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PubMed1999

Bond strength and failure analysis of lining materials to denture resin.

OBJECTIVES: This study was conducted to investigate the bonding properties of five lining materials to a denture base resin. Two hard (chemical-cured resin: Kooliner "Coe Labs, USA" and light-cured VLC resin: Triad "Dentsply, USA") and three soft (chemical-cured resin: Express "Alcos,-USA", heat-temperature vulcanized 'HTV' silicone material: Molloplast-B "Regneri GmbH, Germany" and room-temperature vulcanized 'RTV' silicone material:Ufi Gel-P "Voco, Germany") liners were used. METHODS: Paladent 20 "Heraeus Kulzer GmbH, Germany", a conventional heat-cured polymethylmethacrylate (PMMA), was used as the denture base resin and as the control material. Bonding strength and adhesion properties of the liners to PMMA were compared by tensile test and scanning electron microscope (SEM) analysis. After curing, an aging process was applied and the samples were immersed and stored in distilled water at 37 +/- 1 degrees C and taken out at certain aging intervals (at 0, 15, 30 and 90 days) for examination. Specimens (168) were processed for tensile tests and other specimens (24) for fracture tests. The mean and standard deviation values were calculated. Changes in the mechanical properties and the SEM findings of the adhered surfaces were evaluated. RESULTS: Triad (a hard liner) has the closest tensile strength to the control, indicating the strongest bonding between the base and the liner. Also, during the aging process, formation of better adhesion was observed in SEM micrographs. From the SEM analysis it was found that, Molloplast-B (a soft liner) also has a very good filling capacity. SIGNIFICANCE: Among the hard lining materials, VLC resin to chemical-cured resin; and among the soft lining materials, HTV resin to RTV and chemical-cured ones should be preferred for relining procedures. Molloplast-B and Express as resilient liners were found to have adequate adhesive values for clinical use.

Adhesiveness↗
PubMed1997

Adhesive composite resins for artificial teeth: a laboratory investigation of bond strength to a cobalt-chromium alloy.

Adhesive resin systems are reported to improve the bond strength between resins and cast cobalt-chromium alloy. This investigation compares the behaviour of three resin systems. Cylinders and beams of cobalt-chromium, with 0.6-mm-diameter retention beads regularly cast onto the bonding surfaces, were air-abraded and ultrasonically cleaned. Resin veneers 4 mm deep on the cylinders and 2 mm on the bars were polymerized by heat and pressure or by light. Specimens were water-stored for 7 or 90 days, including thermocycling between 4, 37 and 60 degrees C, before testing in a Universal Testing Machine to examine the shear bond strength or the effect of the bonded resin spine on the flexural strength of the beams using a three-point bend test. Specimens were examined with an optical microscope to attempt to determine the nature of the failures that occurred. The investigation showed that, overall, the heat- and pressure-cured urethane dimethacrylate resin with and adhesive based upon methacrylic acid performed significantly less well than a conventional acrylic resin, or a hybrid composite resin with and adhesive monomer.

Chromium↗
PubMedDate not supplied

Solid phase extraction purification of carboxylic acid products from 96-well format solution phase synthesis with DOWEX 1x8-400 formate anion exchange resin.

The anion exchange resin DOWEX 1x8-400 formate has been developed for the isolation or resin capture of carboxylic acids from solution phase reactions in a 96-well format using a batchwise solid phase extraction technique. Eleven different anion exchange resins (formate forms) were evaluated for their efficiency at scavenging aryl and aliphatic carboxylic acids from solution. The model carboxylic acids had pK(a)s ranging from 3.40 to 4.89. Exchange efficiency onto the resin was pK(a) dependent with the carboxylic acids but not with their diisopropylethylammonium salts. Exchange off of the resin also showed pK(a) dependence with the stronger acids requiring more concentrated solvent acid for exchange. DOWEX 1x8-400 formate was determined to have superior capacity and the fastest exchange rate. Solvents suitable for exchanging the acids onto the resin were CH2Cl2, methanol, and various solvent/water mixtures. Solvents suitable for exchanging the carboxylic acids off of the resin were TFA/solvent or HCO2H/solvent mixtures. The resin was found to swell best in CH2Cl2 and in polar protic solvents such as water, alcohols, and acids. Application of this technique to the crude product mixtures from an arrayed reductive amination and an arrayed Stille reaction provided product carboxylic acids in yields averaging 57% and purities averaging 89%.

