Vanadium-catalyzed anti-selective additions of allenols to imines.
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Alcohols↗
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Copper(II)-catalyzed highly enantioselective addition of enamides to imines: the use of enamides as nucleophiles in asymmetric catalysis.
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Amides↗
Catalytic three-component coupling of alkynes, imines, and organoboron reagents.
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Alkynes↗
Asymmetric catalytic coupling of organoboranes, alkynes, and imines with a removable (trialkylsilyloxy)ethyl group--direct access to enantiomerically pure primary allylic amines.
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Alkynes↗
Highly diastereo- and enantioselective reactions of enecarbamates with ethyl glyoxylate to give optically active syn and anti alpha-alkyl-beta-hydroxy imines and ketones.
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Carbamates↗
Imine-stabilized zinc trimethylsilylchalcogenolates: powerful reagents for the synthesis of II-II'-VI nanocluster materials.
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Chalcogens↗
Carboamination: additions of imine C=N bonds across alkynes catalyzed by imidozirconium complexes.
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Alkynes↗
Asymmetric synthesis of diarylmethyl amines by rhodium-catalyzed asymmetric addition of aryl titanium reagents to imines.
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Catalysis↗
Nucleophile-catalyzed asymmetric acylations of silyl ketene imines: application to the enantioselective synthesis of verapamil.
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Acylation↗
One-pot tandem 1,4-1,2-addition of phosphites to alpha,beta-unsaturated imines for the synthesis of glutamic acid analogues.
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Glutamic Acid↗
Diphenylphosphanylsulfoximines as ligands in iridium-catalyzed asymmetric imine hydrogenations.
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Catalysis↗
Chiral Brønsted acid catalyzed enantioselective aza-Diels-Alder reaction of Brassard's diene with imines.
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Acids↗
Proline-catalyzed mannich reaction of aldehydes with N-boc-imines.
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Aldehydes↗
Catalytic asymmetric acylcyanation of imines.
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Acetylation↗
[Chemistry of substituted thiosemicarbazides and thioureas. V. Contribution on the synthesis and conversion of 1-substituted thiocarbamylethylene-imines in N-substituted derivatives of 2-amino-2-thiazoline].
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Ethylamines↗
[Addition of butadiencarbonic acid ester to cyclic imine].
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Alkaloids↗
Asymmetric hydrogenation of imines and olefins using phosphine-oxazoline iridium complexes as catalysts.
Herein we describe the synthesis of a new class of chiral phosphine-oxazolines and their application as ligands in iridium-catalyzed hydrogenations. Mechanistic aspects of olefin hydrogenation with this class of iridium catalysts are discussed and a selectivity model to help rationalize the results obtained is also presented.
Alkenes↗
Computational exploration of the photocycloaddition of imines to alkenes.
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Alkenes↗