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Water vapor as an active scalar in tropical atmospheric dynamics.

Water vapor is a constituent of the tropical atmosphere which, though to a significant extent locally controlled by vertical advection, precipitation, and surface evaporation, is also affected by horizontal advection. Water vapor affects the flow in turn, because a humid atmosphere supports deep, precipitating convection more readily than a dry atmosphere. Precipitation heats the atmosphere, and this heating drives the flow. Water vapor is thus a dynamically active constituent. Simplifications to the primitive equations of dynamical meteorology, based on the so-called weak temperature gradient approximation, are presented which highlight this behavior. The weak temperature gradient approximation is valid on large scales near the equator. It eliminates gravity waves, leaving only balanced dynamics, though the fundamental balance occurs in the temperature rather than the momentum equation (as is customary in most balance models of geophysical fluid dynamics). The dynamical role of water vapor is examined in a couple of idealized contexts, where either the vertical or horizontal structure of the flow is severely simplified. (c) 2002 American Institute of Physics.

Journal Article↗

"Waves" vs. "particles" in the atmosphere's phase space: a pathway to long-range forecasting?

Thirty years ago, E. N. Lorenz provided some approximate limits to atmospheric predictability. The details---in space and time---of atmospheric flow fields are lost after about 10 days. Certain gross flow features recur, however, after times of the order of 10--50 days, giving hope for their prediction. Over the last two decades, numerous attempts have been made to predict these recurrent features. The attempts have involved, on the one hand, systematic improvements in numerical weather prediction by increasing the spatial resolution and physical faithfulness in the detailed models used for this prediction. On the other hand, theoretical attempts motivated by the same goal have involved the study of the large-scale atmospheric motions' phase space and the inhomogeneities therein. These "coarse-graining" studies have addressed observed as well as simulated atmospheric data sets. Two distinct approaches have been used in these studies: the episodic or intermittent and the oscillatory or periodic. The intermittency approach describes multiple-flow (or weather) regimes, their persistence and recurrence, and the Markov chain of transitions among them. The periodicity approach studies intraseasonal oscillations, with periods of 15--70 days, and their predictability. We review these two approaches, "particles" vs. "waves," in the quantum physics analogy alluded to in the title of this article, discuss their complementarity, and outline unsolved problems.

Journal Article↗

Evidence for large methane releases to the atmosphere from deep-sea gas-hydrate dissociation during the last glacial episode.

Past atmospheric methane-concentration oscillations recorded in polar ice cores vary together with rapid global climatic changes during the last glacial episode. In the "clathrate gun hypothesis," massive releases of deep-sea methane from marine gas-hydrate dissociation led to these well known, global, abrupt warmings in the past. If evidence for such releases in the water column exists, however, the mechanism and eventual transfer to the atmosphere has not yet been documented clearly. Here we describe a high-resolution marine-sediment record of stable carbon isotopic changes from the Papua Gulf, off Papua New Guinea, which exhibits two extremely depleted excursions (down to -9 per thousand ) at approximately 39,000 and approximately 55,000 years. Morphological, isotopic, and trace metal evidence dismisses authigenic calcite as the main source of depleted carbon. Massive methane release associated with deep-sea gas-hydrate dissociation is the most likely cause for such large depletions of delta(13)C. The absence of a delta(13)C gradient in the water column during these events implies that the methane rose through the entire water column, reaching the sea-air interface and thus the atmosphere. Foraminiferal delta(18)O composition suggests that the rise of the methane in the water column created an upwelling flow. These inferred emission events suggest that during the last glacial episode, this process was likely widespread, including tropical regions. Thus, the release of methane from the ocean floor into the atmosphere cannot be dismissed as a strong positive feedback in climate dynamics processes.

Air↗

An atmospheric pCO2 reconstruction across the Cretaceous-Tertiary boundary from leaf megafossils.

