way, it is possible to identify all the mineral phases occurring in the sample. Up to three elements can be selected to calculate the modal percentage of the identified mineral. An automated routine scans the whole set of maps and assigns each pixel that satisfies the imposed requirements to the selected phase. Repeating this procedure for every mineral phase occurring in the mapped area, a modal distribution of the rock-forming minerals can be performed. The final output consists of a digitized image, which can be further analyzed by common image analysis software, and a table containing the calculated modal percentages. The method is here applied to a volcanic and a metamorphic rock sample.

Electron Probe Microanalysis↗

Regulating the ultimate sink: managing the risks of geologic CO2 storage.

The geologic storage (GS) of carbon dioxide (CO2) is emerging as an important tool for managing carbon. While this Journal recently published an excellent review of GS technology (Bruant, R. G.; Guswa, A. J.; Celia, M. A.; Peters, C. A. Environ. Sci. Technol. 2002, 36, 240A-245A), few studies have explored the regulatory environment for GS or have compared it with current underground injection experience. We review the risks and regulatory history of deep underground injection on the U.S. mainland and surrounding continental shelf. Our treatment is selective, focusing on the technical and regulatory aspects that are most likely to be important in assessing and managing the risks of GS. We also describe current underground injection activities and explore how these are now regulated.

Air Pollution↗

Effects of Fe(II) and hydrogen peroxide interaction upon dissolving UO2 under geologic repository conditions.

Iron redox cycling is supposed to be one of the major mechanisms that control the geochemical boundary conditions in the near field of a geologic repository for UO2 spent nuclear fuel. This work investigates the impact of reactions between hydrogen peroxide (H2O2) and iron (Fe2+/Fe3+) on UO2 dissolution. The reaction partners were contacted with UO2 in oxygen-free batch reactor tests. The interaction in absence of UO2 gives a stoichiometric redox reaction of Fe2+ and H2O2 when the reactants are present in equal concentration. Predomination of H202 results in its delayed catalytic decomposition. With UO2 present, its dissolution is controlled by either a slow mechanism (as typical for anoxic environments) or uranium peroxide precipitation, depending strongly on the reactant ratio. Uranium peroxide (UO4 x nH2O, m-studtite), detected on UO2 surfaces after exposure to H2O2, was not found on the surfaces exposed to solutions with stoichometric Fe(II)/ H2O2 ratios. This suggests that H2O2 was deactivated in redox reactions before a formation of UO4 took place. ESR measurements employing the spin trapping technique revealed only the DMPO-OH adduct within the first minutes after the reaction start (high initial concentrations of the OH radical); however, in the case of Fe(II) and H2O2 reacting at 10(-4) mol/L with UO2, dissolved oxygen and Fe2+ concentrations indicate the participation of further Fe intermediates and, therefore, Fenton redox activities.

Geological Phenomena↗

An appraisal of subsurface geology and groundwater resources of Owerri and environs based on electrical resistivity survey and borehole data evaluation.

The research was aimed at determining the depth to the water table, aquifer thickness and subsurface geology of the study area thus revealing its groundwater distribution as well as its potential as a substitute to the surface water resources. Vertical electrical soundings were carried out in the study area with maximum electrode spread. The Schlumberger electrode configuration technique was adopted. VES data were processed using Schlumberger analysis package. Lithologic logs of already existing boreholes in the study area were collected, evaluated and comparison were carried out. The results reveal alternating layers of sands, sandstones, gravel and clay. The lithologic logs revealed that the study area is underlain by coastal sands (Benin formation). The water table varies from 10-64 m and thickness of the aquifer ranges from 20-80 m. Results show that the study area is underlain by a thick extensive aquifer that has a transmissivity of 2.8 x 10(-2) m2 s(-1) to 3.3 x 10(-1) m2 s(-1) and storativity 1.44 x 10(-4) to 1.68 x 10(-3) m s(-1) values. The specific yield is about 0.31. The sandy component of the study area forms more than 90% of the sequence, therefore the permeability, the transmissivity and the storage coefficient are high with an excellent source of groundwater resources.

Agriculture↗