Journal Article↗
PubMed2000

Preparation of Designer Resins via Living Free Radical Polymerization of Functional Monomers on Solid Support.

Merrifield resin is converted to a solid-supported free radical initiator by reacting with the TEMPO-Na. Heating TEMPO-methyl resin with a variety of functionalized styrene and acrylate monomers gives larger resin beads via living free radical polymerization. We have coined the term Rasta resin to describe resin beads prepared in this fashion. The process can be described as a solvent-free suspension polymerization. It is particularly well suited for preparation of resin beads from monomers which contain electrophilic groups that would be destroyed upon suspension polymerization in water. Rasta resins have a novel macromolecular architecture wherein long straight chain polymers bearing reactive functional groups emanate from the phenyl groups of a cross-linked polystyrene core. With judicious choice of co-monomers and polymerization strategy, the solvent affinity, loading capacity, and distance of functionality from the cross-linked core may be controlled giving beads with properties that are tailored to specific uses as synthesis supports and scavenging resins.

Journal Article↗
PubMed2004

Suspension ring-opening metathesis polymerization: the preparation of norbornene-based resins for application in organic synthesis.

A series of norbornene-based resin beads were obtained by aqueous suspension ring-opening metathesis polymerization (ROMP) and used as polymeric supports for organic synthesis. These resins were prepared from norbornene, norborn-2-ene-5-methanol, and cross-linkers such as bis(norborn-2-ene-5-methoxy)alkanes, di(norborn-2-ene-5-methyl)ether, and 1,3-di(norborn-2-ene-5-methoxy)benzene. The resulting unsaturated ROMP (U-ROMP) resins containing olefin repeat units were chemically modified using hydrogenation, hydrofluorination, chlorination, and bromination reactions to produce saturated ROMP resins with different chemical and physical properties. The hydrogenated ROMP (H-ROMP) resin was found to be highly resistant to acidic, basic, Lewis acid, and Birch reduction conditions and was assessed as a polymeric support in a series of solid-phase synthetic applications. The H-ROMP resin was found to have superior performance compared to polystyrene-divinylbenzene (PS-DVB) copolymers in aromatic nitration and acylation reactions. In a conventional five-step solid-phase synthesis of a hydantoin, similar results were obtained for both the H-ROMP and PS-DVB resins. The U-ROMP resin was also shown to be effective in the solid-phase syntheses of benzimidazoles and benzimidazolones.

Journal Article↗
PubMed1996

Correlation between Solvation of Peptide-Resins and Solvent Properties(1).

The solvation properties of model resin and peptide-resins measured in ca. 30 solvent systems correlated better with the sum of solvent electron acceptor (AN) and electron donor (DN) numbers, in 1:1 proportion, than with other solvent polarity parameters. The high sensitivity of the (AN+DN) term to detect differentiated solvation behaviors of peptide-resins, taken as model of heterogeneous and complex solutes, seems to be in agreement with the previously proposed two-parameter model, where the sum of the Lewis acidity and Lewis basicity characters of solvent are proposed for scaling solvent effect. Besides these physicochemical aspects regarding solute-solvent interactions, important implications of this study for the solid phase peptide synthesis were also observed. Each class of peptide-resin displayed a specific solvation profile that was dependent on the amount and the nature of the resin-bound peptide sequence. Plots of resin swelling versus solvent (AN+DN) values allowed the visualization of a maximum solvation region characteristic for each class of resin. This strategy facilitates the selection of solvent systems for optimal solvation conditions of peptide chains in every step of the entire synthesis cycle. Moreover, only the AN and DN concepts allow the understanding of rules for solvation/shrinking of peptide-resins when in homogeneous or in heterogeneous mixed solvents.

Journal Article↗
PubMed2001

Fracture force, deflection at fracture, and toughness of repaired denture resin subjected to microwave polymerization or reinforced with wire or glass fiber.

