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Full-scale trials of recycled glass as tertiary filter medium for wastewater treatment.

Pilot-scale trials at a domestic wastewater treatment works compared the performance of three grades of recycled glass (coarse, medium and fine) when used as tertiary filter media for total suspended solids removal (TSS). Fine glass produced the best effluent quality but blinded rapidly and coarse glass could process three times the flow but with a reduction in final effluent quality. The medium glass offered a compromise with similar flow characteristics to the coarse glass, yet still achieve good solids removal, albeit less than the fine glass. Full-scale studies compared the performance of medium glass with the sand medium that is typically used in this application. There was little difference between them in terms of TSS removal, and they both removed around 75% of TSS from the influent, provided that the solids concentration did not exceed 70mg/l. However, the glass media had superior flow characteristics and was able to treat an additional 8-10% of the influent following the backwash cycle. Over the study period, the influent to the filters had an average TSS concentration of 38mg/l and produced an effluent with an average of 15mg TSS/l. In order to design for an average TSS concentration of 20mg/l, the maximum solids loading on the medium should not exceed 0.25kg solids/m(3)/h. Selecting recycled glass as a tertiary filter medium will give a 10% reduction in the amount of media required, compared to sand. It also carries with it the benefits of using a recycled material, and although these are more difficult to quantify they include: reduced CO(2) emissions and use of a more sustainable product that promotes favourable publicity and positive environmental reporting.

Conservation of Natural Resources↗

Element migration from glass compositions containing no added lead.

Six crystal glass compositions without added lead were used to prepare standard beakers having a volume of ca. 240 ml. The experimentally determined concentrations of the elements in the glass beakers were in satisfactory agreement with the theoretically predicted values. The degree of leaching of selected elements from these beakers was determined using 4% acetic acid as described in the ISO 7086-1:2000 standard test. In addition, to the degree of leaching by 4% acetic acid, migration into cola, red wine, 40% ethanol and 0.3% citric acid was also determined. Elements tested included antimony, barium, bismuth and zinc as these were considered to be of most interest. The results show that it is possible to produce durable glass containing no added lead. The overall quality of the glasses was good and the concentrations of the various elements migrating (leaching) into the various test solutions used was very small and it is clear that they would not present a hazard to consumers in the event that they were to use glasses of any of these compositions for consumption of either alcoholic or non-alcoholic beverages. The original ISO7086-1:2000 test using a 4% acetic acid leaching solution was developed to test for lead migration from crystal containing added lead and ceramic ware containing lead glazes or colouring. This work also shows that it is an excellent leaching agent for assessing the safety of crystal containing no added lead as it gave the highest degree of migration for all the glass compositions and all the elements tested. In the case of glasses containing ZnO, it was shown that the degree of zinc migration was linearly related to the mole-% of ZnO in the glass. With respect to the durability of glasses, it was shown that the degree of attack increases when the degree of silica depolymerisation increases.

Acetic Acid↗

In vivo vs in vitro anticariogenic behavior of glass-ionomer and resin composite restorative materials.

OBJECTIVE: To evaluate the in vivo vs the in vitro anticariogenic potential of glass-ionomer and resin composite restoratives, utilizing a standardized interfacial gap model. METHODS: (a) In vitro study. Box shaped cavities were prepared at the buccal surfaces of extracted premolars limited to enamel. The incisal cavity walls received no treatment and were covered with 40 microm-thick metal spacers. The cavities were restored with a glass-ionomer (Ketac-Fil, n=8) and a fluoride-free resin composite (Scotchbond MP Plus/Z100, n=8). After 4 weeks immersion in an acidic gel (pH 4), thin sections were produced and examined under polarized-light microscopy.(b) In vivo study. Four low caries activity volunteers, with first four premolars, each planned to be extracted for orthodontic reasons, participated in the study. Cavities were prepared as before and filled contralaterally per patient with glass-ionomer (n=8) and resin composite (n=8). After 6 months in vivo, the teeth were extracted, sectioned and investigated by polarized-light microscopy, Raman microspectroscopy and SEM-EDS X-ray microanalysis. Unpaired t-test (lesion dimensions) and one-way ANOVA and Newman-Keuls tests (Ca, P wt%, Ca/P ratios) were used to identify statistically significant differences in lesion analysis (alpha=0.05). RESULTS: (a) In vitro study. All restorations developed lesions at incisal and cervical margins. At gap-free regions glass-ionomers showed reduced lesion dimensions compared to those of composites (p<0.05). At regions with gaps, no significant differences were found in lesion depth between the restorative groups tested. Lesion length was increased in composite, and decreased in glass-ionomer, whereas lesion depth in both restorative groups was increased in comparison to gap-free regions (p<0.05).(b) In vivo study. No lesions were observed at gap-free regions. At gap regions, 75.5% of glass-ionomer and 62.5% of composite restorations developed lesions. The lesion dimensions were significantly greater in glass-ionomer (p<0.05). A reduction in PO4(3-), CO3(2-), Ca and P was found in lesions compared to intact tissues. No F was detected and no CaF2 lattice vibrations were found at the enamel margins facing the gap adjacent to glass-ionomers. SIGNIFICANCE: In the presence of a standardized interfacial gap, no preventive effect was exerted in vivo from the glass-ionomer to protect the adjacent enamel wall from secondary caries attack. The lack of any correlation between the in vivo and in vitro models tested implies that artificial caries experiments have a negligible clinical relevance in predicting the in vivo effect.

