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Environmental health risks of toxic waste site exposures--an epidemiological perspective.

A general account is given of the problems of assessing the impact of human exposure to toxic waste sites, including the identification of truly exposed populations and of exposure pathways. Epidemiological studies of populations at risk are briefly reviewed and methodological problems summarised. These include the use of relatively weak study designs, inadequate exposure assessment and recall biases associated with symptom reporting among anxious residents living in the vicinity of waste sites. In South Africa, health risks associated with exposure to toxic waste sites need to be viewed in the context of current community health concerns, competing causes of disease and ill-health, and the relative lack of knowledge about environmental contamination and associated health effects. A nonspecific deterioration of health and well-being is more likely to result from waste site exposures than is overt clinical disease. Socially acceptable policies and controls may have to be based on criteria other than demonstrable ill-health. Detailed inventories and registries of the nature of disposed materials need to be maintained, sites of poorly controlled disposal in the past identified and selective environmental monitoring conducted. Epidemiological studies may be justified in situations where exposures well in excess of acceptable norms are demonstrated. An integrated national waste management policy for the country is urgently needed.

Environmental Exposure↗

Short- and long-term releases of fluorocarbons from disposal of polyurethane foam waste.

Several halocarbons having very high global warming or ozone depletion potentials have been used as a blowing agent (BA) for insulation foam in home appliances, such as refrigerators and freezers. Many appliances are shredded after the end of their useful life. Release experiments carried out in the laboratory on insulation foam blown with the blowing agents CFC-11, HCFC-141b, HCF-134fa, and HFC-245fa revealed that not all blowing agents are released during a 6-week period following the shredding process. The experiments confirmed the hypothesis that the release could be divided into three segments: By shredding foam panels, a proportion of the closed cells is either split or damaged to a degree allowing for a sudden release of the contained atmosphere in the cell (the instantaneous release). Cells adjacent to the cut surface may be only slightly damaged by tiny cracks or holes allowing a relative slow release of the BA to the surroundings (the short-term release). A significant portion of the cells in the foam particle will be unaffected and only allows release governed by slow diffusion through the PUR cell wall (the long-term release). The magnitude of the releases is for all three types highly dependent on how fine the foam is shredded. The residual blowing agent remaining after the 6-week period may be very slowly released if the integrity of the foam particles with respect to diffusion properties is kept after disposal of the foam waste on landfills. It is shown by setting up a national model simulating the BA releases following decommissioning of used domestic refrigerators/freezers in the United States that the release patterns are highly dependent on how the appliances are shredded.

Air Movements↗

[Kinetics of Electro-Fenton treatment of leachate from municipal solid waste incinerator].

SPR electrode was used in Electrio-Fenton treatment on the effluent from biological and coagulative treatments of solid waste incinerator leachate, at the same time, the kinetics model for the COD effluent concentration were set up. The result indicated that the disposal curve of COD confirm to the pseudo third order kinetics, and the formula is c(t) = (2kt + c(0)(-2))(-0.5), in which the c(t) is the COD concentration of treatment effluent. With the statistical analysis to the disposal curve of COD from Electro-Fenton treatment in different conditions, the experience mathematics model of k value was set up, in which the current density, pH value and COD concentration of influent are effective factors. Moreover, with the comparison between the simulative COD of effluent and the experimental results, it was showed that this kinetic model could be used to investigate the COD disposal efficiency of Electro-Fenton treatment on the effluent from biological and coagulative treatments of solid waste incinerator leachate preferably.

Catalysis↗

Disposal of low-level radioactive wastes.

The generation of low-level radioactive waste is a natural consequence of the societal uses of radioactive materials. These uses include the application of radioactive materials to the diagnosis and treatment of human disease and to research into the causes of human disease and their prevention. Currently, low level radioactive wastes are disposed of in one of three shallow land-burial disposal sites located in Washington, Nevada, and South Carolina. With the passage in December 1980 of Public Law 96-573, "The Low-Level Radioactive Waste Policy Act," the disposal of low-level wastes generated in each state was identified as a responsibility of the state. To fulfill this responsibility, states were encouraged to form interstate compacts for radioactive waste disposal. At the present time, only 37 states have entered into compact agreements, in spite of the clause in Public Law 96-573 that established January 1, 1986, as a target date for implementation of state responsibility for radioactive wastes. Recent action by Congress has resulted in postponement of the implementation date to January 1, 1993.

