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Comparisons of surface roughnesses and sliding resistances of 6 titanium-based or TMA-type archwires.

Six titanium-based or TMA-type archwires (Beta III, Resolve, CNA, TMA, low-friction ion-implanted TMA or TMAL, and TiMolium) were studied as functions of composition, morphology, surface roughness, and sliding mechanics by using a scanning electron microscope, an x-ray energy dispersive wavelength analyser, a laser specular reflectometer, and a frictional testing machine. In the last instrument, all wires were coupled with 0.022-in stainless steel brackets in which normal forces were applied by 0.010-in stainless steel ligatures. With regard to composition, 5 wires were true beta-titanium alloys having nominal compositions of 80% titanium, 10% molybdenum, 6% zirconium, and 4% tin, and 1 was an alpha-beta alloy having a nominal composition of 90% titanium, 6% aluminum, 3% vanadium, and 1% other. Morphologies varied from surfaces with striations, scale, or layers of drawn material that suggested surface steps or fissures. Specular reflectance and optical roughness measurements divided the archwires into 2 groups of 3: Beta III, Resolve, and CNA had an overall mean value of 0.148 microm; and TMA, TMAL, and TiMolium had a mean overall value of 0.195 microm. These roughness measurements and their accompanying details of the compositional analyses suggested that there could be as few as 2 vendors manufacturing the 5 beta-titanium products. For 6 different values of angulation that embraced the passive and active regions of sliding, the coefficients of friction varied rather narrowly from 0.17 to 0.27 and were independent of surface roughnesses. Although these contemporary products are better than their predecessors of over a decade ago, other issues might be more important than surface finishes or frictional resistances because all products appear fairly comparable.

Alloys↗

Production of radioactive particles for endovascular therapeutic interventions.

Recanalization is a common phenomenon that decreases the efficacy of embolization procedures. It can be inhibited by beta-radiation. Two novel ways of producing radioactive particles are described, by neutron beam irradiation of gold-containing microspheres, or by using the 32P binding capacity of zirconium-containing microspheres. Particles were tested in vivo, to assess their ability to deliver radioactivity locally, using canine renal artery, porcine rete mirabile, and rabbit ear embolization models. Both radioactive microspheres (198Au and 32P) showed no detectable activity outside the target territory. 32P microspheres demonstrated typical radiation changes in a porcine rete mirabile arteriovenous malformation model.

Animals↗

Adsorption and removal of As(V) and As(III) using Zr-loaded lysine diacetic acid chelating resin.

An adsorption process for the removal of As(V) and As(III) was evaluated under various conditions using zirconium(IV) loaded chelating resin (Zr-LDA) with lysine-Nalpha,Nalpha diacetic acid functional groups. Arsenate ions strongly adsorbed in the pH range from 2 to 5, while arsenite was adsorbed between pH 7 and 10.5. The sorption mechanism is an additional complexation between arsenate or arsenite and Zr complex of LDA. Adsorption isotherm data could be well interpreted by Langmuir equation for As(V) at pH 4 and As(III) at pH 9 with a binding constant 227.93 and 270.47 dm3 mol(-1) and capacity constant 0.656 and 1.1843 mmol g(-1), respectively. Regeneration of the resin was carried out for As(V) using 1 M NaOH. Six adsorption/desorption cycles were performed without significant decrease in the uptake performance. Column adsorption studies showed that the adsorption of As(V) is more favorable compared to As(III), due to the faster kinetics of As(V) compared to As(III). Influence of the coexisting ions on the adsorption of As(V) and As(III) was studied. The applicability of the method for practical water samples was studied.

Acetates↗

New stationary phases for high-performance liquid chromatography based on poly(methyltetradecylsiloxane) thermally immobilized onto zirconized silica.

