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Volatile constituents of redblush grapefruit (Citrus paradisi) and pummelo (Citrus grandis) peel essential oils from Kenya.

The volatile constituents of cold-pressed peel essential oils of redblush grapefruit (Citrus paradisi Macfadyen forma Redblush) and pummelo (Citrus grandis Osbeck) from the same locality in Kenya were determined by GC and GC-MS. A total of 67 and 52 compounds, amounting to 97.9 and 98.8% of the two oils, respectively, were identified. Monoterpene hydrocarbons constituted 93.3 and 97.5% in the oils, respectively, with limonene (91.1 and 94.8%), alpha-terpinene (1.3 and 1.8%), and alpha-pinene (0.5%) as the main compounds. Sesquiterpene hydrocarbons constituted 0.4% in each oil. The notable compounds were beta-caryophyllene, alpha-cubebene, and (E,E)-alpha-farnesene. Oxygenated compounds constituted 4.2 and 2.0% of the redblush grapefruit and pummelo oils, respectively, out of which carbonyl compounds (2.0 and 1.3%), alcohols (1.4 and 0.3%), and esters (0.7 and 0.4%) were the major groups. Heptyl acetate, octanal, decanal, citronellal, and (Z)-carvone were the main constituents (0.1-0.5%). Perillene, (E)-carveol, and perillyl acetate occurred in the redblush grapefruit but were absent from the pummelo oil. Nootkatone, alpha- and beta-sinensal, methyl-N-methylanthranilate, and (Z,E)-farnesol were prominent in both oils.

Citrus↗

Volatile constituents of Capillipedium parviflorum.

The essential oil of aerial parts of Capillipedium parviflorum (family Poaceae) was obtained by hydrodistillation in 0.4% yield on dry weight basis. The oil was analysed by capillary GC and GC-MS techniques. Two new compounds from plant source 4-nonanol 51.7% and 4-undecanone 23.5% predominated in the essential oil and were separated by column chromatography, identified and confirmed by 1H and 13C NMR. Thirty one compounds were identified from the essential oil accounting for 96% of total identifications.

Gas Chromatography-Mass Spectrometry↗

Gas chromatography: an investigative tool in multiple allergies to essential oils.

Essential or fragrant oils are volatile odourous mixtures of organic chemical compounds that are widely used in aromatherapy and in the perfume industry. Because of their frequent use, allergy to essential oils is being increasingly recognized. We report 2 cases of multiple allergies to essential oils in professional aromatherapists. Gas chromatography/mass spectrometry was used to analyse the oils in order to identify a common allergen responsible for the contact dermatitis. In both the cases, alpha- and beta-pinene were found to be the most common constituent in the oils and thus appeared to be key allergens. alpha-pinene was confirmed as an allergen on repeat patch testing with pure alpha-pinene in both cases. 12 controls tested were negative for the same. Gas chromatography-mass spectrometry was found to be an extremely useful tool that could be utilized in investigating multiple allergies to essential oils.

Allergens↗

Volatile constituents of the flower and fruit oils of Pittosporum tobira (Thunb.) Ait. grown in Iran.

The volatile components of the flower and fruit oils from Pittosporum tobira (Thunb.) Ait. grown in Iran, obtained through hydrodistillation, were analyzed by GC/MS. Sixteen compounds (representing 90.7% of the oil) and seventeen constituents (representing 89.9% of the oil) were identified in the flower and fruit oils, respectively. While the flower oil contained a-pinene (38.6%), n-nonane (11.8%), (E)-nerolidol (9.0%) and (E)-beta-ocimene (7.7%), the fruit oil contained a-pinene (30.2%), n-nonane (12.2%), germacrene-D (12.0%), a-cubebene (7.6%) and beta-cubebene (5.1%) as the main compounds.

Flowers↗