Radioactive Waste↗

Legislative and environmental issues on the use of ash from coal and municipal sewage sludge co-firing as construction material.

For the economy of any co-firing process, it is important that the common waste management options of ash remain practical. Ash from bituminous coal combustion is typically handed to the construction industry. This paper describes the current European legislation on use of ash for construction purposes. Also, it presents an experimental study on the suitability of fly ash from combustion of mixtures of bituminous coal and municipal sewage sludge as additive to cement and concrete, and for use in open-air construction works, based on the ash chemical composition and the characteristics of the extract of the ash. Presently, two European standards forbid the use of ash from co-firing as additive to cement or concrete. This study shows that ash derived from coal and sewage sludge co-firing contains generally less unburned carbon, alkali, magnesium oxide, chlorine, and sulfate than coal ash. Only the concentration of free lime in mixed ash is higher than in coal, even though, at least up to 25% of the thermal input, still below the requirements of the standards. This ash also meets the requirements for the use of fly ash in open-air construction works--concentration and mobility of few elements--although this management option is forbidden to ash from co-firing. The leaching of Cd, Cr, Cu, Ni, Pb and Zn was investigated with three leaching tests. The concentration of these metals in the extracts was below the detection limit in most cases. The concentration of Cu and Zn in the extract from fly ash was found to increase with increasing share of sewage sludge in the fuel mixture. However, the concentration of these two metals in the extract is not regulated. This study indicates that excluding a priori the use of ash from co-firing as a suitable additive for construction material could cause an unnecessary burden on the environment, since probably ash would have to be disposed of in landfill. However, allowing this requires the modification of current European standards to include limitations on all elements and compounds, absent in coal but which might be present in other fuels, that are deleterious for the quality of construction materials.

Air Pollution↗

A comparison of in situ vitrification and rotary kiln incineration for soils treatment.

In the hazardous waste community, the term "thermal destruction" is a catchall phrase that broadly refers to high temperature destruction of hazardous contaminants. Included in the thermal destruction category are treatment technologies such as rotary kiln incineration, fluidized bed incineration, infrared thermal treatment, wet air oxidation, pyrolytic incineration, and vitrification. Among them, conventional rotary kiln incineration, a disposal method for many years, is the most well established, and often serves as a barometer to gauge the relative success of similar technologies. Public sentiment on environmental issues and increasingly stringent environmental regulations has, over time, spurred design and development of innovative thermal treatment processes directed toward reducing harmful emissions and residuals that may require further treatment or disposal. In situ vitrification (ISV), a technology that combines heat and immobilization, is one such innovative and relatively new technology. This paper presents a comparison of ISV and rotary kiln incineration for soils treatment in the areas of process performance, process residuals, process limitations, applicable or relevant and appropriate (ARARs) regulations, criteria and limitations, and costs.

Hazardous Waste↗

Role of state regulatory agencies in the disposition of low-activity radioactive materials.

Since the opening of the first disposal site for commercially generated low-level radioactive waste at Beatty, Nevada, in September 1962, the states have been explicitly involved in the process. The states have been involved as landowners, regulators, environmental monitors, and sometimes promoters of the sites and/or the businesses operating the sites.

Decision Making↗

Controlling the exotic diseases: 2. Nursing management.