The end-Cretaceous mass extinctions, 65 million years ago, profoundly influenced the course of biotic evolution. These extinctions coincided with a major extraterrestrial impact event and massive volcanism in India. Determining the relative importance of each event as a driver of environmental and biotic change across the Cretaceous-Tertiary boundary (KTB) crucially depends on constraining the mass of CO(2) injected into the atmospheric carbon reservoir. Using the inverse relationship between atmospheric CO(2) and the stomatal index of land plant leaves, we reconstruct Late Cretaceous-Early Tertiary atmospheric CO(2) concentration (pCO(2)) levels with special emphasis on providing a pCO(2) estimate directly above the KTB. Our record shows stable Late Cretaceous/Early Tertiary background pCO(2) levels of 350-500 ppm by volume, but with a marked increase to at least 2,300 ppm by volume within 10,000 years of the KTB. Numerical simulations with a global biogeochemical carbon cycle model indicate that CO(2) outgassing during the eruption of the Deccan Trap basalts fails to fully account for the inferred pCO(2) increase. Instead, we calculate that the postboundary pCO(2) rise is most consistent with the instantaneous transfer of approximately 4,600 Gt C from the lithic to the atmospheric reservoir by a large extraterrestrial bolide impact. A resultant climatic forcing of +12 W.m(-2) would have been sufficient to warm the Earth's surface by approximately 7.5 degrees C, in the absence of counter forcing by sulfate aerosols. This finding reinforces previous evidence for major climatic warming after the KTB impact and implies that severe and abrupt global warming during the earliest Paleocene was an important factor in biotic extinction at the KTB.

Carbon Dioxide↗

Induction of soybean vegetative storage proteins and anthocyanins by low-level atmospheric methyl jasmonate.

Soybean seedlings were exposed to atmospheric methyl jasmonate (MJ) to determine if low levels of this compound could regulate the expression and accumulation of the vegetative storage proteins (VSPs) in soybeans. Low levels of atmospheric MJ induced the accumulation of three VSPs with molecular masses of 27 kDa, 29 kDa, and 94 kDa (vsp27, vsp29, and vsp94, respectively). Atmospheric MJ caused vsp94 to be accumulated in all above-ground organs of the seedling uniformly after just 3 days of exposure. vsp27 preferentially accumulated in shoot tips and primary leaves, whereas vsp29 preferentially accumulated in the cotyledons. In addition to these effects, MJ also induced the biosynthesis of anthocyanins in light-grown seedlings but inhibited anthocyanin biosynthesis in etiolated seedlings. It is concluded that low levels of atmospheric MJ regulate anthocyanin biosynthesis and the organspecific accumulation of VSPs in developing soybean seedlings. The organ-specific differential accumulation may reflect changes in the pattern of nitrogen partitioning between various compounds and/or organs. These results lend substance to the hypothesis that volatile MJ may act as a gaseous messenger or growth regulator in plants.

Journal Article↗

An isotopic approach for understanding the CH(3)Br budget of the atmosphere.

The atmospheric budget of methyl bromide (CH(3)Br), an ozone-depleting gas, is highly uncertain, because it has complex sources and sinks. Although oceans, biomass burning, and industrial production are identified as the major sources, the fraction of CH(3)Br that is contributed by each source is not well known. A mass-balance approach that exploits differences in the carbon isotopic signature (delta(13)C) of CH(3)Br sources and sinks may provide a means of reducing uncertainties in the atmospheric budget. This approach depends on the distinctiveness of industrially produced methyl bromide. Our delta(13)C measurements of industrial CH(3)Br from the three largest manufacturers worldwide yield a weighted average of -54.4 per thousand relative to the Peedee Belemnite standard. This result suggests that industrial CH(3)Br is isotopically distinct and that the carbon isotopic composition of atmospheric CH(3)Br may indicate what fraction of atmospheric CH(3)Br is anthropogenic.

Air↗

Minimizing the residual oxygen in modified atmosphere packaging of bakery products.