Adolescent↗

The effect of investment material and ceramming regime on the surface roughness of two castable glass-ceramic materials.

OBJECTIVE: To assess the surface roughness (R(a)) of two castable glass-ceramic materials, cast using four different investment materials and employing different ceramming regimes. METHODS: Forty discs, each 12 mm diameter and 2 mm thick were produced from two castable glass-ceramic materials, one a glass ionomer derivative based on 1.5SiO(2)-1Al(2)O(3)-0.53P(2)O(5)-1CaO-0.67CaF(2) (LG112), the other a fluorcanasite material based on 0.60SiO(2)-0.05K(2)O-0.10Na(2)O-0.15CaO-0.10CaF(2) (SG3). The discs were made using four dental investments, two gypsum-bonded (Whip-Mix Cristobalite (WMC), Degussa California (DC)) and two phosphate-bonded (Fujivest Super (FS), Techceram Glass (TG)). A Ni-Cr metal/ceramic alloy (Wiron 99) was also used as a control. Each investment was used to produce 10 discs for each glass-ceramic material, five left in the as-cast, glass state, the other five cerammed. Ceramming was carried out either within the investment mold or after de-vesting from the investment mold. The discs had their surface roughness values measured using a stylus, surface contact measuring instrument. RESULTS: For the Ni-Cr alloy the phosphate-bonded investments produced discs significantly smoother than those produced by the two gypsum-bonded investments (p<0.05). The FS investment produced the smoothest discs (p<0.05), but there was no significant difference between the discs produced by the two gypsum-bonded investments (p>0.05). For the SG3 material no significant differences were seen between the as-cast glass and cerammed discs (p>0.05), with the WMC investment producing the smoothest discs (p<0.05), and the TG investment the roughest (p<0.05). The LG112 material showed a significant difference between glass and cerammed discs for the gypsum-bonded investments (p<0.05) but not when using phosphate-bonded investments (p>0.05). With LG112 the WMC investment produced smoother discs than the DC and TG investments (p<0.05). The DC investment produced rougher discs than the two phosphate-bonded investments (p<0.05). SIGNIFICANCE: The selection of investment material can have a significant effect on the as-cast surface finish of castable glass-ceramic materials. A gypsum-bonded investment material gave smoother surface finishes compared to phosphate-bonded investments. The ceramming process significantly increases surface roughness.

Analysis of Variance↗

Properties and cytotoxicity of water soluble Na2O-CaO-P2O5 glasses.

Various compositions of Na2OCaO-P2O5 glasses are prepared to estimate glass formation, dissolution properties and cytotoxicity. In the wide composition range of 40 mol% of P2O5 or more, clear glass samples were obtained. The estimated glass forming region was consistent with other ternary phosphate glass systems. The glass transition temperatures and crystallization temperatures decreased with increasing P2O5 content and increased with CaO content. Dissolution properties in distilled water and simulated body fluid (SBF) were measured. In distilled water, CaO free glasses showed extremely fast dissolution. The dissolution rate decreased with increasing CaO content and decreasing P2O5 content. This composition effect results from cross-link formation between the non-bridging oxygens of two different chains by Ca2+ ions which improves the phosphate network strength. In SBF, the dissolution rate followed a similar trend, but glass dissolution was suppressed. This suppression occurred due to the existence of soluble species of glass such as Na+, Ca2+ and HPO(2-)4. The cytotoxicity decreased with increasing CaO content and with decreasing PO2.5 content. This was the result of a change in pH and ion concentration in the medium.

Biocompatible Materials↗

Bioactive ceramics prepared by sintering and crystallization of calcium phosphate invert glasses.

