Search PubMed⌕ Search

SEARCH · Search PubMed

Results for “CHROMATES”

Search indexed PubMed citations on genomics, clinical trials, systematic reviews and public health. Explore titles, authors and supplied subject terms, then open the PubMed record.

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

At least 937 records · Page 52Linked to original sources
PubMed2005

Modulation of the human photopic ERG luminance-response function with the use of chromatic stimuli.

In response to progressively brighter flashes, the amplitude of the photopic b-wave of the human electroretinogram (ERG) first increases, then saturates at a maximal value (V(max)) to finally decrease with the brightest flashes. The purpose of this study was to investigate if this "photopic hill" could be modulated with the use of stimuli of different wavelengths. ERGs were evoked to flashes of white, blue, green and red light presented against a white background in 30 normal subjects. Each chromatic stimulus produced a photopic hill. Findings indicate that the amplitude of V(max) was essentially identical except for that measured in response to the red stimuli, where it was 20% smaller than the others.

Adolescent↗
PubMed2006

Method to recover and reuse chromated copper arsenate wood preservative from spent treated wood.

The volume of chromated copper arsenate (CCA) treated wood products coming out of service is expected to increase dramatically during the next decade. There is a need for an alternative waste management approach to landfilling. This paper investigates the variables affecting extraction of CCA components from wood particles and the potential to oxidize and reuse the recovered chemicals. Most of the CCA components could be extracted by 10% H2O2 at 50 degrees C in 6 h with an average extraction efficiency of 95% for Cr, 94% for Cu and 98% for As. The extract containing Cr(III), Cu(II) and As(V) could be oxidized in several stages by aqueous 2.5% w/w H2O2 in less than 2 h to a condition where it was compatible with CCA treating solutions and could be reused for treating new wood. When the recovered extract was mixed with fresh CCA solution in different ratios, the mixed CCA-C solutions had similar solution stability as freshly prepared CCA-C solution and treated wood had similar leaching properties as wood treated with fresh solution.

Arsenates↗
PubMed2003

Monocular chromatic contrast threshold and achromatic contrast sensitivity in children born prematurely.

PURPOSE: To study the effect of prematurity on monocular chromatic contrast thresholds (CCT) and achromatic contrast sensitivity (ACS). DESIGN: Case-control study. METHODS: A prospective study of 59 children born at less than 33 weeks' gestation was undertaken. Subjects were identified during routine neonatal screening for retinopathy of prematurity and recalled for testing at age 7 to 13 years. Five had stage 1 retinopathy of prematurity, seven had stage 2, and three had stage 3. Sixty-eight full-term children were recruited as controls. Those with major cerebral or eye disease were excluded. The CCT and ACS were measured monocularly in the eye with better visual acuity using static, computer-generated, sinusoidal gratings, displayed on a high-resolution monitor. The CCT and ACS were determined using a randomized double-staircase reversal algorithm. The ACS was measured at five spatial frequencies (0.22, 0.44, 0.88, 1.75, and 3.50 cycles/degree), and the CCT was measured along red-green and tritan confusion axes. RESULTS: Red-green (P =.326) and tritan (P =.910) contrast thresholds and ACS (P >.394 for all spatial frequencies) were similar to the control group. CONCLUSIONS: Previous research suggests that prematurity adversely affects color vision and ACS. This study used a computerized psychophysical test that minimized the test errors inherent in many previous studies. Unexpectedly, CCT and ACS were found to be similar to full-term children.

Adolescent↗
PubMed1989

Predictions about chromatic receptive fields assuming random cone connections.

We hypothesize that color vision depends on random connections between cones containing different pigments and neurons at higher levels in the macaque visual system. This hypothesis predicts the same types and proportions of chromatic receptive fields reported in the physiological literature at least up through the lateral geniculate nucleus. The results suggest that the specificity of connections demanded by the labelled-line model of color coding are unnecessary to account for current physiological data.

Animals↗
PubMed2001

Toxicity of chromated copper arsenate (CCA)-treated wood to non-target marine fouling communities in Langstone Harbour, Portsmouth, UK.

