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At least 631 records · Page 35Linked to original sources
PubMed1980

Effects of whole-body vibration on spinal reflexes in man.

Recent studies have described sensory-motor function alterations resulting from vibrations applied to various parts of the body. The present work describes the effects produced at the myotatic loop level by long-term vibration. Hoffmann and Tendon reflexes as well as tendon vibration response were substantially depressed by 18 Hz, +/- 0.25 G vibration applied to the whole body or to the legs of seated human subjects. The reflex inhibition lasted throughout the 15-min vibration period and persisted minutes after stimulus cessation. In contrast, vibration limited to the S's head and trunk showed much weaker effects. This suggests that the vibration acts mainly upon extero- and proprioceptive receptors rather than upon the vestibular organs. The results are discussed in relation to findings derived from experiments involving locally applied short-duration vibration.

Adolescent↗
PubMed1994

Vibration exposure and symptoms in postal carriers using motorbikes.

An investigation was made on vibration exposure among postal carriers using motorbikes (mainly letter carriers) and vibration symptom manifestations as a means to obtain information on hand-arm vibration exposure limits. The first report deals with the correlation of vibration and cold exposure with white finger symptoms. The group in which daily vibration exposure was greatest, for which the 4-hour equivalent value of the frequency weighted vibration acceleration was estimated to be above 2 m/s2, showed a greater incidence of white finger than other groups, and the changes synchronized with the timing of motorbike antivibration measures. This group, however, also displayed evidence of varying degrees of cold-exposure white finger. The vibration exposure limit was considered to be over 2 m/s2 as the 4-hour equivalent value of the frequency weighted vibration acceleration.

Humans↗
PubMedDate not supplied

[Hand-arm vibration syndrome: diagnostic aspects, dose-response relationship and exposure limits].

This paper reviews the clinical aspects and laboratory methods to diagnose the vascular, sensorial and neural components of the hand-arm vibration syndrome. The resolutions adopted by the experts of the Stockholm Workshop 94 are reported. The methods of measurement and assessment of both daily and cumulative vibration exposure are discussed with respect to the risk for vibration-induced disorders of the upper extremities. An update of the relationship between vibration exposure and the occurrence of vibration-induced white finger (VWF) is given, as well as the results of epidemiologic studies of the reversibility of VWF after cessation of vibration exposure or introduction of vibration isolation systems in forest work. Regarding occupational exposure to hand-transmitted vibrations, this review considers the guidelines and provisions contained in the European Communities (EC) Directive for machinery (89/393/EC) and the proposal for an EC Directive for physical agents (94/C 230/03).

Arm↗
PubMed1996

A new examination system using photoplethysmography to evaluate skin blood flow during exposure to vibration.

We introduce a new examination method developed at the University Dermatology Hospital in Tübingen in cooperation with the Institute for High Frequency Techniques of Aachen Technical College and the Metabo Factory in Nürtingen, Germany. The Tübingen workplace simulator for studying vibration white finger (VWF) syndrome standardized vibrations reproducing the vibration pattern of actual hand-held tools. This stimulator makes it possible to evaluate on-line the effects of defined vibrations on skin blood flow in the fingers and to investigate the etiopathogenesis of vibration white finger syndrome. The vibration simulator itself is modelled after an altered router with two side-mounted handles. The electronic speed control and exchangeable unbalance pins make it possible to adjust the frequency and amplitude of the vibrations to simulate actual conditions in the job. New developed photoplethysmographic sensors are fastened to the fingertips with double adhesive rings and measure blood flow in the skin. Measurements are recorded simultaneously with a multi-channel plotter. This method is not only useful as a diagnostic tool but has potential future applications in pre-employment screening in the affected industries and in the development of reduced-vibration tools.

Fingers↗
PubMed1982

The effect of vibration on the skeleton, joints and muscles. A review of the literature.

Owing to the elasticity and plasticity of the skeleton, joints and muscles, the musculoskeletal system is capable of absorbing and damping mechanical vibration without damage as long as the vibration level is within tolerable limits. However, technical developments have led to the exposure of many people to intolerable variation levels with destructive changes as a result. These injuries to the musculoskeletal system continue to be the subject of research interest. Initially, the joints and joint complaints attracted the greatest attention. Vibration damping takes place mainly in the joints. The incidence of destructive joint changes has been examined in comprehensive clinical, epidemiological and radiographic studies, mainly concentrating on the joints of the hand and arm. The response of muscles to vibration is often expressed in the form of a tonic vibration reflex (TVR) which arises as a result of stimulation of the muscle spindles and therefore resembles the classic tonic stretch reflex. There is increased muscular activation for stabilisation of the joint positions, especially during whole-body vibration. Studies have also disclosed how vibration affects body equilibrium and equilibrium control and how vibration can elicit muscle pain, cramps and reduced muscular strength.