The modification of silica with zirconium oxide followed by sorption and thermal immobilization of poly(methyltetradecylsiloxane) (PMTDS) is used to prepare a reversed stationary phase for high-performance liquid chromatography. The thermal immobilization of PMTDS on zirconized silica was optimized using a central composite design. The new stationary phase was characterized by spectroscopic and chromatographic methods. Stationary phases with good reproducibility and good chromatographic performance for various compounds were obtained. PMTDS thermally immobilized on zirconized silica presented quite significant chemical stability at pH 10 and 50 degrees C.

Chromatography, High Pressure Liquid↗

Sulfated nanozirconia: an investigation on acid-base properties and n-butane isomerization activity.

Hydrated zirconia was synthesized by an organo-inorganic route employing surfactant and was sulfated using aqueous ammonium persulfate, followed by drying at 110 degrees C. The sample thus obtained was calcined at 600 degrees C to obtain sulfated zirconia and was characterized by several physicochemical methods. Crystallite sizes of sulfated zirconia were calculated from X-ray line broadening using the Debye-Scherer equation and were found to be in the range of 25 nm. When pretreated in air, the catalyst was found to exhibit butane isomerization activity at a temperature as low as 35 degrees C under atmospheric pressure. It showed conversion as high as 37% at 100 degrees C under normal pressure when pretreated in air, whereas nitrogen-pretreated catalyst showed zero activity under similar conditions. NH(3) and CO(2) temperature-programmed desorption studies on air- and helium-pretreated samples indicated that the catalyst surface changes appreciably during air pretreatment. Results on butane isomerization in conjunction with TPD studies suggest that zirconium-oxy sites play an important role in butane activation during the reaction.

Butanes↗

Adsorption of Co(II), Ni(II), Cu(II), and Zn(II) on hexagonal templated zirconia obtained thorough a sol-gel process: the effects of nanostructure on adsorption features.

Using zirconium tetrabutoxide, diaminedecane, and diamineoctane as precursors, a templated hexagonal zirconia matrix is synthesized and characterized by X-ray diffractometry and scanning electron microscopy. The adsorption capacity of such a matrix toward Co(II), Ni(II), Cu(II), and Zn(II) from aqueous solutions is studied. The adsorption affinity of the synthesized hexagonal templated zirconia toward the cations is Cu(II)>Zn(II) >>Ni(II)>Co(II). It is also verified that the adsorption of the cations follows a Langmuir and not a Freundlich isotherm. All obtained isotherms are of type I, according to the IUPAC classification. The observed adsorption affinity sequence can be explained by taking into account the velocity constant for the substitution of water molecules into the cation coordination spheres, as well as the Irving-Williams series.

Adsorption↗

Synthesis and characterization of a new inorganic cation-exchanger-Zr(IV) tungstomolybdate: analytical applications for metal content determination in real sample and synthetic mixture.

An amorphous sample of inorganic cation-exchanger Zr(IV) tungstomolybdate was prepared by mixing varying ratios of 0.1M aqueous solution of sodium tungstate and 0.1M aqueous solution of sodium molybdate into 0.1M aqueous solution of zirconium oxychloride at pH 1. This cation-exchanger was found to have a good ion-exchange capacity (2.40 mequiv.g(-1) for Na(+)), high thermal and chemical stability. A tentative structural formula was proposed on the basis of chemical composition, FTIR and thermogravimetric analysis. Distribution coefficients (K(d)) values of metal ions in various solvent systems were determined. Some important and analytically difficult quantitative binary separations viz. Ni(II)-Pb(II), Ni(II)-Zn(II), Ni(II)-Cd(II), Mg(II)-Al(III), etc. were achieved. The practical applicability of the cation-exchanger was demonstrated in the separation of Cu(II)-Zn(II) from a synthetic mixture as well as from real samples of pharmaceutical formulation and brass alloy.

Cation Exchange Resins↗

Sample-specific diamagnetic and paramagnetic passive shimming.