STATEMENT OF PROBLEM: The ultimate goal of denture repair is to restore the denture's original strength and avoid further fracture. The best materials and methods for repair have not been conclusively determined. PURPOSE: This study investigated the fracture force, deflection at fracture, and toughness of a heat-polymerized denture base material repaired with heat-polymerized resin, autopolymerized resin alone, or autopolymerized resin with glass fiber or wire reinforcement. MATERIAL AND METHODS: Eight groups were evaluated: 6 with autopolymerized resin repairs, 1 with heat-polymerized resin repairs, and a control group of intact specimens. The 6 autopolymerized resin groups included 1 group with no reinforcement, 1 treated with microwave irradiation after polymerization, 2 with monolayer or multilayer glass fiber reinforcement, and 2 with round or braided wire reinforcement. Each group consisted of 12 specimens. The experimental specimens were cut, and a 3-mm butt joint gap was repaired as indicated by the group assignment. A 3-point bending test was used to determine the fracture force, deflection at fracture, and toughness of the specimens. The data were analyzed with 1-way analysis of variance and the Tukey post-hoc test (alpha=.05). RESULTS: The fracture force (28.4 to 73.4 N), deflection (1.6 to 3.8 mm), and toughness (0.02 to 0.13 J) values for all repaired groups were significantly lower than those for the control group (82.79 N, 4.4 mm, and 0.16 J, respectively), with one exception: the mean fracture force of specimens reinforced with round wire (102.9 N). Failure mode was always adhesive, meaning that fracture occurred between the denture base and repair resin. CONCLUSION: Among the repair treatments tested, the most effective was microwave-irradiated, autopolymerized resin reinforced with round wire or monolayer glass fiber ribbon.

Analysis of Variance↗
PubMed2004

[The effect of woven glass fiber reinforced composites on the transverse strength of three denture base resins].

PURPOSE: This study evaluated the effect of woven glass fiber reinforced composite (FRC) on transverse strength of denture base materials. METHODS: Three denture base resins (heat-activated resin, autopolymerizing resin and microwave-activated resin) and FRC (Vectris Frame, Ivoclar-Vivadent) were selected for the study. The FRC was light-cured and sandwiched in the middle of denture base resin and then the specimen was polymerized according to manufacturers' instructions in a gypsum mold with a cavity of 65 mm x 10 mm x 2.5 mm. Each specimen was immersed in 37 degrees C distilled water for 50 hours. The control group was without FRC. Ten specimens were fabricated for each group. The transverse strength test was performed on a universal testing machine at a crosshead speed of 5 mm/min. RESULTS: The transverse strengths of all denture base resins reinforced with FRC were significantly higher than that of denture base resin bulk. CONCLUSIONS: Within the limitation of the current study, the FRC has an effect upon reinforcement of denture base resin.

English Abstract↗
PubMed2006

Modification of 4-META/MMA-TBB resin for safe debonding of orthodontic brackets--influence of the addition of degradable additives or fluoride compound.

The purpose of this study was to evaluate the performance of modified 4-META/MMA-TBB resin cements (Superbond C&B) in terms of debonding orthodontic brackets easily and safely from enamel without the loss of proper bracket bond strength. Poly (DL-lactide-co-glycolide) (PLGA), calcium fluoride (CaF2), or alpha-tricalcium phosphate (alpha-TCP) was added to the polymer powder of 4-META/MMA-TBB resin, and the shear bond strength of orthodontic brackets to human enamel using modified resins was measured before and after 10,000-cycle thermal cycling test between 5 degrees C and 55 degrees C. The modified resins tended to provide lower bond strength compared with the original 4-META/MMA-TBB resin. However, alpha-TCP- or CaF2-modified resin showed no significant differences in bond strength before and after thermal cycling. Moreover, there was a tendency of more residual resin remaining on the tooth surface after debonding, thereby suggesting a lower risk of enamel fracture. In conclusion, alpha-TCP- or CaF2-modified 4-META/MMA-TBB resin seemed to allow easy and safe debonding of orthodontic brackets without loss of proper bracket bond strength.