Advance planning can facilitate the care of a patient with an exotic disease who is admitted to a hospital that lacks facilities for high-security isolation. The Department of National Health and Welfare contingency plan for dealing with such patients lacks specific information in a number of areas of medical care, as described in this paper. Consideration must be given to the number of personnel trained and readied for employment, the criteria for selection and special preparation. The protective clothing generally used for hospital isolation procedures is inadequate. Several types of special clothing, including a respirator, are available for total protection of personnel; the clothing may be uncomfortable when worn for long periods, and does restrict movement, vision and communication. All persons entering the isolation suite must change into fully protective clothing, and double layers of clothing are required for direct patient care. All personnel must shower and change before leaving the isolation suite. Suitable facilities for dressing and showering, together with entry and exit routines, must be considered. Hand washing, daily cleaning procedures and disposal of liquid and solid wastes all require special procedures. The social and psychologic problems of patients and their families must also be considered. Preplanning is required to decrease the risks involved in monitoring vital signs and implementing emergency procedures requiring contact with the patient's blood.

Communicable Diseases↗

Hospitals dispose of destructive waste habits. Recycling protects the environment, but facilities are finding it can pay off in numerous ways.

Across the country, hospitals are setting up recycling programs. While protecting the environment is their first concern, they've also found that recycling offers other benefits, such as lower landfill fees, reduced energy and supply costs, less cluttered work areas, better employee morale and improved community relations.

Conservation of Natural Resources↗

An outbreak of Norwalk virus gastroenteritis associated with eating raw oysters. Implications for maintaining safe oyster beds.

OBJECTIVE: To determine the characteristics and the cause of an outbreak of gastroenteritis associated with eating raw oysters. DESIGN: Survey of groups of persons reporting illness to the health department after eating oysters; survey of convenience sample of oyster harvesters; and tracing of implicated oysters. SETTING: General community. MAIN OUTCOME MEASURES: Relative risk for illness after oyster consumption, source bed of contaminated oysters, presence of antibodies to Norwalk virus in serum, presence of a Norwalk virus in stool by direct electron microscopy and reverse transcription-polymerase chain reaction (RT-PCR), and DNA sequences of RT-PCR products. RESULTS: Seventy (83%) of 84 persons who ate raw oysters became ill vs three (7%) of 43 people who did not eat raw oysters (relative risk, 11.9; 95% confidence interval, 4.0 to 34.2). Eleven (79%) of 14 serum pairs had at least a fourfold increase in antibody to Norwalk virus. All 12 stool samples tested were positive by electron microscopy and/or RT-PCR for Norwalk virus. The RT-PCR products from all seven stool samples tested had identical DNA sequences. Implicated oysters were harvested November 9 through 13, 1993, from a remote oyster bed. Crews from 22 (85%) of 26 oyster harvesting boats working in this area reported routine overboard disposal of sewage. One harvester with a high level of antibodies to Norwalk virus reported having gastroenteritis November 7 through 10 and overboard disposal of feces into the oyster bed. CONCLUSIONS: This outbreak was caused by contamination of oysters in the oyster bed, probably by stool from one or more ill harvesters. Education of oyster harvesters and enforcement of regulations governing waste disposal by oyster harvesting boats might prevent similar outbreaks.

Adolescent↗

Shigellosis on Indian reserves in Manitoba, Canada: its relationship to crowded housing, lack of running water, and inadequate sewage disposal.

OBJECTIVES: This study compares incidence and hospitalization rates for shigellosis between Indians and the rest of the population in Manitoba, Canada. It examines the relationship between shigellosis and environmental conditions on reserves. METHODS: Rates were calculated with surveillance data and a survey of environmental infrastructure was done. RESULTS: Indians had shigellosis incidence and hospitalization rates that were 29 and 12 times as high, respectively, as those of the rest of the population. Household crowding, lack of piped water, and inadequate sewage disposal were significantly associated with an increased incidence of shigellosis on reserves. CONCLUSIONS: Many cases of shigellosis may be prevented by improving living conditions on Indian reserves.

Adolescent↗

Environmental and health impacts of household solid waste handling and disposal practices in third world cities: the case of the Accra Metropolitan Area, Ghana.