When homogenizing the static magnetic field over extended in vivo volumes, significant residual inhomogeneity can remain after spherical harmonic shim optimization. This is due to the low spatial orders of shims available on in vivo MR systems and the presence of higher-order inhomogeneity in the vicinity of anatomic air cavities. Mediation of this problem through the development of higher-order spherical harmonic shims is severely impeded by bore space limitations. Sample-specific passive shims are not limited to low-order spatial compensation and offer an alternative means to increased homogenization. Here, we present a novel construction protocol for sample-specific passive shims comprised of both diamagnetic (bismuth) and paramagnetic (zirconium) materials. A prototype shim is constructed and shown to significantly homogenize the mouse brain at 9.4 T. Further homogenization capabilities are simulated through alteration of the shim construction.

Animals↗

Flexural strength of a layered zirconia and porcelain dental all-ceramic system.

STATEMENT OF PROBLEM: New processing techniques have facilitated the use of zirconia core materials in all-ceramic dental prostheses. Zirconia has many potential advantages compared to existing core materials; however, its performance when layered with porcelain has not been evaluated. PURPOSE: This study investigated the strength of a wide variety of layered zirconia and porcelain beams to determine whether the inclusion of zirconia cores results in improved strength. MATERIAL AND METHODS: Eight types of layered or simple zirconia and porcelain beams (n = 10), approximately fixed partial denture-size, were made of a tetragonal polycrystalline zirconium dioxide partially stabilized with yttria core (Lava System Frame) and a feldspathic dental porcelain (Lava Ceram veneer ceramic). Elastic moduli of the materials were measured using an acoustic method. Maximum force and modulus of rupture were determined using 3-point flexural testing and a universal testing machine. Descriptive statistical methods were used. RESULTS: Beams with porcelain tensile surfaces recorded mean tensile strengths or moduli of rupture from 77 to 85 MPa, whereas beams with zirconia tensile surfaces recorded moduli of rupture almost an order of magnitude higher, 636 to 786 MPa. The elastic moduli of the porcelain and zirconia materials were 71 and 224 GPa, respectively. Crack propagation following initial tensile cracking often involved the porcelain-zirconia interface, as well as bulk porcelain and zirconia. CONCLUSION: The layered zirconia-porcelain system tested recorded substantially higher moduli of rupture than have been previously reported for other layered all-ceramic systems.

Dental Porcelain↗

Sorption materials for arsenic removal from water: a comparative study.

Five different sorption materials were tested in parallel for the removal of arsenic from water: activated carbon (AC), zirconium-loaded activated carbon (Zr-AC), a sorption medium with the trade name 'Absorptionsmittel 3' (AM3), zero-valent iron (Fe(0)), and iron hydroxide granulates (GIH). Batch and column tests were carried out and the behavior of the two inorganic species (arsenite and arsenate) was investigated separately. The sorption kinetics of arsenate onto the materials followed the sequence Zr-AC >> GIH = AM3 > Fe(0) > AC. A different sequence was obtained for arsenite (AC >> Zr-AC = AM3 = GIH = Fe(0)). AC was found to enhance the oxidation reaction of arsenite in anaerobic batch experiments. The linear constants of the sorption isotherms were determined to be 377, 89 and 87 for Zr-AC, AM3 and GIH, respectively. The uptake capacities yielded from the batch experiment were about 7gl(-1) for Zr-Ac and 5gl(-1) for AM3. Column tests indicated that arsenite was completely removed. The best results were obtained with GIH, with the arsenate not eluting before 13100 pore volumes (inflow concentration 1 mg l(-1) As) which corresponds to a uptake capacity of 2.3 mg g(-1) or 3.7 g l(-1).

Arsenic↗

Column-mode phosphate removal by a novel highly selective adsorbent.