Acid Etching, Dental↗
PubMed1998

The effect of glass ionomer cement or composite resin bases on restoration of cuspal stiffness of endodontically treated premolars in vitro.

The purpose of the present study was to decide whether composite resin or conventional glass ionomer cement should be preferred as a base material in endodontically treated premolars. Twelve extracted human maxillary premolars were mounted in a universal testing machine at a 35 degrees angle. Cuspal stiffness was determined by applying a load of 75 N to the buccal cusp and recording the displacement of the cusp using inductive displacement transducers. In the same teeth, different cavity preparations and restorations were performed sequentially. Standard MOD cavities were enlarged to allow endodontic access. In addition, the cusps were undermined. Half of the teeth were restored to the level of the previous shallow cavities using conventional glass ionomer cement (Ketac Fil), in the rest of the teeth dentine bonding agent (Syntac) and composite resin (Tetric) were used instead. Finally, composite resin fillings (Tetric) were placed. All restorations were removed and the experiments were repeated twice. For each replication, the assignment of the base materials to the experimental groups was reversed, and ceramic inlays (Empress) were used as final restorations for the last replication. Improvement of cuspal stiffness achieved by conventional glass ionomer bases was very small, whereas composite resin bases increased cuspal stability by more than a factor of two. After placement of the final restorations, however, there was no longer a difference between teeth with different base materials. Nevertheless, composite resin bases might be preferred for two reasons. Firstly, deterioration of adhesive restorations will probably start at the cavosurface margins. The incidence of margin gaps, however, will not only compromise marginal seal but also the stabilizing effect of the restoration. In this situation, the resin base may still stabilize the tooth. Moreover, resin bases may reduce the risk of cusp fracture during the time between cavity preparation and the insertion of adhesive inlays.

Aluminum Silicates↗
PubMed1986

A new visible light-cured resin system applied to removable prosthodontics.

Preliminary studies of VLC resins have produced promising results; however, additional research is necessary to completely define qualities of this material. Biologic testing of VLC (Triad) resins indicated that they are nontoxic and biocompatible. They have a wide range of uses in all subdisciplines of prosthodontics. Advantages such as accuracy of fit, superior strength, complete polymerization without residual compounds, ease of fabrication and manipulation, patient acceptance, ability to bond with other denture base resins, and low bacterial adherence make this material an important addition to the choices available to dentists. As with many new materials, there are initial problems or hurdles that must be overcome before there is widespread use. Initial formulations of material had insufficient flexural strength and tended to fracture when flexed over uncut sites on a stone cast. This problem has been reduced by Dentsply International, Inc. with the introduction of the new improved formulation. The original VLC bonding agent did not provide sufficient bond strength with acrylic resin denture base materials, but this also has been improved with development of a new VLC bonding agent. The problem of microporosity and small voids produced when adapting VLC resin sheets against a stone cast may be overcome with pressure or vacuum adaptation techniques. A promising application of VLC resin material is in direct intraoral procedures such as relining of dentures. Physical and chemical properties are superior to autopolymerizing methacrylates. Preliminary studies have shown successful patient acceptance to this clinical procedure. It is of particular advantage to the patient not to be without dentures for the period of at least 1 day necessary for a laboratory-processed relining. Immediate light-curing is time-saving and convenient compared to indirect (heat-cured) relining. Until recently, most direct intraoral applications of autopolymerizing acrylic resin reliner material were considered temporary or expedient to a permanent procedure. The patient and dentist may now have another treatment choice. The release of residual methyl methacrylate, among other shortcomings of AP materials, is not a concern when using the VLC reliner material. Some patients may notice a nonobjectionable taste to the uncured material; however, they can be reassured that the taste will be only temporary until the material is completely polymerized in the curing unit. The flow of the material can be regulated by selection of appropriate viscosity, warming and cooling measures, and partial intraoral polymerization with hand-held curing lights.(ABSTRACT TRUNCATED AT 400 WORDS)

Acrylic Resins↗
PubMed1986

Escherichia coli adherence to anion exchange resin. In vitro model for initial screening of potential antiadherence agents.