Journal Article↗
PubMed1987

Vibration in car repair work.

The main objective of the study was to find efficient hand tools which caused only minor vibration loading. Vibration measurements were carried out under standardised working conditions. The time during which car body repairers in seven companies were exposed to vibration was determined. Chisel hammers, impact wrenches, sanders and saws were the types of tools which generated the highest vibration accelerations. The average daily exposure at the different garages ranged from 22 to 70 min. The risk of vibration injury is currently rated as high. The difference between the highest and lowest levels of vibration was considerable in most tool categories. Therefore the choice of tool has a major impact on the magnitude of vibration exposure. The importance of choosing the right tools and working methods is discussed and a counselling service on vibration is proposed.

Journal Article↗
PubMed1990

The relative importance of noise and vibration from railways.

An experiment was conducted to determine the subjective equivalence of railway noise and railway-induced building vibration, and hence the relative importance of the two stimuli. Six magnitudes of whole-body, vertical (z-axis) vibration and six levels of noise were presented simultaneously to each of 30 subjects in all 36 possible paired combinations. The stimuli were reproductions of the noise and vibration recorded inside a house during the passage of a train. The subjects were asked to indicate, after each presentation, which of the two stimuli (noise and vibration) they would prefer to be reduced. A seven-point scale was employed to indicate the total annoyance produced by the two stimuli. A subjective equivalence contour was determined from the levels at which 50% of the subjects preferred the reduction of noise and 50% preferred the reduction of vibration. The contour may be described by the relation L(AE) = 29.3 log10 VDV + 89.2, where L(AE) is the sound exposure level and VDV is the vibration dose value. This relation may be used to determine whether a reduction of noise or a reduction of vibration would be more beneficial to residents near railways. The total annoyance due to simultaneous noise and vibration was shown to depend on the magnitude of both stimuli.

Journal Article↗
PubMed2002

Complex vibration ultrasonic welding systems with large area welding tips.

Vibration and welding characteristics of complex vibration ultrasonic welding systems of 27 and 40 kHz were studied. Complex vibration systems, which have elliptical to circular or rectangular to square locus, are effective for ultrasonic welding of various specimens including the same and different metal specimens, and for direct welding of semiconductor tips and packaging of various electronic devices without solder. The complex vibration systems consist of a one-dimensional longitudinal-torsional vibration converter with slitted part, a stepped horn and a longitudinal vibration transducer as a driving source. The complex vibration welding tips of 27 and 40 kHz have enough area of 6-8 mm square for various welding specimens. Aluminum plate specimens of 0.3-1.0 mm thickness were successfully joined with weld strengths almost equal to aluminum specimen strength, and independent to the specimen direction. Required vibration amplitude of 40 kHz is smaller than that of 27 kHz.

Journal Article↗
PubMed2000

Transverse and torsional complex vibration systems for ultrasonic seam welding of metal plates

Transverse and torsional complex vibration systems for ultrasonic seam welding of metal plate specimens, using a 27 kHz complex vibration disk welding tip vibrating in transverse and torsional vibration modes, were studied. Using a complex vibration welding system with a welding tip vibrating in elliptical or circular locus, thick plate specimens can be welded with a more uniform and larger area compared to a conventional ultrasonic welding system. The disk welding tip vibrates in an elliptical or circular locus. The complex vibration system can continuously weld multiple parts of metal plate specimens such as heat sinks with a large number of fins.

Journal Article↗
PubMed2000

One-dimensional longitudinal-torsional vibration converter with multiple diagonally slitted parts

For increasing the available vibration velocity of the one-dimensional longitudinal-torsional vibration converter, a new type of complex vibration converter with multiple slitted parts installed in the positions avoiding longitudinal nodal positions along the converter for decreasing the maximum vibration stress level at the vibration nodal part was studied. The free end of the converter vibrates in an elliptical or circular locus. Complex vibration systems with elliptical to circular or rectangular to square loci can be applied effectively for various high-power applications, including ultrasonic welding of metal or plastics, ultrasonic wire bonding of IC, LSI and electronic devices, and also ultrasonic motors. The converter with multiple slitted parts was improved in the vibration stress level and the quality factor compared with the converter with single slitted part.