A phosphoric acid resin RGP was immobilized with zirconium(IV) (Zr(IV)) to investigate its applicability in phosphate removal. When loaded with Zr(IV), RGP was changed into an effective ligand exchanger with phosphate sorption capacity of 0.345 mmol/ml. Little metal leakage was observed. Breakthrough of phosphate sorption depended on solution acidity and phosphate concentration. An increase of solution pH greatly suppressed phosphate removal, but even at pH 8.21, about 56% of the added phosphate (2.8mM) in the feed solution could still be sorbed. Electrolytes in the aqueous solution did not interfere with phosphate sorption; on the contrary, an enhancement effect was observed. Due to the high sorption capacity of Zr(IV)-loaded RGP, low concentration of phosphate can be removed at high flow rate (100 h(-1) in space velocity). The sorbed phosphate on the Zr(IV)-loaded RGP could be quantitatively eluted with 0.5M sodium hydroxide solution. The Zr(IV)-loaded RGP is a promising ligand exchanger for treating wastewater containing trace amounts of inorganic phosphate.

Adsorption↗

Automated separation process for radioanalytical purposes at nuclear power plants.

Chemical separation processes have been developed to remove the matrix components and thus to determine fission products, especially radioiodine nuclides, in the primary coolant of WWER-type nuclear reactors. Special procedures have been elaborated to enrich long-lived nuclides in waste waters to be released and to separate and enrich caesium isotopes in the environment. All processes are based mainly on ion-exchange separations using amorphous zirconium phosphate. Automated equipment was constructed to meet the demands of the plant personnel for serial analysis.

Autoanalysis↗

Control of electroosmotic flow in zirconia-coated capillaries.

The inner surface of a silica capillary has been modified using an anhydrous sol-gel method: zirconium propoxide reacted with silanol groups to give, after hydrolysis, a "zirconia-like" surface. The electroosmotic properties of zirconia-modified capillaries have been studied under various conditions: working parameters were nature and concentration of the electrolyte, ionic strength, pH and solvent composition. Using different ions such as sodium, potassium, chloride, nitrate or methanoate, a positive electroosmotic flow (cathodic flow) was observed in the pH range 5-11. But below pH 5, a negative electroosmotic flow (anodic flow) occurred, corresponding to a permanent positive surface charge of the capillary walls. The value of the electroosmotic flow (including the sign) can be easily controlled by adding multivalent ions in the electrolyte. Some of these modifications of surface charge can be made irreversible. The observed electroosmotic flow has been related to surface characteristics using the triple layer model. With the large set of working parameters, the optimisation of separations can be facilitated. An example of flow control is given for the separation of four antihistaminic compounds.

Electrochemistry↗

Characterization of wear debris associated with aseptic loosening of a canine hip prosthesis.

A 12-month-old Golden Retriever bitch underwent unilateral hip arthroplasty following a diagnosis of coxofemoral osteoarthritis secondary to hip dysplasia. The hip prosthesis underwent aseptic loosening and was removed 6 months after implantation. Synovial biopsies taken at that time revealed scattered foci of granulomatous inflammation associated with intra-cytoplasmic and extracellular particulate material. Electron microscopical analyses demonstrated that this material contained cobalt, chromium, titanium and zirconium, which was probably wear debris from the loosened prosthesis. In human patients with hip arthroplasty, widespread dissemination of wear debris from loosened prostheses occasionally occurs, with an increased prevalence of neoplasia. A similar phenomenon may be predicted to occur with the increasing use of hip arthroplasty in the dog.

Animals↗

Improvement in capacitive deionization function of activated carbon cloth by titania modification.

Activated carbon cloth (ACC) was modified by the reaction between polar groups on its surface and metal alkoxides of titanium, silicon, aluminum and zirconium to enhance its capacitive deionization (CDI) performance. Incorporated state of metals and surface property of modified ACC were deduced from surface analysis results obtained using FE-SEM, XRD, XPS and zeta-potential meter. Titania was highly dispersed on the ACC surface with tetrahedral coordination, and the incorporated titania was effective to decrease physical adsorption of NaCl and to increase electric field adsorption, resulting in a significant enhancement of CDI performance. The negligible contribution of silica, alumina and zirconia modifications suggested that the small oxidation-reduction potential of titania was responsible for the enhancement of the electric field adsorption. Reversibility of adsorption and desorption operation on titania-modified ACC were also discussed relating to its CDI function.

Adsorption↗

A new adhesive technology for all-ceramics.