Novel glass-ceramics were synthesized via sintering and crystallization by heating powder compacts of SiO2-free calcium phosphate invert glasses of 60CaO x 30P2O5 x 7Na2O x 3TiO2 or 60CaO x 30P2O5 x 7Na2O x 3MgO at 800-850 degrees C in air. The glass-ceramics were relatively dense materials consisting of crystalline phases such as beta-Ca3(PO4)2 and beta-Ca2P2O7 with glassy phases. The compacts were densified by the viscous flow of the glassy phases while heating. By soaking in simulated body fluid at 37 degrees C, a calcium phosphate phase was formed newly on the surface of the glass-ceramic derived from 60CaO x 30P2O5 x 7Na2O x 3TiO2 glass, while the phase was not formed on that derived from 60CaO x 30P2O5 x 7Na2O x 3MgO glass: the former was implied to show bioactivity. Composition of the glassy phase as the matrix varies with the additives such as TiO2 and MgO, and the chemical properties of the phase influence the bioactivity of the glass-ceramics. The glass-ceramic derived from 60CaO x 30P2O5 x 7Na2O x 3TiO2 glass has relatively high fracture toughness of K(IC) approximately 2 MPa m(0.5) and bending strength of 100-120 MPa.

Calcium Compounds↗

Foreign body retention in glass-caused wounds.

STUDY OBJECTIVE: To describe patient and wound characteristics that are clinically useful in identifying wounds that were caused by glass and retained a foreign body. DESIGN: Retrospective consecutive case review. SETTING: Urban, university-affiliated teaching hospital. TYPE OF PARTICIPANTS: Four hundred thirty consecutive patients with a total of 578 evaluable wounds caused by glass during a 12-month period. MEASUREMENTS AND RESULTS: Medical records were reviewed to determine patient demographics, primary wound data (eg, location, type, description), mechanism of injury, type of glass involved, and presence of foreign body sensation. Glass was found by examination in 7% of wounds. Eight percent of 137 radiographs were positive. Wounds with the highest prevalence of retained glass were puncture wounds (P < .0005), those caused by stepping on glass or by a motor vehicle accident (P < .005), and those of the head or foot (P < .003). CONCLUSION: Characteristics of wounds most likely to retain glass were identified in this retrospective study. The presence of these factors should increase the clinician's suspicion of a retained glass foreign body. The indications for radiography for the detection of retained glass in wounds should be clarified with prospective studies.

Adult↗

Retained glass foreign bodies in wounds: predictive value of wound characteristics, patient perception, and wound exploration.

A convenience sample of 164 adult patients with 185 glass-caused wounds who presented to an emergency department (ED) and consented to a radiograph was prospectively studied. The purpose was to determine the characteristics of wounds at high risk for foreign body (FB) and the predictive value of patient FB sensation and probing wound exploration for FB retention. Retained glass was located in 28 (15%) wounds. Motor vehicle as a mechanism of injury (P=.003), head as a location (P=.035), and puncture as wound type (P=.002) were more likely to be associated with retained FBs (chi2 analysis). Patients with wounds with glass were more likely to have a positive perception of a foreign body (41%) than those with no glass (17%) (P=.005). The positive predictive value of patient perception was 31%; negative predictive value was 89%. In five cases, wound exploration was negative and subsequent radiograph was positive for FB. In one of these cases, a 4-mm glass FB was removed; in the other four, no FB was found. In conclusion, head wounds resulting from motor vehicle accidents or puncture wounds are more likely to harbor retained glass FBs. Patients with glass FB in wounds are more likely to have a positive perception of FB; however, a positive perception has a low predictive value of glass FB. In this series, a negative wound exploration made the presence of retained FB greater than 2 mm less likely but did not rule out the presence of retained glass.

Adult↗

Glass recycling in cement production--an innovative approach.

An innovative approach of using waste glass in cement production was proposed and tested in a laboratory and cement production plant. The laboratory characterization of 32 types of glass show that the chemical composition of glass does not vary significantly with its color or origin but depends on its application. The alkali content of glass, a major concern for cement production varies from 0 to 22%. For the glass bottles mainly found in Hong Kong waste glasses, the alkali content (Na2O) ranges from 10 to 19% with an average around 15%. There is no significant change of the SO2 content in the gas exhaust of the rotary kiln when about 1.8 t/h of glass bottles were loaded along with the 280-290 t/h raw materials. The content of NOx, mainly depends on the temperature of the kiln, does not show significant change either. The SO3 content of the clinker is comparable with that obtained without the loading of glass. The alkaline content shows a slight increase but still within three times the standard deviation obtained from the statistical data of the past year. The detailed analysis of the quality of the cement product shows that there is not any significant impact of glass for the feeding rate tested.

