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At least 505 records · Page 28Linked to original sources
PubMed1994

Determination of thyroxine in urine by cathodic stripping square-wave voltammetry.

A square-wave polarographic method for the determination of the amino acid thyroxine in urine, after isolation from the matrix on a C18 Sep-Pak cartridge and subsequent elution through a column packed with Amberlite IRA-400 anionic resin, was developed. The optimal working conditions for the application of the method were found to be pH 10, provided by a carbonate buffer, and a potential of -0.690 V during 10 min. The equilibration time was applied during 5 s, and potential scans were performed at a square-wave amplitude of 100 mV and a scan rate of 300 mV s-1, with a square-wave frequency of 100 Hz. The measuring-system response was linear over the thyroxine concentration range from 10 to 60 ng ml-1 and the detection limit achieved was 2.71 ng ml-1. The relative error and relative standard deviation obtained were 1.18 and 4.67%, respectively.

Electrochemistry↗
PubMed2004

An improved palladium-based DMFCs cathode catalyst.

A novel carbon-supported palladium-rich Pd3Pt1/C catalyst prepared by a modified polyol process showed a better cell performance than Pt/C in direct methanol fuel cells, which may be attributed to palladium's inactivity to methanol electro-oxidation while exhibiting good performance to oxygen reduction reaction.

Journal Article↗
PubMed2005

Mesoporous palladium-the surface electrochemistry of palladium in aqueous sodium hydroxide and the cathodic reduction of nitrite.

The voltammetry of nanostructured palladium layers electrodeposited from a hexagonal liquid crystal phase onto platinum microdiscs show well defined peaks for the adsorption/desorption of hydrogen and surface oxidation/reduction in 2 M NaOH. These peaks are more clearly resolved than at smooth palladium and reveal the complications associated with hydrogen adsorption/desorption on palladium in aqueous alkaline solutions. The reduction of nitrite at the nanostructured palladium is also reported and it is shown that it occurs via a mechanism involving a chemical reaction between adsorbed hydrogen and adsorbed nitrite ion.

Adsorption↗