The total elimination of air represents a serious hurdle in modified atmosphere packaging of bakery products, due both to the high spin-rates of the packaging lines and, particularly, to the typical texture of bakery products which retain large quantities of air inside their porous structure. Simulating the gas-flushing modified atmosphere packaging with laboratory equipment and measuring the oxygen concentration directly inside bread rolls, by means of a gas analyser connected with the internal portion, it was possible to follow the rate of atmosphere substitution, evaluating the effects of different baking treatments (7, 12 and 23 min at 230 degrees C) and the role played by different gases (nitrogen, argon, helium, nitrous oxide and carbon dioxide). The oxygen content inside the products, plotted versus time, led to typical logistic 'dose-response' curves which made it possible to forecast the time needed to reach established values of residual oxygen concentration and to emphasize the effects of the different conditions used. The gas properties particularly affected the rate of oxygen substitution and the less water-soluble was the gas, the faster was the oxygen reduction; the larger was the gas molecule, the slower was the process. Also baking time was shown to have, to a different extent, some measurable effects on the rate of oxygen substitution and hence, its optimization as well as the choice of gas mixture can contribute to improve modified atmosphere packaging of bakery products.

Argon↗

In vitro study of TMAO reduction by Shewanella putrefaciens isolated from cod fillets packed in modified atmosphere.

A strain of Shewanella putrefaciens was isolated from cod fillets in a modified atmosphere (60% CO2, 30% O2, 10% N2). The effect of pH on the growth of Shewanella putrefaciens and TMAO reduction was studied in fish extract with citrate buffer systems at pH values from 5.8 to 6.8. The effect of the modified atmosphere (CO2, O2) on the growth of S. putrefaciens and on the reduction of TMAO to TMA was studied using solid media from fish extract packed under variable mixtures of CO2, O2 and N2. All the samples were incubated at 7 degrees C for 7 days. Slow development of S. putrefaciens and no production of TMA was observed in fish extract buffered at pH 5.8. Inclusion of O2 in packaging atmosphere of solid fish extract, even at small proportions (10%), was inhibitory for the reduction of TMAO, while there was no effect of O2 on the growth of S. putrefaciens. Increased levels of CO2 (> or = 50%) in the atmosphere were inhibiting the growth of S. putrefaciens and consequently the production of TMA.

Animals↗

Isotope composition of Zelkova serrata leaves as an indicator of atmospheric pollution in Japan.

In spite of increasing concern regarding the effects of greenhouse gases, atmospheric CO2 concentration continues to increase, with current levels now as high as 370 ppm. This elevated CO2 concentration influences not only atmospheric characteristics, but also ground vegetation: leaf structure, chemical composition and carbon-isotope composition are all affected. It was with this in mind that we investigated the viability of coupling an isotopic and a botanical approach to determine leaf interaction in relation to atmospheric pollution levels. Results show that, among the botanical indexes considered, the most reliable proxy of atmospheric CO2 levels would appear to be leaf mass per area (LMA), which increases with pollution. Our study also shows that LMA determination coupled with carbon-isotope compositions is a sensitive tracer of the local pollution-level variations.

Air Pollutants↗

Concentration of atmospheric pollutants in the gaseous emissions of medical waste incinerators.

The purpose of this paper is to quantify the production of medical waste from a general hospital and to evaluate the atmospheric pollutant concentrations in gaseous emissions associated with its incineration. A 3.8 kg (bed.day)-1 production of medical waste was estimated for 1998; its incineration is related with an ash production of 0.3-0.4 kg (bed.day)-1. The concentrations of atmospheric pollutants were estimated using emission factors, comparing the effluents with and without control of atmospheric pollutants. The calculated concentrations were compared with the emission limits established by Portuguese legislation. The results indicate that, if there is no control of atmospheric pollutants, their concentrations exceed the established limits. This is observed even if correct operation and maintenance procedures are used. The emission concentrations of dioxins are higher than the Portuguese emission limit, which is particularly worrying due to the high toxicity of some of these compounds. Generally, it is possible to reduce pollutant concentrations if appropriate control equipment is used. The conclusions obtained clearly justify the great concern regarding air pollution associated with medical waste incinerators currently operating in Portugal.

Air Pollutants, Occupational↗

Atmospheric lead and the related blood-levels of workers in high-speed can-making.