OBJECTIVES: Evaluation of a new surface treatment method to obtain a good bond strength between a luting composite and several ceramics. METHODS: Specimen preparation and test procedure were done according to ISO 10477 Amendment 1. The surfaces of Empress II, InCeram-Alumina, InCeram-Zirconia and Frialit (ZrO2) were ground under water-cooling with 400 grit grinding paper, afterwards polished with 800 grit and air-dried. Each ceramic material investigated was divided into three groups of 10 specimens each. Group 1 was flame-treated with the PyrosilPen for 2.5 s, group 2 for 5 s and group 3 for 10 s/cm(2). After the flame treatment, a methacryl silane was applied followed by a luting composite. Prior to measuring shear bond strength, the specimens were thermocycled 5,000 times in a water-bath between +5 and +55 degrees C. Furthermore, SEM- and Fourier-transform infrared spectrophotometer (FT-IR)-investigations were done. As a control, Empress II etched and silaned was used. RESULTS: Shear bond strength measurements indicated that the optimal treatment time was 5 s/cm(2). Regarding this time the following bond strength values between the luting composite and the various ceramics were obtained: Empress II 23 (5)MPa, InCeram-Alumina 23 (5)MPa, InCeram-Zirconia 13 (8)MPa, and Frialit 16 (6)MPa. The control achieved 27 (6)MPa. On all surfaces of the flamed specimens Si could be detected by FT-IR.Significance. The PyrosilPen-Technology is an easy and effective method for surface-treating silicate, aluminum oxide and zirconium oxide ceramics to obtain good bonding to luting composites.

Aluminum Oxide↗

Radiopaque acrylic resins containing miscible heavy-metal compounds.

Radiopacity is needed in order to facilitate diagnosis of polymeric appliances, which may be dislodged and become impacted in the upper respiratory or digestive tracts. In order for a stable, optically transparent, radiopaque material to be provided, heavy-metal compounds were investigated which we had previously shown to form homogeneous structures with methyl methacrylate-based systems. It was found that, when present in PMMA at 11 to 14%, several compounds of either bismuth or uranium or 35% of an organo-zirconium compound impart radiopacity equivalent to that of aluminum. A low level of cytotoxicity and lack of mutagenicity indicated that a high level of biocompatibility can be expected. Processing characteristics are somewhat altered, but formulations satisfactory for use in various dental devices were found.

Acrylic Resins↗

Platelet release of transforming growth factor-beta and beta-thromboglobulin after in vitro contact with acrylic bone cements.

Three methacrylate-based bone cements used for the fixation of joint prostheses were evaluated: Sulfix-60 (Sulzer Orthopedic Inc., Baar, Switzerland). CMW1 (DePuy International Ltd., England). and CMW2 (DePuy International Ltd., England). The cements after polymerization were put in contact in vitro with platelet-rich plasma. Plasma, in contact only with siliconized glass, was used as a negative control. After contact, platelet number. beta-thromboglobulin (beta-TG), and transforming growth factor-beta1 (TGF-beta1) were determined. The Student's paired t test showed that the ccments induced no significant modifications of platelet number. CMWI and Sulfix-60 determined a significant increase in beta-TG compared with the negative control. All cements determined a significant increase in TGF-beta1. Significant differences were also seen in the levels of beta-TG and TGF-beta1 between cements with a content of benzoyl peroxide < 1 (Sulfix-60) and those with a content > 1 (CMW1 and CMW2). The cement with zirconium dioxide (Sulfix-60) produced higher levels of beta-TG and TGF-beta1, compared to those with barium sulphate (CMW1 and CMW2). In conclusion, all the cements induced the secretion of TGF-beta1 CMW1 and Sulfix-60 determined also a significant release of beta-TG. Platelet activation induced by the cements from one side could contribute to the pathogenesis of deep venous thrombosis, that often occurs after prosthetic implant and is caused also by other factors, including surgical trauma and venous stasis. From the other side, activated platelets can release growth factors favoring bone formation.

Acrylic Resins↗