The first step in developing a bladder infection is attachment of bacteria to the bladder epithelium. Removing the bladder mucin increases bacterial adherence up to a thousand-fold, and this increase can be prevented by pretreating the mucin-deficient bladder with heparin. To develop a rapid, in vitro antiadherence screening assay, we studied the adherence of Escherichia coli to various chromatography resins and the ability of heparin and other agents to antagonize this attachment. The results can be summarized as follows: Although E. coli attached to all resins, only the adherence to the anion exchange resin was inhibited by heparin (up to 95%). Agents which did not effect E. coli adherence to the resin did not affect attachment to the bladder. Agents which inhibited E. coli adherence to the bladder also inhibited E. coli adherence to the resin. Similar to the effect of heparin on E. coli attachment, the adherence of Klebsiella ozaene, Proteus mirabilis, and Streptococcus fecalis to both bladder epithelium and anion exchange resin were also antagonized. These studies indicate that the adherence of E. coli (as well as other bacterial species) to anion exchange resin responds to heparin and other chemical agents in a similar manner as does adherence to the mucin-deficient rabbit urinary bladder. Because of the ease and rapid nature of this in vitro assay, it serves as a useful screen for potential bacterial antiadherence agents and could be used to help elucidate mechanisms of bacterial attachment.

Adhesiveness↗
PubMed1996

Regional bond strengths of resins to human root dentine.

OBJECTIVES: The demand for restoration of root dentine defects such as cervical erosion and root caries has significantly increased recently, but there is limited information on the performance of the adhesive resins to radicular dentine. The purpose of this study was to measure the regional tensile bond strength (TBS) of composite bonded to human root and coronal dentine, and to observe the interface between resin and root dentine by SEM. METHODS: Human extracted cuspid teeth were used to measure TBS with a new microtensile bond test. Enamel and cementum were removed from the labial tooth surfaces to form a long cavity preparation into dentine from the mid-crown to the apex of the root within the same tooth. All Bond 2 (all etch technique) or Imperva Bond (no etch) was bonded to dentine surfaces and covered with Protect Liner resin composite. The resin-bonded teeth were serially sliced into 16 sections at right angles to the long axis of the tooth, and the bonded surfaces were trimmed to give a bonded surface area of 1 mm2 for TBS testing. RESULTS: All Bond 2 bond strengths to coronal and apical dentine showed high values (23.5 MPa) but the bond strength was significantly lower on cervical root dentine. Imperva Bond produced a relatively high tensile bond strength to all regional areas. SEM showed that the thickness of the resin-infiltrated layer formed by All Bond 2 in root dentine was less than coronal areas. Resin infiltration with Imperva Bond was always less than 0.5 micron. The results suggest that high TBS values can be obtained with minimal resin infiltration in root dentine.

Acid Etching, Dental↗
PubMed2006

Experimental and computational approach for evaluating the mechanical characteristics of dental composite resins with various filler sizes.

This study aimed to investigate the influence of particle size of fillers on flexural properties of dental composite resins by laboratory testing with computational analysis validation. Four kinds of silica fillers with mean particle sizes of 3.3, 4.3, 7.9, and 15.5 microm were used. Filler content was kept constant at 70 mass% (or 53.8 vol.%). The three-point bending test was performed with a constant loading speed of 1.0mm/min, and a span length of 20mm using an Instron machine, in order to measure flexural strength and modulus of composite resins with various particle sizes. Test specimens were 2-mm wide, 2-mm thick, and 25-mm long rectangular bars. Furthermore, a numerical simulation using three-dimensional finite element (FE) analysis was performed to investigate stress distribution in composite resins under loading. As a result, flexural strength decreased with increasing particle size of the filler of the composite resins (p<0.05). On the other hand, there was no significant difference in Young's modulus among composite resins with various filler sizes (p>0.05). Moreover, FE analysis indicated that stress concentration increased with increasing particle size in agreement with experimental results of flexural strength. In conclusion, within the limitations of this investigation, we confirmed that flexural strength of composite resins decreased with increasing filler particle size. In addition, FE analysis was effective for evaluating stress distributions of dental composite resins with various filler sizes.

