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Adsorption of bentazon and propanil from aqueous solutions at the high area activated carbon-cloth.

Removal of the pesticides bentazon and propanil from single and bisolute solutions by adsorption at the high area activated carbon-cloth was investigated. Kinetics of adsorption was followed and adsorption isotherms of the two pesticides were determined. A special V-shaped cell with an UV cuvette attached to it was used for adsorption studies. With this cell it was possible to follow the concentration of pesticide molecule by in situ UV spectroscopy as it is adsorbed at the carbon-cloth. It was found that concentration of pesticides decreased from the same initial concentration of 4.5 x 10(-5) to 1.1 x 10(-5) for bentazon and to 9.5 x 10(-6) for propanil in about 2 h. The fits of experimental adsorption isotherm data to Langmuir and Freundlich isotherm equations were almost equally successful. Monolayer capacities determined from Langmuir isotherms of pesticides showed that bentazon has greater monolayer capacity than propanil. This conclusion was also confirmed through the 1/n parameter of Freundlich equation.

Adsorption↗

Flexural properties of denture base polymers reinforced with a glass cloth-urethane polymer composite.

OBJECTIVES: A newly designed light-cured reinforcement made from urethanemethacrylate oligomer and woven glass cloth has orthotropic anisotropy. This is produced for incorporation into the outermost position under the greatest tension in denture base resins. In this study, the flexural properties of self-, heat-, and light-curing reinforced resins were determined. METHODS: The silanized glass cloth was soaked in urethanemethacrylate oligomer containing camphorquinone and 2-(dimethylamino)ethylmethacrylate. It was sandwiched between two pieces of polyethylene film and pressed to form a reinforcement sheet 0.3 mm in thickness, which was light-cured and prepared using four different surface conditions: with or without the polyethylene film and with or without a bonding agent. The reinforcement sheet was fixed in a fluorocarbon resin mold 3 mm in thickness, which was filled with self-, heat-, or light-curing resin and cured. The cured laminated plate was cut for flexural testing (40 x 7 x 3 mm3). A three-point flexural test was carried out at a crosshead speed of 2 mm/min and a span length of 30 mm. In this study, the glass fiber content was measured at percentages by weight because it was not possible to determine accurately the volume of the various polymers. RESULTS: The baseline flexural strengths of the self-, heat-, and light-curing resins were 76.2, 68.6, and 55.6 MPa, respectively, and these values were increased to 271.7, 216.4, and 266.5 MPa by the reinforcement sheet. The baseline flexural moduli of self-, heat-, and light-curing resins were 2.0, 2.4, and 2.1 GPa, respectively. These values were increased to 7.2, 5.1, and 6.6 GPa by the reinforcement sheet. SEM photographs revealed good impregnation of the glass fiber within the polymer matrix. SIGNIFICANCE: The differences in the flexural strengths and flexural moduli of the control and reinforced specimens were significant (p < 0.01).

Composite Resins↗

Gene expression in the gut of keratin-feeding clothes moths (Tineola) and keratin beetles (Trox) revealed by subtracted cDNA libraries.

Few lineages of insects are able to feed on keratin (hair, feathers) and it remains unknown which genes enable this metabolism and what is their evolutionary origin. We conducted a transcriptomic study of two keratin-feeding insects, the clothes moth Tineola bisselliella (Lepidoptera) and the keratin beetle Trox sp. (Coleoptera). Using subtracted cDNA libraries enriched for gut-expressed transcripts, a total of 672 clones sequenced per library resulted in > 150 tentative unique sequences for each species. Sequence similarity predictions identified 22.4% (Tineola) and 6.8% (Trox) of the ESTs as proteases, and mainly as serine proteases of the trypsin and chymotrypsin type, while lacking cysteine proteases. None of the sequences showed similarity to subtilisin type proteases that confers keratinolytic activities in prokaryotes and fungi. Neighbor-Joining trees grouped Tineola and Trox serine proteases near other lepidopteran and coleopteran sequences, respectively, but distant from each other. A few abundant ESTs had no database matches but their presence suggests a role specific to these keratin-feeding insects. While high expression of specific serine proteases appears linked to keratin digestion in both species, it remains to be established if their action requires additional enzymatic or physiological functions to initiate the degradation of the abundant cysteine bonds of keratins. These catabolic pathways are of great interest in the leather industry for the removal of hair, while proteinase inhibitors could prevent damage from clothes moths.