Journal Article↗
PubMed1996

Vibrational Analysis of a Molecular Heme-Copper Assembly with a Nearly Linear Fe(III)-CN-Cu(II) Bridge: Insight into Cyanide Binding to Fully Oxidized Cytochrome c Oxidase.

The complete vibrational analysis of [(1-MeIm)Fe(OEP)-CN-Cu(Me(6)tren)](2+) (1), which has been constructed as a model for the cyanide-ligated binuclear center in the respiratory protein cytochrome c oxidase, has been carried out. The resonance Raman spectra (lambda(exc) = 647 nm) and the mid-infrared spectra display three cyanide isotope-dependent vibrational modes. Two vibrations showed monotonic decreases with increasing mass of the cyanide ligand (2182-2137-2146-2101 cm(-)(1) and 535-526-526-520 cm(-)(1), respectively, for the (12)C(14)N-(13)C(14)N-(12)C(15)N-(13)C(15)N isotopomers), and could thus be assigned to the C&tbd1;N and Fe-CN-Cu stretching vibrations, respectively. The third vibration, detected with resonance Raman, showed a zigzag-type behavior (495-487-493-485 cm(-)(1) with the set of isotopomers above) with the frequency being more sensitive to (13)C labeling of the cyanide ligand than with (15)N labeling. This pattern of isotopic dependence is characteristic of a bending vibration. Additionally, with the same laser excitation frequency, the C&tbd1;N stretching mode was observed, which is the first time that this vibration has been detected in the resonance Raman spectrum of a synthetic heme-cyanide complex. The normal coordinate analysis showed marked differences between bridged and unbridged heme-cyanide complexes. Internal coordinates that are orthogonal in unbridged systems are significantly mixed in the bridged model, despite the overall linearity of the Fe-CN-Cu moiety. These measurements strengthen the proposal that cyanide bridges the two metal atoms in the cyanide-ligated, oxidized binuclear center of cytochrome c oxidase. A quantitative consideration of the vibrational characteristics of cyanide bound to the resting enzyme, in light of our model compound results, strongly suggests that the binuclear center is flexible and can undergo structural rearrangement to accommodate exogenous ligands. This is likely to be of mechanistic importance in both dioxygen reduction and proton translocation.

Journal Article↗
PubMed2004

Direct dynamics trajectory study of vibrational effects: can polanyi rules be generalized to a polyatomic system?

We present an ab initio direct dynamics trajectory study of the hydrogen abstraction reaction: H2CO+ + CD4 --> H2COD+ + CD3, with methane excited in two different distortion modes (nu4 and nu2). The trajectory simulations were able to reproduce experimental results and for the first time show how vibrational enhancement originates in reaction of small polyatomic species. Roughly equal contributions from two vibrational enhancement mechanisms were found. The "distortion" mechanism correlates the vibrational effects with vibration-induced reactant distortions, and the "velocity" mechanism correlates vibrational effects with vibrational velocities of the constituent atoms. This reaction has a reactant-like transition state and, thus, would correspond to an "early" barrier system in the context of the well-known Polanyi rules for predicting effects of vibration and collision energy. Straightforward application of these rules would predict that vibration should be ineffective in driving reaction, in disagreement with both experiment and trajectory results. Using the trajectories for guidance, we were able to construct a two-dimensional cut through the reaction potential energy surface that does suggest a predictive, Polanyi-type rule.

Journal Article↗
PubMed2006

Zero-point corrections and temperature dependence of HD spin-spin coupling constants of heavy metal hydride and dihydrogen complexes calculated by vibrational averaging.

Vibrational corrections (zero-point and temperature dependent) of the H-D spin-spin coupling constant J(HD) for six transition metal hydride and dihydrogen complexes have been computed from a vibrational average of J(HD) as a function of temperature. Effective (vibrationally averaged) H-D distances have also been determined. The very strong temperature dependence of J(HD) for one of the complexes, [Ir(dmpm)Cp*H2]2 + (dmpm = bis(dimethylphosphino)methane) can be modeled simply by the Boltzmann average of the zero-point vibrationally averaged JHD of two isomers. For this complex and four others, the vibrational corrections to JHD are shown to be highly significant and lead to improved agreement between theory and experiment in most cases. The zero-point vibrational correction is important for all complexes. Depending on the shape of the potential energy and J-coupling surfaces, for some of the complexes higher vibrationally excited states can also contribute to the vibrational corrections at temperatures above 0 K and lead to a temperature dependence. We identify different classes of complexes where a significant temperature dependence of J(HD) may or may not occur for different reasons. A method is outlined by which the temperature dependence of the HD spin-spin coupling constant can be determined with standard quantum chemistry software. Comparisons are made with experimental data and previously calculated values where applicable. We also discuss an example where a low-order expansion around the minimum of a complicated potential energy surface appears not to be sufficient for reproducing the experimentally observed temperature dependence.