The effect of the anti-marine-borer timber preservative chromated copper arsenate (CCA) (a pressure impregnated solution of copper, chromium and arsenic compounds) on non-target marine fouling animals was investigated during a subtidal exposure trial. Panels of Scots pine treated to target retentions of 12, 24 and 48 kg CCA per m-3 of wood, plus untreated controls were submerged at a coastal site on the south coast of the UK for 6, 12 and 18 months. After each exposure period the fouling communities that formed on the surface of panels were assessed both qualitatively and quantitatively. Community structure was similar on panels treated to the three CCA loadings, but was significantly different from community structure on untreated panels. The total number of species (species richness) was similar on all panels, although the number of individual organisms attached to the surface of panels was significantly higher on CCA-treated panels than on untreated panels. k-dominance curves revealed that the difference in numbers of individuals between CCA-treated and untreated panels was caused by higher numbers of the dominant species (Elminius modestus, Hydroides ezoensis, and Electra pilosa) on CCA-treated panels. Other species were present in similar numbers on panels of all treatments. Results indicate that there are no detrimental toxic effects to epibiota caused by the presence of CCA preservative within the matrix of the wood at any of the treatment levels. Differences in community structure between CCA-treated and untreated panels may be due to enhanced larval settlement on CCA-treated timber by some species as a result of modifications to the surface properties of the timber by the CCA preservative.

Animals↗
PubMed2000

Time course of chromatic adaptation for color appearance and discrimination.

Adaptation to a steady background has a profound effect on both color appearance and discrimination. We determined the temporal characteristics of chromatic adaptation for appearance and discrimination along different color directions. Subjects were adapted to a large uniform background made up of a CRT screen and a 45x64 degrees wall, illuminated by computer controlled lamps. After an instant change in background color along a red-green or blue-yellow color axis, we measured thresholds for the detection of increments along the same axes at fixed times between 25 ms and 121 s. Analogously, color appearance was determined using achromatic matching. Three components of adaptation could be identified by their temporal characteristics. A slow exponential time course of adaptation with a half-life of about 20 s was common to appearance and discrimination. A faster component with a half-life of 40-70 ms--probably due to photoreceptor adaptation--was also common to both. Exclusive for color appearance, there was a third, extremely rapid mechanism with a half-life faster than 10 ms. This instantaneous process explained more than 50% of total adaptation for color appearance and could be shown to act in a multiplicative manner. We conclude that this instantaneous adaptation mechanism for color appearance is situated at a later processing stage, after mechanisms common to appearance and discrimination, and is based on multiplicative spatial interactions rather than on local, temporal adaptational processes. Color appearance, and thus color constancy, seems to be determined in large part by cortical computations.

Adaptation, Physiological↗
PubMed2000

Contrast matching across spatial frequencies for isoluminant chromatic gratings.

Contrast matching was performed with isoluminant red-green and s-cone gratings at spatial frequencies ranging from 0.5 to 8 c/deg. Contrast threshold curves were low-pass in shape, in agreement with previous findings. Contrast matching functions resembled threshold curves at low contrast levels, but became flat and independent of spatial frequency at high contrasts. Thus, isoluminant chromatic gratings exhibited contrast constancy at suprathreshold contrast levels in a similar manner as has been demonstrated for achromatic gratings.

Color Perception↗
PubMed2002

Spatial frequency discrimination: a comparison of achromatic and chromatic conditions.

In this study, we have compared foveal SF discriminations for luminance and color-defined stimuli using two different tasks (criteria): in criterion-A, the discrimination is based on spatial (size of the stimuli) and/or spatial frequency; in criterion-B, it is based on apparent motion (contraction/expansion). We used high contrast (75%) spatially localized D6 stimuli and cosine gratings (0.25-9.5 cpd). The SF discrimination was measured by the method of constant stimuli with a two-interval forced-choice procedure. Data show that: (i) for criterion-A, the discrimination thresholds for color stimuli were lower than that for luminance stimuli at low SFs, but similar or higher at higher SFs; for criterion-B, the thresholds to chromatic stimuli were higher than that to achromatic stimuli for all SFs; (ii) SF discrimination was best at inter-stimulus-interval (ISI) of about 200 ms for color stimuli and at ISI of 0 ms for luminance stimuli; (iii) SF discrimination got better with stimulus duration and reached to plateau at 200 ms (or more) for color stimuli and at 67 ms (or more) for luminance stimuli; (iv) SF discrimination threshold (mean Delta(f)=0.19 octaves) is about one-tenth of the full bandwidth (mean=1.96 octaves) of SF tuned mechanisms and is in hyperacuity range; both (discrimination and hyperacuity) can be explained by the relative activities within a population of tuned mechanisms. We conclude that color and luminance SF discrimination thresholds have a different SF dependence. While color appears to perform better than luminance vision at low SFs, this effect is lost or even reversed at high SFs. Data imply that color and form interact, but color and motion are largely segregated (i.e. they weakly interact).