Any lead in the atmosphere around high-speed can-making lines consists wholly of solid particulate lead metal or lead oxidation products. The working temperature is below the boiling-point of lead, and so none of it is the result of condensation of lead vapor. Level of lead in blood does not appear to be related to the level of total lead in atmosphere or with the worker's proximity to the can-line. There may however perhaps be some relation between blood-lead level and the atmospheric concentration of the respirable part of the lead in the air breathed; investigation is therefore now directed into comparing blood-lead level with atmospheric lead-level measured by analytical procedures which select the particle-size of the sample taken. The paper presents an interim report, with data, on results so far obtained. The whole research program will study the individual operations of can-making.

Air Pollutants↗

Equilibrium Chemistry in a Brown Dwarf's Atmosphere: Cesium in Gliese 229B.

The distribution of Cs in Gliese 229B's atmosphere reveals how equilibrium chemistry establishes the atmospheric composition. The rapid kinetics of cesium chemistry keeps the Cs abundance in thermochemical equilibrium and renders Cs a sensitive measure of chemical processes in brown dwarf atmospheres. Observations of Gliese 229B indicate a subsolar bulk abundance of Cs, the depletion of alkali metals in the upper atmosphere from condensation, and a partitioning of heavy elements different from that of the Sun.

Journal Article↗

The Porous Atmosphere of eta Carinae.

We analyze the wind generated by the great 20 yr-long super-Eddington outburst of eta Carinae. We show that by using the classical stellar atmosphere and wind theory, it is impossible to construct a consistent wind model in which a sufficiently small amount of mass, like the one observed, is shed. One expects the super-Eddington luminosity to drive a thick wind with a mass-loss rate substantially higher than the observed one. The easiest way to resolve the inconsistency is if we alleviate the implicit notion that atmospheres are homogeneous. An inhomogeneous, or "porous," atmosphere allows more radiation to escape while exerting a smaller average force. Consequently, such an atmosphere yields a considerably lower mass-loss rate for the same total luminosity. Moreover, all the applications of the Eddington luminosity as a strict luminosity limit should be revised or at least reanalyzed carefully.

Journal Article↗

Bacillus subtilis spores on artificial meteorites survive hypervelocity atmospheric entry: implications for Lithopanspermia.

An important but untested aspect of the lithopanspermia hypothesis is that microbes situated on or within meteorites could survive hypervelocity entry from space through Earth's atmosphere. The use of high-altitude sounding rockets to test this notion was explored. Granite samples permeated with spores of Bacillus subtilis strain WN511 were attached to the exterior telemetry module of a sounding rocket and launched from White Sands Missile Range, New Mexico into space, reaching maximum atmospheric entry velocity of 1.2 km/s. Maximum recorded temperature during the flight was measured at 145 degrees C. The surfaces of the post-flight granite samples were swabbed and tested for recovery and survival of WN511 spores, using genetic markers and the unique DNA fingerprint of WN511 as recovery criteria. Spore survivors were isolated at high frequency, ranging from 1.2% to 4.4% compared with ground controls, from all surfaces except the forward-facing surface. Sporulation-defective mutants were noted among the spaceflight survivors at high frequency (4%). These experiments constitute the first report of spore survival to hypervelocity atmospheric transit, and indicate that sounding rocket flights can be used to model the high-speed atmospheric entry of bacteria-laden artificial meteorites.

Acceleration↗

Determination of aromatic acids and nitrophenols in atmospheric aerosols by capillary electrophoresis.

A capillary zone electrophoresis method is developed for the determination of aromatic organic acids and nitrophenols in atmospheric aerosols. The procedure is based on sampling atmospheric particulate matter on quartz fiber filters and the extraction and analysis of the extracts by capillary electrophoresis. Separation conditions are optimized by varying the pH and acetonitrile content of the electrolyte buffer. Separations in a 20% acetonitrile-20 mM borate mixture (pH 9.9) are able to resolve all of the geometric isomers of hydroxybenzoic acid, phthalic acid, benzenetricarboxylic acid, and nitrophenol as well as 1,2,4,5-benzenetricarboxylic acid, m-toluic acid, and sulfosalicylic acid. A buffer consisting of 11% acetonitrile-20 mM borate (pH 9.9) is found to be most suitable for the analysis of atmospheric aerosol samples. Detection limits are in the order of 40 to 130 ng/mL. Intersample migration time reproducibility is generally better than 1.5%, with day-to-day variations under 3%. A general extraction scheme using diethyl ether-HCl in combination with a preconcentration step is developed. Recoveries of spiked standards range from 59% to 102%, with relative standard deviations ranging from 2% to 17% for five determinations. The method is applied towards the analysis of ambient aerosol samples as well as vehicle emission studies with promising results, thus showing it to be a potential complement to already existing methodology for the analysis of organic acids and nitrophenols in atmospheric aerosols.