Journal Article↗
PubMed2005

A quasiclassical trajectory study of the reaction H + O2 <==> OH + O with the O2 reagent vibrationally excited.

Quasiclassical trajectories have been computed on the Melius-Blint (MB) Potential Energy Surface (PES) and on the Double Many-Body Expansion (DMBE) IV PES of Pastrana et al. describing the H + O(2) <==> OH + O reaction with the nonrotating (J = 0) O(2) reagent vibrationally excited to levels v = 6, 7, 8, 9, and 10 at four temperatures: 1000, 2000, 3000, and 4000 K. The vibrational energy levels were selected by using a semiclassical Einstein-Brillouin-Keller (EBK) quantization procedure while the relative translational energy was sampled from a Boltzmann weighted distribution. The rate coefficient for the formation of the OH + O products is seen to increase monotonically with quantum number and nearly monotonically with temperature. On the MB PES, at T = 1000 K, the total rate coefficient increases by a factor of 5.2 as the initial vibrational quantum number of the O(2) diatom increases from v = 6 to v = 10. For T = 2000 K, this factor drops to 3.3, to 2.9 for T = 3000 K, and to 2.5 for T = 4000 K. On the DMBE IV PES, at T = 1000 K the total rate coefficient increases by a factor of 4.1 as the initial vibrational quantum number of the O(2) diatom increases from v = 6 to v = 10. For T = 2000 K, this factor drops to 3.5, to 2.1 for T = 3000 K, and to 2.0 for T = 4000 K. The less-direct group (defined below) of trajectories is sensitive to the initial O(2) vibrational excitation in several different temperature ranges, apparently retaining the effect of reagent vibrational excitation. The more-direct group (defined below) of trajectories does not exhibit this behavior. Reagent vibrational excitation does not increase the total rate coefficients for the title reaction more than the increase due to a simple temperature increase. The less-direct and more-direct groups of trajectories differ in their contribution to the rate coefficient for the title reaction. In particular, at T = 4000 K, the two PESs used in this work differ dramatically in the roles of the less-direct and more-direct trajectories. The behavior of the more-direct and less-direct groups of trajectories can be understood in terms of the efficiency of intramolecular vibrational energy transfer. This work utilizes the recently introduced PES Library, POTLIB 2001, which made the comparisons between the two PESs discussed in this work possible in a very straightforward way.

Journal Article↗
PubMed2004

Use of the ultraviolet absorption spectrum of CF2 to determine the spatially resolved absolute CF2 density, rotational temperature, and vibrational distribution in a plasma etching reactor.

Broadband ultraviolet absorption spectroscopy has been used to determine CF(2) densities in a plasma etch reactor used for industrial wafer processing, using the CF(2) A (1)B(1)<--X (1)A(1) absorption spectrum. Attempts to fit the experimental spectra using previously published Franck-Condon factors gave poor results, and values for the higher vibrational levels of the A state [(0,v(2),0), with v(2) (')>6] from the ground state were missing; hence new values were calculated. These were computed for transitions between low-lying vibrational levels of CF(2) X (1)A(1) to vibrational levels of CF(2) A (1)B(1) (v(1) ('),v(2) ('),0) up to high values of the vibrational quantum numbers using high level ab initio calculations combined with an anharmonic Franck Condon factor method. The Franck Condon factors were used to determine the absorption cross sections of CF(2) at selected wavelengths, which in turn were used to calculate number densities from the experimental spectra. Number densities of CF(2) have been determined in different regions of the plasma, including the center of the plasma and outside the plasma volume, and CF(2) rotational temperatures and vibrational energy distributions were estimated. For absorption spectra obtained outside the confined plasma volume, the CF(2) density was determined as (0.39+/-0.08)x10(13) molecule cm(-3) and the vibrational and rotational temperatures were determined as 303 and 350 K, respectively. In the center of the plasma reactor, the CF(2) density is estimated as (3.0+/-0.6)x10(13) molecules cm(-3) with T(rot) approximately 500 K. The fitted vibrational distribution in the CF(2) ground state corresponds to two Boltzmann distributions with T(vib) approximately 300 and T(vib) approximately 1000 K, indicating that CF(2) molecules are initially produced highly vibrationally excited, but are partially relaxed in the plasma by collision.