Adult↗
PubMed1997

Cone electroretinogram to chromatic stimuli in myopic eyes.

The cone electroretinograms (ERGs) to different chromatic stimuli were recorded in myopic subjects. Ganzfeld color flashes under bright white background illumination were used to elicit short-wavelength-sensitive (S-), and mixed long-(L-) and middle-(M-) wavelength-sensitive cone ERGs. Nineteen subjects with mild myopia (between -3.0 and -6.0 D), 12 subjects with high myopia (greater than -6.25 D) but without chorioretinal atrophy or posterior staphyloma, and 22 age-matched normal controls were compared. The S-cone and L,M-cone b-wave amplitudes decreased progressively with increasing myopia. The amplitudes of the S-cone and the L,M-cone b-wave were significantly lower in highly myopic subjects, as compared with controls. The implicit times of both b-waves were normal in most myopic subjects. The S-cone and the L,M-cone ERGs were almost equally affected in myopic eyes. The selective reduction of the S-cone pathway in high myopia, reported previously, may not originate from the other retina.

Adolescent↗
PubMed1998

Objective measurement of the off-axis longitudinal chromatic aberration in the human eye.

Longitudinal chromatic aberration (LCA) of the human eye has been studied repeatedly, but only at the fovea. Poor visual acuity prevents its subjective determination beyond a few degrees eccentricity. Consequently, we have used an objective approach, similar to that of Charman and Jennings [(1976). Vision Research 16, 999-1005], to measure ocular LCA across the visual field. To determine the validity of our double-pass approach, a direct comparison between objective and subjective results was established where possible, namely at the fovea and parafoveally (2.5 deg). In both cases we focused a monochromatic point source at four different wavelengths (458, 501.8, 543.5 and 632.8 nm). At the fovea, for a 3 mm pupil, we found a close match between subjective and objective results. However, as the subjective task became harder (off-axis or larger pupils), subjective results tended to yield slightly more myopic eyes than the results for objective refraction. In all cases, the offset was virtually independent of the wavelength used. Therefore, we have not found evidence of any biased estimates of the LCA, as determined objectively. Our foveal results show reasonable agreement with previous findings, except for slightly smaller amounts of LCA. Starting at the fovea, LCA tends to gradually increase with eccentricity, up to 40 deg, although such an increase is small, just approaching statistical significance. Computation of the LCA using a model eye predicts a slightly smaller increase with eccentricity.

Adult↗
PubMed1999

S-cone signals to temporal OFF-channels: asymmetrical connections to postreceptoral chromatic mechanisms.

Psychophysical tests of S-cone contributions to temporal ON- and OFF-channels were conducted. Detection thresholds for S-cone modulation were measured with two kinds of test stimuli presented on a CRT: a rapid-on sawtooth test and a rapid-off sawtooth test, assumed to be detected differentially by temporal ON- and OFF-channels, respectively. S-cone related ON- and OFF-temporal responses were separated by adapting for 5 min to 1 Hz monochromatic (420, 440, 450, 540, or 650 nm in separate sessions) sawtooth flicker presented in Maxwellian view. Circular test stimuli, with a sawtooth temporal profile and a Gaussian spatial taper, were presented for 1 s in one of four quadrants 1.0 degree from a central fixation point. A four-alternative forced-choice method combined with a double-staircase procedure was used to determine ON- and OFF-thresholds in the same session. Following adaptation, the threshold elevation was greater if the polarity of the test stimulus was the same as the polarity of the sawtooth adaptation flicker, consistent with separate ON- and OFF-responses from S-cones. This asymmetrical pattern was obtained, however, only when the adaptation stimuli appeared blue with a little redness. When the adaptation flicker had a clear reddish hue component, the threshold elevation did not depend on the polarity of the sawtooth test stimuli. These results are consistent with a model in which OFF-signals originating from S cones are maintained by a postreceptoral mechanism signaling redness, but not by a postreceptoral chromatic mechanism signaling blueness.

