Textile dye contact allergens.
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Endotoxin exposure has been implicated in the etiology of lung disease in cotton workers. We investigated this potential relationship in 443 cotton workers from 2 factories in Shanghai and 439 control subjects from a nearby silk mill. A respiratory questionnaire was administered and pre- and postshift forced expiratory volume (FVC) and flow in one second (FEV1) were determined for each worker. Multiple area air samples were analyzed for total elutriated dust concentration (range: 0.15 to 2.5 mg/m3) and endotoxin (range: 0.002 to 0.55 microgram U.S. Reference Endotoxin/m3). The cotton worker population was stratified by current and cumulative dust or endotoxin exposure. Groups were compared for FEV1, FVC, FEV1/FVC%, % change in FEV1 over the shift (delta FEV1%), and prevalences of chronic bronchitis and byssinosis, and linear and logistic regression models were constructed. No dose-response relationships were demonstrated comparing dust concentration to any pulmonary function or symptom variable. A dose-response trend was seen with the current endotoxin level and FEV1, delta FEV1%, and the prevalence of byssinosis and chronic bronchitis, except for the highest exposure level group in which a reversal of the trend was seen. The regression coefficients for current endotoxin exposure were significant (p less than 0.05) in the models for FEV1 and chronic bronchitis but not in the models for delta FEV1% (i.e., acute change in FEV1) or byssinosis prevalence. The coefficient for dust level was never significant in the models.(ABSTRACT TRUNCATED AT 250 WORDS)
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The use of a radiolucent composite material permits easier and more accurate radiographic evaluation of the bone healing process, and results in a much lighter system. The finite element method (FEM) is employed to determine the worst possible in-service loading condition and the ring dimensions are modified accordingly. Half-ring prototypes are produced using two types of composite materials: knitted aramid fibre fabric reinforced epoxy and random short carbon (RSC) fibre reinforced epoxy. The in-plane compressive strength and axial stiffness of the complete frame are tested according to ASTM specifications. The performance is evaluated, and compared with an existing system in simulated in-service conditions.
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The objective was to determine if garnetting and raw cotton dusts differed in botanical composition. Estimates of dust composition were based on the contents of gross trash in cotton raw materials and the potential of each gross trash component to be converted into less than 10 mum particulate by a laboratory abrasion test. All types of garnetting dusts are predicted to contain a lower percent content of leaflike material than raw cotton dust. Garnetting dusts arising from linter-polyester blends are estimated to contain only 20 to 25 percent of the concentration of leaflike ingredients predicted to be present in raw cotton dusts. The low prevalence of byssinosis reported in the garnetting industry may be explained, in part, by the relatively low percent content of leaflike particulate in this cotton dust.
We have investigated transformation of eight industrial dyes by a white-rot fungus, Trametes versicolor. The fungus was found to decolorize Reactive Golden Yellow R, Procion Red, Reactive Violet 5, Reactive Blue 28, and Ponceau Red 4R at an initial dye concentration of 80 ppm within 72 h of incubation, whereas it took 5 d to completely decolorize Reactive Black 5 (40 ppm). However, it did not significantly decolorize Reactive Red 152 and Novatic Blue BC S/D. During decolorization in liquid medium, laccase and manganese-independent peroxidase (MiP) activities were detected in culture filtrate of T. versicolor. Dye-decolorizing activity of the culture was found to be associated with H2O2-dependent activity of the culture filtrate. Furthermore, dye-decolorizing activity of the culture filtrate was not influenced by Mn2+ or veratryl alcohol, thus suggesting a role of extracellular MiP in decolorization of synthetic dyes by T. versicolor.
The sorption of artificial dye effluent made from two different dyes, Solar orange 7 GLL and Solar Jade Green FFB from Clariant, onto three different agricultural residues--barley husk, sugarcane bagasse, and wheat straw--was studied. Twenty percent of 600-microm particle size of these agricultural residues was used as substrates and studied individually. The percentage of dye removal was observed in concentrations of dye varying from 50 to 200 mg/L. The effect of temperature ranging from 25 to 50 degrees C and pH from 6.0 to 12.0 on the dye removal by the substrates was also studied. The effective adsorption of the substrates was calculated.