Animals↗

Adsorption of benzoic acid onto high specific area activated carbon cloth.

The adsorption of benzoic acid from aqueous solution onto high area carbon cloth at different pH values has been studied. Over a period of 125 min the adsorption process was found to follow a first-order kinetics and the rate constants were determined for the adsorption of benzoic acid at pH 2.0, 3.7, 5.3, 9.1, and 11.0. The extents of adsorption and the percentage coverage of carbon cloth surfaces were calculated at 125 min of adsorption. Adsorption isotherms at pH values of 2.0, 3.7, and 11.0 were derived at 25 degrees C. Isotherm data were treated according to Langmuir and Freundlich equations and the parameters of these equations were evaluated by regression analysis. The fit of experimental isotherm data to both equations was good. It was found that both the adsorption rate and the extent of adsorption at 125 min were the highest at pH 3.7 and decreased at higher or lower pH values. The types of interactions governing in the adsorption processes are discussed considering the surface charge and the dissociation of benzoic acid at different pH values.

Adsorption↗

Trivalent chromium removal from wastewater using low cost activated carbon derived from agricultural waste material and activated carbon fabric cloth.

An efficient adsorption process is developed for the decontamination of trivalent chromium from tannery effluents. A low cost activated carbon (ATFAC) was prepared from coconut shell fibers (an agricultural waste), characterized and utilized for Cr(III) removal from water/wastewater. A commercially available activated carbon fabric cloth (ACF) was also studied for comparative evaluation. All the equilibrium and kinetic studies were conducted at different temperatures, particle size, pHs, and adsorbent doses in batch mode. The Langmuir and Freundlich isotherm models were applied. The Langmuir model best fit the equilibrium isotherm data. The maximum adsorption capacities of ATFAC and ACF at 25 degrees C are 12.2 and 39.56 mg/g, respectively. Cr(III) adsorption increased with an increase in temperature (10 degrees C: ATFAC--10.97 mg/g, ACF--36.05 mg/g; 40 degrees C: ATFAC--16.10 mg/g, ACF--40.29 mg/g). The kinetic studies were conducted to delineate the effect of temperature, initial adsorbate concentration, particle size of the adsorbent, and solid to liquid ratio. The adsorption of Cr(III) follows the pseudo-second-order rate kinetics. From kinetic studies various rate and thermodynamic parameters such as effective diffusion coefficient, activation energy and entropy of activation were evaluated. The sorption capacity of activated carbon (ATFAC) and activated carbon fabric cloth is comparable to many other adsorbents/carbons/biosorbents utilized for the removal of trivalent chromium from water/wastewater.

Adsorption↗

The effect of acid treatment of carbon cloth on the adsorption of nitrite and nitrate ions.

The effects of functional groups on the adsorption efficiency of nitrate and nitrite from water by carbon cloth were investigated. The carbon cloth was treated by sulfuric acid and used for the adsorption of nitrate and nitrite from water samples at nearly neutral solutions. The concentrations of ions in the solution were monitored using in situ UV spectroscopy. Acid treatment caused a significant increase in the adsorption rate of ions and the adsorption capacity of the adsorbent.

Adsorption↗

Thromboembolic complications with the cloth-covered Starr-Edwards aortic prosthesis in patients not receiving anticoagulants.