Inadequate provision of solid waste management facilities in Third World cities results in indiscriminate disposal and unsanitary environments, which threatens the health of urban residents. The study reported here examined household-level waste management and disposal practices in the Accra Metropolitan Area, Ghana. The residents of Accra currently generate large amounts of solid waste, beyond the management capabilities of the existing waste management system. Because the solid waste infrastructure is inadequate, over 80 percent of the population do not have home collection services. Only 13.5 percent of respondents are served with door-to-door collection of solid waste, while the rest dispose of their waste at communal collection points, in open spaces, and in waterways. The majority of households store their waste in open containers and plastic bags in the home. Waste storage in the home is associated with the presence of houseflies in the kitchen (r = .17, p < .0001). The presence of houseflies in the kitchen during cooking is correlated with the incidence of childhood diarrhea (r = .36, p < .0001). Inadequate solid waste facilities result in indiscriminate burning and burying of solid waste. There is an association between waste burning and the incidence of respiratory health symptoms among adults (r = .25, p < .0001) and children (r = .22, p < .05). Poor handling and disposal of waste are major causes of environmental pollution, which creates breeding grounds for pathogenic organisms, and the spread of infectious diseases. Improving access to solid waste collection facilities and services will help achieve sound environmental health in Accra.

Animals↗

[Essays on the history of rendering in Austria (author's transl)].

Following a short historical outline of the former manner of disposing of cadavers and slaughter offals a detailed analysis is made of the Austrian spade-work in this field supported by an relevant documentation dating back to 1743, and of the importance for controlling animal epidemics and for meat hygiene.

Animals↗

Soil biochemical activity and growth response of rice Oryza sativa in flyash amended soil.

Soil amended with different proportions of flyash, a solid waste generated from coal-fired thermal power plants, was evaluated as a soil conditioner and nutrient supplement during a field study on the growth of rice, Oryza sativa. Generally, pH and organic carbon (OC) content did not increase significantly (P > 0.05) in flyash amended soil, but significant increases (P < 0.05) in soil conductivity (32%), available phosphorus (48%) and organic matter (OM, 29%) were observed during harvest at the 20 t ha-1 flyash application rate. Amylase, invertase, dehydrogenase and protease activities, and CO2 evolution increased in flyash amended soil over the control. The pigment (chl-a, chl-b, and carotenoid) content in rice plants did not vary significantly (P > 0.05) between different flyash amendments. Total plants biomass and aboveground biomass increased (P < 0.05) significantly (17% and 25%, respectively) at the 20 t ha-1 flyash application. However, there was a retarded growth of underground biomass. Grain and straw yield increased by 21% and 18%, respectively, at 17.5 t ha-1 flyash amendment when compared to the control. Although, a significant increase (P < 0.05) in plant biomass and grain yield in flyash amended soil is encouraging from the point of waste disposal and management, elucidation of reasons for retarded growth in underground biomass will require additional research based on long-term studies.

Amylases↗

Release of arsenic to the environment from CCA-treated wood. 2. Leaching and speciation during disposal.

Wood treated with chromated copper arsenate (CCA) is primarily disposed within construction and demolition (C&D) debris landfills, with wood monofills and municipal solid waste (MSW) landfills as alternative disposal options. This study evaluated the extent and speciation of arsenic leaching from landfills containing CCA-treated wood. In control lysimeters where untreated wood was used, dimethylarsinic acid (DMAA) represented the major arsenic species. The dominant arsenic species differed in the lysimeters containing CCA-treated wood, with As(V) greatest in the monofill and C&D lysimeters and As(III) greatest in the MSW lysimeters. In CCA-containing lysimeters, the organoarsenic species monomethylarsonic acid (MMAA) and DMAAwere virtually absent in the monofill lysimeter and observed in the C&D and MSW lysimeters. Overall arsenic leaching rate varied for the wood monofill (0.69% per meter of water added), C&D (0.36% per m), and MSW (0.84% per m) lysimeters. Utilizing these rates with annual disposal data, a mathematical model was developed to quantify arsenic leaching from CCA-treated wood disposed to Florida landfills. Model findings showed between 20 and 50 t of arsenic (depending on lysimeter type) had leached prior to 2000 with an expected increase between 350 and 830 t by 2040. Groundwater analysis from 21 Florida C&D landfills suspected of accepting CCA-treated wood showed that groundwater at 3 landfills was characterized by elevated arsenic concentrations with only 1 showing impacts from the C&D waste. The slow release of arsenic from disposed treated wood may account for the lack of significant impact to groundwater near most C&D facilities at this time. However, greater impacts are anticipated in the future given that the maximum releases of arsenic are expected by the year 2100.

