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Extraction mechanism for palladium(II) from hydrochloric acid solution with 2-dodecylthiomethylpyridine using a stirred transfer cell.

2-Dodecylthiomethylpyridine (DTP) was newly synthesized to study its extraction properties for precious metals. DTP was a selective extractant for palladium(II) and gold(III) over base metals. The loading test for palladium(II) showed that one palladium ion reacted with one molecule of DTP. The extraction rate of palladium with DTP was measured using a Lewis-type transfer cell at 303 K. The extraction reaction of palladium with DTP has been found to be a first order reaction with respect to palladium ion, DTP, and hydrogen ion concentrations. This reaction is inversely proportional to chloride ion concentration. The rate-determining step was the parallel reactions of DTP with PdCl3(-) and PdCl4(2-) in the aqueous phase.

Journal Article↗

Effect of oxytetracycline-hydrochloric acid on reproduction of female turkeys.

Effects of oxytetracycline-HCl on reproductive performance of turkey breeder hens from the 13 to 24-wk production period were evaluated. During the 13th wk of production, females were grouped into low, medium, and high fertility subclasses. Females within each fertility subclass were randomly reassigned to treatments. The antibiotic was administered via the drinking water (T-2) or via the drinking water plus an intravaginal lavage (T-3). Hens receiving T-2 treatment showed significantly higher fertility than untreated controls (T-1) but also showed significantly higher early embryonic mortality than those receiving the T-3 treatment. Hatchability of all egg set was significantly higher in both antibiotic-treated groups than in controls. Females in the fertility subclasses remained significantly different from each other throughout the experiment. To determine the duration of the effect of antibiotic treatment, eggs were collected in a treatment and posttreatment periods. Fertility (P less than .05), and hatchability (P less than .10) were improved during the treatment period compared with results of the posttreatment period. The T-3 treatment had a long-term effect: it maintained early embryonic mortality at 10% and hatchability at the same level during both treatment periods. A short-term effect was observed in the T-2 group; early embryonic mortality increased (P less than .05) and hatchability decreased (P less than .10) during the posttreatment period. No correlations were found between mycoplasmal or bacterial populations and fertility subclass or antibiotic treatment. Egg production, body weight, feed consumption, feed consumed per egg, egg weight, and egg specific gravity were unaffected by antibiotic treatment.

Animals↗

[Histochemical study of carbonic anhydrase and HCO3(-)-stimulated adenosine triphosphatase in the rat stomach during hydrochloric acid secretion].

By means of histochemical methods it was established that carboanhydrase of the parietal cells of fundal glands and HCO-3 stimulated ATP-ase of the rat's gastric mucosa capillaries disposed next to the parietal cells were activated by food and histamine. The obtained data confirm the idea of the multicellular functional essembly sustaining HCL secretion (R. I. Salganik, 1974). Should gastrin induce the formation of histamine in endocrinous cells and the histamine activate carboanhydrase in parietal cells, our data confirm the supposition that HCO-3-ions stimulate ATP-ase sustaining the exchange between HCO-3-cells and C1- of blood to form HCl in the endothelial cells of blood capillaries adjacent to the parietal cells.

Adenosine Triphosphatases↗