A comparison of the incidence of thromboembolic (TE) episodes was made in three groups of patient who underwent aortic valve replacement with the cloth-covered Starr-Edwards prostheses. Group 1 consisted of patients who received anticoagulants for either the entire period of follow-up or for a period of variable duration, after which these agents were no longer administered. When anticoagulants were stopped, 22 patients were categorized as Group 3 for study. Group 2 comprised patients who never received anticoagulants. Of the 147 patients followed in Group 1, 14 suffered one episode of TE. Six patients experienced major emboli; 3 of them died. Twenty of the 82 patients followed in Group 2 (no anticoagulants) suffered TE complications. There were 10 episodes of major emboli. Five of the 22 patients in Group 3 suffered an episode (all major) of TE. It is concluded from this study that anticoagulants should be given permanently to all patients with cloth-covered Starr-Edwards prostheses. Indeed, there is no period after operation when the incidence of TE is so low that anticoagulation may be safely discontinued.

Acenocoumarol↗

Role of titania incorporated on activated carbon cloth for capacitive deionization of NaCl solution.

Adsorption isotherms of NaCl on activated carbon cloth (ACC) and titania-incorporated activated carbon cloth (Ti-ACC) under an electric field were investigated to deduce the role of titania in capacitive deionization (CDI) of NaCl. Electrosorption of NaCl on the ACC was significantly increased by titania incorporation, whereas its physical adsorption was considerably decreased, resulting in an improved performance of the Ti-ACC as a CDI electrode. Langmuir isotherms based on a localized and fixed amount of adsorption were suitable for the simulation of electrosorption and physical adsorption of ions on the ACC electrodes. The variances of q(m) and b of Langmuir isotherms with electric potential indicate increases in the number of ions per adsorption site and in electrosorption strength of ions by titania incorporation. A cyclic voltammetric study for ion adsorption on ACC electrodes confirms the reversibility between electrosorption and desorption of ions, regardless of titania incorporation.

Journal Article↗

Assay of Salmonella in enrichment cultures of foods, feeds and environmental samples by the polymyxin-cloth enzyme immunoassay.

A variety of foods, animal feeds and environmental samples were analyzed for the presence of Salmonella using the polymyxin-cloth enzyme immunoassay (p-CEIA) system. Salmonella lipopolysaccharide (LPS) antigens were captured from test samples on polymyxin-coated polyester cloth, followed by immunoenzymatic detection of bound antigens using a monoclonal antibody recognizing an LPS common core oligosaccharide. Dairy and egg products, animal feeds and environmental samples from food processing plants were pre-enriched for 24 h, followed by selective enrichment for a further 24 h in either tetrathionate brilliant green (TBG), selenite cystine (SC) or brain-heart infusion broth containing 0.5% yeast extract, 0.5% cholate and 0.3% selenite (BYCS). The samples were assayed by the p-CEIA after each stage of enrichment. After selective enrichment, the p-CEIA gave results which were in complete agreement with the standard culture technique in the analysis of all foods examined. On the other hand, a combination of selective enrichment and the p-CEIA out-performed the Modified Semi-Solid Rappaport Vassiliadis (MSRV) method in screening pre-enrichment cultures of feeds and environmental samples. Use of the new selective medium BYCS prior to performing the p-CEIA gave the highest recovery of Salmonella from feeds and environmental samples.

Animal Feed↗

Comparison of cloth, paper, and warm air drying in eliminating viruses and bacteria from washed hands.

We compared the efficiency of paper, cloth, and electric warm air drying in eliminating rotaviruses and Escherichia coli remaining on finger pads washed with 70% isopropanol, a medicated liquid soap, an unmedicated liquid soap, or tap water alone. The contaminated area on the finger pads of a volunteer was exposed to the hand-washing agent for 10 seconds and then rinsed in 40 degrees C tap water. The washed areas were dried for 10 seconds by one of the three methods. Irrespective of the hand-washing agent used, electric air drying produced the highest and cloth drying the lowest reduction in the numbers of both test organisms. These findings indicate the importance of selecting the right means for drying washed hands, particularly when less effective hand-washing agents are used.