Arsenates↗

[Research on low emission MSW gasification and melting system].

In order to eliminate the secondary pollution caused by MSW incineration, fluidized bed gasification and swirl-flow melting process is proposed which produces less emission. MSW of China can be effectively gasified in fluidized bed at about 600 degrees C. Combustion fly ash of MSW can be melted into vitrification at about 1300 degrees C and that of MSW combusted with coal can be done at about 1 400 degrees C, during which dioxins (PCDD/Fs) is decomposed over 99.99% and heavy-metals are mostly solidified. Two novel and improved MSW gasification and melting schemes are brought forward preferably: (1) The gasification and melting system based on integrated disposal of MSW. (2) The gasification and melting system of original MSW + assistant fuel. It is testified that the two schemes are suitable for China by thermo-performance analysis.

Air Pollution↗

Management of infectious waste by US hospitals.

In July 1987 and January 1988, forty-six percent (441/955) of randomly selected US hospitals responded to a questionnaire intended to identify their waste disposal practices. Survey responses were received from hospitals in 48 states. United States hospitals generated a median of 6.93 kg of hospital waste per patient per day and infectious waste made up 15% of the total hospital waste. Most hospitals (greater than 90%) considered blood, microbiology, "sharps," communicable disease isolation, pathology, autopsy, and contaminated animal carcass waste as infectious. Other sources of hospital waste that were commonly (greater than 80%) designated infectious were surgical, dialysis, and miscellaneous laboratory waste. The infectious waste was normally (80%) treated via incineration or steam sterilization before disposal, whereas noninfectious waste was discarded directly in a sanitary landfill. Eight-two percent of these US hospitals are discarding blood, microbiology, sharps, pathology, and contaminated animal carcass waste in accordance with the Centers for Disease Control's recommendations, while the compliance rate for the Environmental Protection Agency's recommendations (excluding optional waste) is 75%. No hospital could identify an infection problem (excluding needle-stick injuries) that was attributable to the disposal of infectious waste. While the management of infectious waste by US hospitals is generally consistent with the Centers for Disease Control's guidelines, many hospitals employ overly inclusive definitions of infectious waste.

Centers for Disease Control and Prevention, U.S.↗

Recommendations for handling cytotoxic drugs in hospitals.

Recommended procedures for handling cytotoxic drugs in hospitals are presented. The recommended procedures are designed to reduce the number of opportunities for unnecessary contact with cytotoxic agents (CYTAs) by hospital personnel and to prevent contamination of the hospital environment and staff with cytotoxic agents. The recommendations incorporate elements of previously published and unpublished guidelines; they admittedly are based on informed judgment as well. Three sets of recommended procedures are presented, each offering a varying degree of protection. The number of cytotoxic drug doses prepared and administered is suggested as the determinant of which level of protection is followed. The cytotoxic workload index, defined as the number of CYTAs prepared or administered (or both) divided by the number of available staff hours, is proposed as a quantitative method of deciding which level of protection is required for a particular work station or work shift. The recommended procedures cover the following seven topic areas: general guidelines; apparel, equipment, and facilities; drug preparation; drug administration; housekeeping, waste disposal, and management of spills and contamination; medical surveillance of staff; and legal and personnel considerations. The recommended procedures and associated equipment are considered to be practical and to adequately protect hospital personnel from risks associated with handling cytotoxic agents.

Antineoplastic Agents↗