Journal Article↗
PubMed2005

Vibrational energy transfer in N2-N2 collisions: a new semiclassical study.

The vibrational energy relaxation in collisions between N2 molecules in the low- and medium-lying vibrationally excited levels was revisited using the semiclassical coupled-state method and the use of two different potential-energy surfaces having the same short-range potential recently determined from ab initio calculations but with different long-range interactions. Compared to the data reported in the classical work by Billing and Fisher [Chem. Phys. 43, 395 (1979)], the newly calculated vibration-to-translation rate constant K(1,0 / 0,0) is in much better agreement with the available experimental data over a large temperature interval, from T = 200 K up to T = 6000 K. Nevertheless, as far as the vibration-to-translation exchanges are concerned, the lower-temperature regime remains quite critical in that the new rate constants do not completely account for the rate constant curvature suggested by the experiments for temperatures lower than T = 500 K. The dependence of the state-selected vibration-to-vibration rate constants, K(v,v-delta v / 0,1), both upon the vibrational quantum number v and the gas temperature are calculated. The substantial deviations from previously found behaviors could have major consequences for the vibrational kinetic modeling of N2-containing gas mixtures.

Journal Article↗
PubMed2006

Vibrationally promoted electron emission from low work-function metal surfaces.

We observe electron emission when vibrationally excited NO molecules with vibrational state v, in the range of 9 < or = v < or =18, are scattered from a Cs-dosed Au surface. The quantum efficiency increases strongly with v, increasing up to 10(-2) electrons per NO (v) collision, a value several orders of magnitude larger than that observed in experiments with similar molecules in the ground vibrational state. The electron emission signal, as a function of v, has a threshold where the vibrational excitation energy slightly exceeds the surface work function. This threshold behavior strongly suggests that we are observing the direct conversion of NO vibrational energy into electron kinetic energy. Several potential mechanisms for the observed electron emission are explored, including (1) vibrational autodetachment, (2) an Auger-type two-electron process, and (3) vibrationally promoted dissociation. The results of this work provide direct evidence for nonadiabatic energy-transfer events associated with large amplitude vibrational motion at metal surfaces.

Journal Article↗
PubMed2006

2-pyridone: The role of out-of-plane vibrations on the S1<-->S0 spectra and S1 state reactivity.

The S(1)<-->S(0) vibronic spectra of supersonic jet-cooled 2-pyridone [pyridin-2-one (2PY)] and its N-H deuterated isotopomer (d-2PY) have been recorded by two-color resonant two-photon ionization, laser-induced fluorescence and emission, and fluorescence depletion spectroscopies. By combining these methods, the B origin of 2PY at 0(0) (0)+98 cm(-1) and the bands at +218 and +252 cm(-1) are identified as overtones of the S(1) state out-of-plane vibrations nu(1) (') and nu(2) ('), as are the analogous bands of d-2PY. Anharmonic double-minimum potentials are derived for the respective out-of-plane coordinates that predict further nu(1) (') and nu(2) (') overtones and combinations, reproducing approximately 80% of the vibronic bands up to 600 cm(-1) above the 0(0) (0) band. The fluorescence spectra excited at the electronic origins and the nu(1) (') and nu(2) (') out-of-plane overtone levels confirm these assignments. The S(1) nonplanar minima and S(1)<--S(0) out-of-plane progressions are in agreement with the determination of nonplanar vibrationally averaged geometries for the 0(0) (0) and 0(0) (0)+98 cm(-1) upper states by Held et al. [J. Chem. Phys. 95, 8732 (1991)]. The fluorescence lifetimes of the S(1) state vibrations show strong mode dependence: Those of the out-of-plane levels decrease rapidly above 200 cm(-1) excess vibrational energy, while the in-plane vibrations nu(5) ('), nu(8) ('), and nu(9) (') have longer lifetimes, although they are above or interspersed with the "dark" out-of-plane states. This is interpreted in terms of an S(1) (') state reaction with a low barrier towards a conical intersection with a prefulvenic geometry. Out-of-plane vibrational states can directly surmount this barrier, whereas in-plane vibrations are much less efficient in this respect. Analysis of the fluorescence spectra allows to identify nine in-plane S(0) (') state fundamentals, overtones of the S(0) state nu(1) (") and nu(2) (") out-of-plane vibrations, and >30 other overtones and combination bands. The B3LYP6-311++G(d,p) calculated anharmonic wave numbers are in very good agreement with the observed fundamentals, overtones, and combinations, with a deviation Delta(rms)=1.3%.

Journal Article↗