Disinfectants↗

Temperature dependence of herbicide adsorption from aqueous solutions on activated carbon fiber and cloth.

Diuron and amitrole adsorption from aqueous solution on an activated carbon fiber and an activated carbon cloth were studied as a function of temperature. Diuron adsorption was greater than that of amitrole and increased with rising temperature, whereas amitrole adsorption decreased when the temperature increased. Endothermicity of diuron adsorption was due to an increase in the planarity and diffusion of diuron molecules with higher temperatures. However, the exothermicity found for amitrole was due to the increase in amitrole solubility and in vibrational energy of adsorbed molecules with higher temperature. External mass transfer resistance was also found to play an important role in diuron adsorption on activated carbon cloth.

Journal Article↗

Phosphate poisoning by ingestion of clothes washing liquid and fabric conditioner.

A case of deliberate ingestion of clothes washing liquid and fabric conditioner is described. Tracheal intubation and controlled ventilation became necessary because of respiratory muscle dysfunction associated with hypocalcaemia. We suggest that the phosphate component of the clothes washing liquid was responsible for the dramatic metabolic upset and subsequent need for admission to the Intensive Care Unit.

Adult↗

Right coronary artery occlusion by cloth from a Starr-Edwards aortic valve prosthesis.

We report a case of sudden onset of angina 11 years after implantation of a No. 8 Model 2300 Starr-Edwards cloth-covered aortic valve prosthesis for aortic stenosis and insufficiency. At operation the cloth covering one strut of the metal cage was tenuously attached to the ring of the prosthesis, with its free end completely occluding the right coronary artery ostium. The valve was replaced and the obstructing foreign body removed, re-establishing the patency of the right coronary artery.

Angina Pectoris↗

Enzyme activities of rumen particles and feed samples incubated in situ with differing types of cloth.

Three ruminally cannulated non-lactating dairy cows were used to investigate the effects of six different bag cloth types with pore size (microns): free surface area (%) ratios of 200:45, 41:33, 16:5, 10:2, 6:5 and 1:2 respectively on the disappearance of grass silage DM and neutral-detergent fibre (NDF), and on particle-associated carboxymethylcellulase (EC 3.2.1.4; CMCase) and xylanase (EC 3.2.1.8) activities extracted from feed residues. Another objective was to compare microbial activity inside the bags and in rumen ingesta. Rumen incubation periods were 3, 6, 12, 24, 48 and 96 h. DM and NDF disappearance and particle-associated enzyme activities were greatly reduced with the smaller pore size and/or open surface area. Re-analysing some of the data as a 2 x 2 factorial (pore size x free surface area) indicated that, generally, free surface area rather than pore size affected the disappearance of feed components and particle-associated enzyme activities. Enzyme activities were highly correlated with NDF disappearance at 6-48 h of incubation. Cumulative area under CMCase and xylanase activity curves explained 0.79 and 0.88 of the variation in NDF disappearance when different cloth type and 6-48 h incubation data were combined. Weighted mean enzyme activities inside the bags were less than 0.35 those in rumen ingesta. The highest activity values inside the bags (24 or 48 h) were less than 0.50 those found in rumen ingesta. The lower microbial activity inside the bags explains the slower rates of NDF digestion reported with in situ techniques than with rumen evacuation techniques. The general assumption of similar microbial activity inside the bags and in rumen ingesta is not justified by the present results, and caution must be taken in interpreting in situ results quantitatively for feed evaluation systems.

Animal Nutritional Physiological Phenomena↗

Coupling ultrafiltration with an activated carbon cloth for the treatment of highly coloured wastewaters: a techno-economic study.