Acrylic Resins↗
PubMed2005

Mechanical stability of resin-dentin bond components.

OBJECTIVES: To evaluate the effects of long-term storage on the mechanical properties of the components of resin-dentin bonds, that is, resin composite, adhesive system, demineralized and mineralized dentin. METHODS: Specimens of resin composite (Z250) and adhesive systems (Single Bond-SB; One-Step-OS and Clearfil Liner Bond 2V-CL) were cast in molds. Dentin specimens were prepared from dentin discs obtained from the crowns of extracted human molars. Specimens of demineralized dentin were obtained by immersion of dentin discs for 6 days in 0.5 mol/l EDTA (pH 7.0). Both dentin and resin-based substrates were shaped to hourglass or I-beam specimens that were used to determine the true stress (TS) or apparent modulus of elasticity (E), respectively. Control specimens were subjected to tensile testing at 0.6 mm/min after 24 h of immersion in distilled water. Experimental specimens were stored at 37 degrees C in either distilled water or mineral oil and tested after 12 months. The data of each group were individually analyzed by ANOVA and Tukey's test. RESULTS: Both TS and E of the resin-based materials decreased significantly after 12 months of storage in water (p < 0.05) except the TS of SB (p > 0.05). No changes were observed for specimens of mineralized dentin, regardless of storage condition (p > 0.05). Storage of demineralized dentin in water did not cause any significant effect in either TS or E (p > 0.05), however, significant reductions of TS and E of demineralized dentin occurred after storage in oil for 1 year (p < 0.05). SIGNIFICANCE: Storage time and medium may be deleterious to the mechanical properties of the resin-dentin bond components, which ultimately could compromise the durability of resin-dentin bonds.

Analysis of Variance↗
PubMed2006

Mechanical properties and bond strength of dual-cure resin composites to root canal dentin.

OBJECTIVES: To evaluate the regional mechanical properties of dual-cure resin composites and their regional bond strengths to root canal dentin. METHODS: One of the following dual-cure resin composites was placed in artificial post spaces: Unifil Core (UC), Clearfil DC Core (DC), Build-It FR (BI), Clearfil DC Core-automix (DCA), and photo-cured for 60s. After 24h storage, each specimen was serially sliced to harvest eight hour-glass shaped specimens for measurement of regional ultimate tensile strength (UTS), and the remaining eight semi-circular slabs were polished for the measurement of Knoop Hardness Number (KHN). For the microtensile bond strength (muTBS) test, post cavities were prepared in human premolar roots, and the cavity surfaces treated with Clearfil SE Bond and photo-cured for 10s. The post spaces were then filled with one of the above resin composites and photo-cured for 60s. After 24h storage, each specimen was serially sliced into 8, 0.6x0.6 mm-thick beams for the muTBS test. The data were divided into coronal and apical regions and analyzed using ANOVA and post hoc test (alpha=0.05). RESULTS: UTS and KHN were affected by the type of dual-cure resin composite and region (p<0.0001). There was no relationship between UTS and KHN for each material. The auto-mix type of resin composite possessed superior UTS to that of the hand-mix type. muTBS among the four composite materials were not significantly different at both apical and coronal regions (p>0.05). Regional differences in bond strengths were found for all materials (p<0.05). SIGNIFICANCE: The UTS and KHN of the dual-cure resin composites varied among each material, however, differences in the mechanical properties of the resin core materials did not affect their adhesion to root canal dentin.

Composite Resins↗
PubMed2006

Effect of surface conditioning methods on the microtensile bond strength of resin composite to composite after aging conditions.