Journal Article↗

Simultaneous gas chromatographic determination of four toxic gases generally present in combustion atmospheres.

The measurement of combustion gases produced by burning aircraft cabin materials poses a continuing limitation for smoke toxicity research. Because toxic effects of gases depend on both their concentrations and the duration of exposure, frequent atmosphere sampling is necessary to define the gas concentration-exposure time curve. A gas chromatographic (GC) method was developed for the simultaneous analyses of carbon monoxide (CO), hydrogen sulfide (H2S), sulfur dioxide (SO2), and hydrogen cyanide (HCN). The method used an MTI M200 dual-column gas chromatograph equipped with 4-m molecular sieve-5A and 8-m PoraPlot-U wall-coated capillary columns and two low-volume, high-sensitivity thermal conductivity detectors. Detectability (in parts per million [ppm]) and retention times (in seconds) for the gases were as follows: CO, 100 ppm, 28 s; H2S, 50 ppm, 26 s; SO2, 125 ppm, 76 s; and HCN, 60 ppm, 108 s. The method was effective for determining these gases in mixtures and in the combustion atmospheres generated by burning wool (CO, HCN, and H2S) and modacrylic fabrics (CO and HCN). Common atmospheric gaseous or combustion products (oxygen, carbon dioxide, nitrogen, water vapor, and other volatiles) did not interfere with the analyses. However, filtration of the combustion atmospheres was necessary to prevent restriction of the GC sampling inlet by smoke particulates. The speed, sensitivity, and selectivity of this method make it suitable for smoke toxicity research and for evaluating performance of passenger protective breathing equipment. Also, this method can potentially be modified to analyze these gases when they are liberated from biosamples.

Air Pollutants↗

Graded atmospheric oxygen level effects on performance and ascites incidence in broilers.

The effects of graded atmospheric O2 concentration (12, 14, 16, 18, and 20.6%) on chick performance and propensity to develop ascites were investigated using commercial male broilers. Chicks were housed in calorimetry chambers for 2 wk with incoming air diluted with N to provide the desired O2 concentration at thermoneutral (TN) ambient temperature. Day 14 body weight, weight gain, feed consumption, and gain-to-feed ratio increased (P < 0.01) as O2 concentration incrementally rose from 12 to 20.6%. Body weight was 138 g for the lowest atmospheric O2 level compared to 371 g for 20.6% O2. The greatest treatment difference occurred between the 12 and 14% O2 concentrations. Growth depression appeared related to feed consumption. Ascites heart ratio (AHR), ascites score (AS), right ventricular mass (RVM), and hematocrit (HCT) all increased (P < 0.01) as O2 concentration decreased. Blood HCT appeared to be a more sensitive indicator of physiological change attributable to atmospheric O2 than AHR, AS, or RVM. The data reported herein suggests that 19.6% atmospheric O2 is the minimal allowable level for housing birds within a relatively stress-free, TN environment to avoid cardiac and HCT changes related to ascites.

Altitude↗

Atmospheric CO(2) and the ratio of intercellular to ambient CO(2) concentrations in plants.

Much attention is focused today on predicting how plants will respond to anticipated changes in atmospheric composition and climate, and in particular to increases in CO(2) concentration. Here we review the long-term global fluctuations in atmospheric CO(2) concentration as a framework for understanding how current trends in atmospheric CO(2) concentration fit into a selective, evolutionary context. We then focus on an integrated approach for understanding how gas exchange metabolism responds to current environmental conditions, how it previously responded to glacial-interglacial conditions, and how it may respond to future changes in atmospheric CO(2) concentration.

Journal Article↗