This work investigates the coupling of a membrane technique, ultrafiltration, with a recent adsorbent, activated carbon cloth for the treatment of industrial highly coloured wastewaters. A first experimental part shows the high treatment ability of this process for fountain-pen inks effluents arising from the rinsing of vats in which inks were produced. Whereas ultrafiltration enables more than 97% of colour removal, COD and DOC are not completely retained and a residual value of 1,700 mg l(-1) of DOC is obtained in the permeate. The second step of the process, activated carbon cloth, allows residual organic matter to be removed and a complete discolouring of the permeate. Adsorption capacities of COD and DOC are high, equal to 500 and 250 mg g(-1) respectively. Furthermore, this adsorbent induces a complete removal of glycol compounds (acting as antifreeze) which were not retined by a nanofiltration technique. A second part is an evaluation of the economic feasibility of such an integrated process. Only direct costs are considered at this phase of the study, and are divided into fixed costs (equipment, depreciation, maintenance), variable costs (electricity and consumption) and labour costs. The technical-economic study is carried out for two configurations: a low capacity unit (the UF membrane area is 2.4 m2) and an industrial capacity unit (with a 100 m2 UF membrane). Costs per treated m3 are respectively 111 and 32 euros, with costs partitioning which are dependent on the unit capacity.

Absorption↗

Hydrogen sulfide and ammonia removal on activated carbon fiber cloth-supported metal oxides.

The present investigation attempts to provide mechanisms for the influence of metal catalysts on carbon supports in odorous gas removal. For this purpose, an activated carbon fiber cloth (ACFC) was subjected to successive metal impregnation to modify its surface properties and so increase its treatment capacity. The carbon fiber cloth adsorbent was prepared by classical incipient wetness impregnation followed by calcination in order to obtain metal oxide phases. Different impregnation parameters (type of metal, level of impregnation, calcination temperature) in the removal of hydrogen sulfide and ammonia were studied. Adsorption kinetics and capacities were carried out in a batch reactor at room temperature. It was found that removal activity depended on metal loading as well as on the order of the metal addition and calcination phase. The capacity of ACFC-supported metal oxides to adsorb both pollutants showed great improvement compared to the virgin adsorbent.

Adsorption↗

External capillary condensation and adsorption of VOCs onto activated carbon fiber cloth and felt.

Adsorption isotherms of some volatile organic compounds (VOCs), present in air at concentrations ranging from 10 to 2500 mg m(-3), were performed onto activated carbon fiber cloth and felt. The VOCs loading air were isopropanol, toluene, acetone, methyl ethyl ketone, ethyl acetate and dichloromethane. Isotherm adsorption data were generated. These experimental values were modeled by the equation of Dubinin and co-workers and by the Langmuir relation. Model parameters are discussed as a function of adsorbent materials and VOC structure. Adsorption capacity was generally found higher for the cloth than for the felt. An effect of external capillary condensation onto the felt of compounds with high surface tension was demonstrated for VOC concentrations above 1500 mg m(-3).

Adsorption↗

Experimental studies on an artificial trachea of collagen-coated poly(L-lactic acid) mesh or unwoven cloth combined with a periosteal graft.

Artificial tracheas were fabricated from poly(L-lactic acid) mesh or unwoven cloth coated with collagen in order to reconstruct the respiratory airway by self regeneration without retaining the prosthesis at the replacement site, thus preventing infection, air leakage, granulation tissue formation, and displacement of the prosthesis. Nine weeks after placing a periosteal autologous graft from the tibia around the cervical trachea of a rabbit, bone rings formed without infection. Two weeks after replacement of an 8 X 8 mm window-shaped section of the cervical trachea with autologous periosteum, the internal surface of the trachea was well epithelialized without local complications, but ossification was not seen. One week after cervical substitution with our 2 cm long artificial trachea combined with the periosteal graft, cartilage was produced around the mesh material but neither ossification nor epithelization was observed thereafter, probably due to local infection. On the other hand, cartilage, bone, and epithelium did not form around the unwoven cloth artificial trachea after the substitution, probably because of severe infection due to collapse of the tracheal lumen. However, the formation of bone rings around the trachea suggests preservation of the neotracheal lumen, which may have potential for the treatment of tracheomalacia and/or bronchomalacia.

Animals↗