The objective of the present study was to assess the biological decolorization of an industrial, spent reactive dyebath and its three dye components (Reactive Blue 19 [RB 19], Reactive Blue 21 [RB 21], and Reactive Red 198 [RR 198]) under methanogenic conditions. Using a mixed, methanogenic culture, batch assays were performed to evaluate the rate and extent of color removal as well as any potential toxic effects. Overall, a high rate and extent of color removal (>10 mg/[L.h] and 88%, respectively) were observed in cultures amended with either RB 19 (an anthraquinone dye) or spent dyebath at an initial dye concentration of 300 mg/L (expressed as RB 19 equivalent) and 30 g/L of NaCl. Inhibition of acidogenesis and, to a larger degree, of methanogenesis resulting in accumulation of volatile fatty acids was observed in both RB 19- and spent dyebath-amended cultures. RB 21 (a phthalocyanine dye) and RR 198 (an azo dye) tested at an initial concentration of 300 mg/L did not result in any significant inhibition of the mixed methanogenic culture. Based on results obtained with cultures amended with RB 19 with and without NaCl, as well as a control culture amended with 30 g/L of NaCl, salt was less inhibitory than either RB 19 or the dyebath. Therefore, the toxic effect of the spent dyebath is at least partially attributed to its major dye component RB 19 and NaCl. Further testing of the effect of RB 19 decolorization products on the methanogenic activity in the absence of NaCl demonstrated that these products are much less inhibitory than the parent dye. Although color removal occurred despite the severe culture inhibition, biological decolorization of full-strength reactive spent dyebaths using methanogenic cultures in a repetitive, closed-loop system is not deemed feasible. For this reason, a fermentative and halotolerant culture was developed and successfully used in our laboratory for the decolorization of industrial reactive dyebaths with 100 g/L of NaCl.
Rainbow trout, Oncorhynchus mykiss, were exposed to a sublethal dose of a wool shrinkproofing effluent for 15, 30, 45 and 60 days. Liver and blood samples were taken after the exposure time together with samples of control handled fish. A light and electron microscope study was carried out to evaluate the histopathological lesions induced in the liver of treated fish. The genotoxic potential of the effluent was assessed by piscine micronucleus test. Vacuolation of liver bile preductular cells was observed in all exposed fish; abnormal lipid accumulation and basophilic foci were seen in the liver of one 30-days- and 45-days-exposed fish, respectively. These specific alterations could be related to a pre-carcinogenic process. On the contrary, other lesions also described in all treated fish such as dilatation, vesiculation and degranulation of the rough endoplasmic reticulum, altered mitochondria, increase in myelin bodies and lysosomes and presence of phagosomes in wandering macrophages might be considered as non-specific alterations, similar to those described in fish exposed to different pollutants. Frequencies of micronucleated peripheral erythrocytes showed a significant increase following 30-days exposure.
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Themoregulatory responses were compared at an ambient temperature of 30 degrees C and a relative humidity of 50% between two kinds of protective clothing for pesticide spraying. One was made of nylon with wet coating polyurethane (A) and another was made of cotton with water repellent finish (B). The clothing ensemble was composed of a short-sleeved cotton shirt, long cotton underpants, cotton socks, shoes and the protective clothing. Five young female adults served as subjects. They took a rest with protective clothing ensemble for 15 min and then walked on a motor-driven treadmill (80m/min, 5% uphill grade) for 40 min, followed by 20-min rest. The increase of forearm sweat rate was higher in clothing A than in clothing B in 4 out of 5 subjects, although the average values were not significantly different. The total sweat rate of the whole body was also significantly larger in clothing A. Mean skin temperature and local skin temperatures in the arm, the chest and the thigh were significantly higher in clothing A than in clothing B. Clothing microclimate humidity was significantly higher in clothing A, while clothing microclimate temperature tended to be higher in clothing A. Individual observations about thermal, humidity and comfort sensation disclosed that the sensation was improved as a whole in clothing B. Local sweat rate was linearly related to mean body temperature and the regression line for clothing A was located above that for clothing B in 4 out of 5 subjects.(ABSTRACT TRUNCATED AT 250 WORDS)
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