OBJECTIVES: This study evaluated the effect of two different surface conditioning methods on the repair bond strength of a bis-GMA-adduct/bis-EMA/TEGDMA based resin composite after three aging conditions. METHODS: Thirty-six composite resin blocks (Esthet X, Dentsply) were prepared (5 mm x 6 mm x 6 mm) and randomly assigned into three groups for aging process: (a) immersion in citric acid (pH 3.0 at 37 degrees C, 1 week) (CA); (b) boiling in water for 8h (BW) and (c) thermocycling (x5000, 5-55 degrees C, dwell time: 30s) (TC). After aging, the blocks were assigned to one of the following surface conditioning methods: (1) silica coating (30 microm SiO(x)) (CoJet, 3M ESPE)+silane (ESPE-Sil) (CJ), (2) phosphoric acid+adhesive resin (Single Bond, 3M ESPE) (PA). Resin composite (Esthet.X) was bonded to the conditioned substrates incrementally and light polymerized. The experimental groups formed were as follows: Gr1:CA+PA; Gr2:CA+CJ; Gr3:BW+PA; Gr4: BW+CJ; Gr5:TC+PA; Gr6: TC+CJ. The specimens were sectioned in two axes (x and y) with a diamond disc under coolant irrigation in order to obtain non-trimmed bar specimens (sticks, 10 mm x 1 mm x 1 mm) with 1 mm(2) of bonding area. The microtensile test was accomplished in a universal testing machine (crosshead speed: 0.5 mm min(-1)). RESULTS: The means and standard deviations of bond strength (MPa+/-S.D.) per group were as follows: Gr1: 25.5+/-10.3; Gr2: 46.3+/-10.1; Gr3: 21.7+/-7.1; Gr4: 52.3+/-15.1; Gr5: 16.1+/-5.1; Gr6, 49.6+/-13.5. The silica coated groups showed significantly higher mean bond values after all three aging conditions (p<0.0001) (two-way ANOVA and Tukey tests, alpha=0.05). The interaction effect revealed significant influence of TC aging on both silica coated and acid etched groups compared to the other aging methods (p<0.032). Citric acid was the least aggressive aging medium. SIGNIFICANCE: Chairside silica coating and silanization provided higher resin-resin bond strength values compared to acid etching with phosphoric acid followed by adhesive resin applications. Thermocycling the composite substrates resulted in the lowest repair bond strength compared to citric acid challenge or boiling in water.

Acrylic Resins↗
PubMed2004

Adhesive permeability affects coupling of resin cements that utilise self-etching primers to dentine.

OBJECTIVES: To examine the effects of an experimental bonding technique that reduces the permeability of the adhesive layer on the coupling of resin cements to dentine. METHODS: Extracted human third molars had their mid to deep dentin surface exposed flat by transversally sectioning the crowns. Resin composite overlays were constructed and cemented to the surfaces using either Panavia F (Kuraray) or Bistite II DC (Tokuyama) resin cements mediated by their respective one-step or two-step self-etch adhesives. Experimental groups were prepared in the same way, except that the additional layer of a low-viscosity bonding resin (LVBR, Scotchbond Multi-Purpose Plus, 3M ESPE) was placed on the bonded dentine surface before luting the overlays with the respective resin cements. The bonded assemblies were stored for 24 h in water at 37 degrees C and subsequently prepared for microtensile bond strength testing. Beams of approximately 0.8 mm(2) were tested in tension at 0.5 mm/min in a universal tester. Fractured surfaces were examined under scanning electron microscopy (SEM). Additional specimens were prepared and examined with TEM using a silver nitrate-staining technique. RESULTS: Two-way ANOVA showed significant interactions between materials and bonding protocols (p<0.05). When bonded according to manufacturer's directions, Panavia F produced bond strengths that were significantly lower than Bistite II DC (p<0.05). The placement of an additional layer of a LVBR improved significantly the bond strengths of Panavia F (p<0.05), but not of Bistite II DC (p>0.05). SEM observation of the fractured surfaces in Panavia F showed rosette-like features that were exclusive for specimens bonded according to manufacturer's directions. Such features corresponded well with the ultrastructure of the interfaces that showed more nanoleakage associated with the more permeable adhesive interface. The application of the additional layer of the LVBR reduced the amount of silver impregnation for both adhesives suggesting that reduced permeability of the adhesives resulted in improved coupling of the resin cements to dentin. CONCLUSIONS: Placement of an intermediate layer of a LVBR between the bonded dentine surface and the resin cements resulted in improved coupling of Panavia F to dentine.

Acid Etching, Dental↗