Adaptation, Ocular↗
PubMed1998

Tracing the timing of human analysis of motion and chromatic signals from occipital to temporo-parieto-occipital cortex: a transcranial magnetic stimulation study.

In human visual analysis, the initial processing of motion and chromatic signals may be mediated by feed-forward pathways from striate cortex to segregated areas of extrastriate cortex. The time-course of occipital to temporo-parieto-occipital motion processing was unknown, as was the selectivity of the effect of transcranial magnetic stimulation (TMS) on motion processing. TMS delivered over occipital cortex degraded the discrimination of motion-defined form (MDF) in a discrete time window beginning 100-120 ms from the onset of the visual stimulus. Bilateral focal TMS delivered over the temporo-parieto-occipital junction (TPO) disrupted the discrimination of MDF in a time window beginning 20-40 ms later than the effect of TMS delivered over occipital cortex. Bilateral focal TMS delivered over TPO also degraded the discrimination of CDF, motion direction, and color.

Adolescent↗
PubMed1999

S-cone contribution to pupillary responses evoked by chromatic flash offset.

On a green or red background, the action spectrum of the pupillary responses evoked following the offset of chromatic test flashes shows a prominent short-wavelength lobe and suggests the contribution from photoreceptors other than the previously inferred M- and L-cones (Kimura & Young, Vision Research (1996). 36, 1543-1550), most likely from S-cones. Systematic changes in the shape of the intensity versus amplitude functions with test wavelengths and in the shape of the short-wavelength lobe with response amplitude criteria suggest an antagonistic interaction involving the short- and longer-wavelength photoreceptors.

Color Perception↗
PubMed2000

Photoreceptor performance and the co-ordination of achromatic and chromatic inputs in the fly visual system.

White noise techniques are used to compare the two photoreceptor sub-types in blowfly retina, the short visual fibres (R1-6) that code achromatic contrast, and the long visual fibres (R7 and R8) that together code wavelength distribution and polarisation plane. Measurements of signal and noise spectra and contrast gain, taken across a broad intensity range, permit a detailed comparison of coding efficiency under natural conditions of illumination. As a function of excitation (effective photons per photoreceptor per second; h upsilon/rec per s), adaptive changes in the long and short visual fibres are similar, suggesting that post-rhodopsin their phototransduction cascades are identical. Under identical natural daylight conditions (photons per cm2 per second; h upsilon/cm2 per s) short visual fibres catch more photons, thus operating with a higher signal to noise ratio and faster response, to consistently outperform the long visual fibres. Long visual fibres compensate for their poor quantum catch by having a higher absolute gain (mV/h upsilon) which at low light intensities enables them to achieve a level of contrast gain (mV/unit contrast) similar to the short visual fibres. Differences in signal to noise ratios are related to known differences in photoreceptor structure and synaptic frequency among visual interneurons. The principles of matching sensitivity and synapse number to quantum catch described here could explain analogous differences between chromatic and achromatic pathways in mammalian and amphibian retinas.

Adaptation, Ocular↗
PubMed2003

Impact of chromated copper arsenate (CCA) in wood mulch.

The production of landscape mulch is a major market for the recycling of yard trash and waste wood. When wood recovered from construction and demolition (C&D) debris is used as mulch, it sometimes contains chromated copper arsenate (CCA)-treated wood. The presence of CCA-treated wood may cause some potential environmental problems as a result of the chromium, copper, and arsenic present. Research was performed to examine the leachability of the three metals from a variety of processed wood mixtures in Florida. The mixtures tested included mixed wood from C&D debris recycling facilities and mulch purchased from retail outlets. The synthetic precipitation leaching procedure (SPLP) was performed to examine the leaching of chromium, copper and arsenic. Results were compared to Florida's groundwater cleanup target levels (GWCTLs). Eighteen of the 22 samples collected from C&D debris processing facilities leached arsenic at concentrations greater than Florida's GWCTL of 50 microg/l. The mean leachable arsenic concentration for the C&D debris samples was 153 microg/l with a maximum of 558 microg/l. One of the colored mulch samples purchased from a retail outlet leached arsenic above 50 microg/l, while purchased mulch samples derived from virgin materials did not leach detectable arsenic (<5 microg/l). A mass balance approach was used to compute the potential metal concentrations (mg/kg) that would result from CCA-treated wood being present in wood mulch. Less than 0.1% CCA-treated wood would cause a mulch to exceed Florida's residential clean soil guideline for arsenic (0.8 mg/kg).

Arsenates↗
PubMed2001

Leaching of chromated copper arsenate wood preservatives: a review.

Recent studies have generated conflicting data regarding the bioaccumulation and toxicity of leachates from preservative-treated wood. Due to the scale of the wood preserving industry, timber treated with the most common preservative, chromated copper arsenate (CCA), may form a significant source of metals in the aquatic environment. The existing literature on leaching of CCA is reviewed, and the numerous factors affecting leaching rates, including pH, salinity, treatment and leaching test protocols are discussed. It is concluded from the literature that insufficient data exists regarding these effects to allow accurate quantification of leaching rates, and also highlights the need for standardised leaching protocols.

Arsenates↗
PubMed1985

Chromatic adaptation in a mutant of Fremyella diplosiphon incapable of phycoerythrin synthesis.

A mutant of the chromatically adapting cyanobacterium Fremyella diplosiphon, incapable of phycoerythrin synthesis but responding to wavelength modulation of its biliprotein content, was isolated. The biliprotein composition of the mutant and of the wild type were identical after growth in red light, but green light induced, in the mutant, the synthesis of a biliviolin-type chromophore bound to some of the alpha subunits of its phycocyanin. Implications of the results on the regulation and possible pathways of biliprotein biosynthesis are discussed.

Adaptation, Physiological↗
PubMed2002

Characteristics of chromated copper arsenate-treated wood ash.

The combustion of recovered wood from construction and demolition waste as biomass fuel is a common practice. When chromated copper arsenate (CCA)-treated wood is present as part of the wood fuel mix, concentrations of arsenic, chromium, and copper become elevated in the ash. The objectives of this study were to estimate the fraction of CCA-treated wood needed to cause the ash to fail regulatory guidelines and to test a series of solvents for the purpose of extracting the metals from the ash. Ash samples were prepared in an industrial furnace using samples of CCA-treated wood, mixtures of CCA-treated wood and untreated wood, and recycled wood waste collected at construction and demolition recycling facilities. Regulatory guidelines were evaluated by measuring total metals concentrations (using neutron activation analysis) and by conducting standardized leaching tests (toxicity characteristic leaching procedure (TCLP) and synthetic precipitation leaching procedure (SPLP)) on the ash. Ten different solvents, ranging from distilled water to strong acids, were also tested for their ability to extract metals. Results of this study indicate that metal concentrations (chromium plus copper plus arsenic) can be as high as 36% of the ash by weight for treated wood samples containing high retention levels (40 kg/m(3)) of CCA. All ash samples from the combustion of 100% CCA-treated wood and mixtures containing 5% CCA-treated wood leached enough arsenic (and sometimes chromium) to be characterized as a hazardous waste under US regulations. Concentrated nitric acid, which was the most effective solvent tested, was capable of removing between 70 and 100% of the copper, between 20 and 60% of the chromium, and 60 and 100% of the arsenic for samples characterized by low retention levels. A particular finding of interest was the efficiency of distilled water and other weak solvents to extract measurable amounts of chromium, especially for ash samples containing low retention levels of CCA. Citric acid was particularly effective at removing arsenic (between 40 and 100%) for ash samples produced from wood containing low CCA retention levels.

Arsenates↗