Conservation of Natural Resources↗

Thermal and optical properties of Tm3+ doped tellurite glasses.

Ultraviolet, visible (UV/VIS) and differential thermal analysis (DTA) measurements were carried out in order to investigate the optical and thermal properties of various 0.5 mol.% Tm2O3 containing (1 - x)TeO2 + xLiCl glasses in molar ratio. The samples were prepared by fusing the mixture of their respective reagent grade powders in a platinum cricuble at 750 degrees C for 30 min. DTA curves taken in the 23-600 degrees C temperature range with a heating rate of 10 degrees C/min reveal a change in the value of the glass transition temperature, Tg, while melting was not observed for the glasses containing LiCl content less than 50 mol.%. These glasses were found to be moisture-resistant. However, the glasses with LiCl content higher than 50 mol.%, in which a melting peak was observed at Tc = 401 degrees C, were moisture-sensitive. Absorption measurements in the UV/VIS region of the glasses without Tm2O3 content show that the Urbach cutoff occurs at about 320 nm and, is relatively independent of the LiCl content. Six absorption bands were observed in the Tm2O3 doped glasses corresponding to the absorption of the 1G4, 3F2, 3F3 and 3F4, 3H5 and 3H4 levels from the 3H6 ground level of Tm3+ ions. The spectra also show that the integrated absorption cross-section of each band depends on the glass composition. Judd-Ofelt theory was used to determine the Judd-Ofelt parameters as well as the radiative transition probabilities for the metastable levels of Tm3+ ions in (0.3)LiCl + (0.7) TeO2: 0.01 Tm2O3 glass which is moisture-resistant.

Crystallization↗

Inertial suppression of protein dynamics in a binary glycerol-trehalose glass.

The traditional approach used to predict the ability of a glassy matrix to maximally preserve the activity of a protein solute is the glass transition temperature (T(g)) of the glass. Recently it has been shown that the addition of a low T(g) diluent (glycerol) can rigidify the structure of a high T(g) glassy matrix in binary glycerol-trehalose glasses. The optimal density of glycerol in trehalose minimizes the average mean square displacements of non-exchangeable protons in the glass samples. The amount of glycerol added to a trehalose glass coincides with the maximal recovery of biological activity in a separate study using similar binary glass samples. In this study, we use molecular dynamics (MD) simulations to investigate the dynamics of a hydrated protein encased in glycerol, unary trehalose and binary glycerol-trehalose glasses. We have found that we are able to reproduce the rigidification of the glycerol-trehalose glassy matrix and that there is a direct correlation between bulk glass dynamics and the extent of atomic fluctuation of protein atoms. The detailed microscopic picture that emerges is that protein dynamics are suppressed mainly by inertia of the bulk glass and to a lesser extent specific interactions at the protein-solvent interface. Thus, the inertia of the glassy matrix may be an influential factor in the determination of pharmaceutically relevant formulations.

Glass↗

The role of the ionomer glass component in polyacid-modified composite resin dental restorative materials.

In order to model the processes that occur within polyacid-modified composite resin ("compomer") dental restoratives, a series of experiments has been carried out with silanated and silane-free ionomer glass G338, and silanated and silane-free unreactive glass (Raysorb T-4000). In an acid-base reaction with dental grade aqueous maleic acid-acrylic acid copolymer solution, the setting time of the silanted G338 was found to be 9 min, compared with 5 min for the silane-free glass. Inclusion of each glass in an experimental composite resin system showed that the formulations which contained G338 absorbed more water than the formulations which contained Raysorb T-4000, regardless of whether or not the glass was silanted. Biaxial flexure strength was superior for experimental composites containing Raysorb T-4000, with highest results being obtained with the silanated glass. Overall these results demonstrate that silanation of the filler is essential for optimal physical properties but that, for the ionomer glass, it inhibits the acid-base reaction. The presence of ionomer glass led to an increase in water uptake compared with the unreactive glass, regardless of the presence of silane.

Composite Resins↗

Calcium and silicon from bioactive glass concerned with formation of nodules in periodontal-ligament fibroblasts in vitro.

Previously, the authors reported that bioactive glass promoted formation of nodules in cultured periodontal-ligament fibroblasts and high concentrations of calcium and silicon were detected in the culture medium. Herein, the effects of bioactive glass, calcium alone and calcium and silicon for formation of nodules on the periodontal-ligament fibroblasts are examined. The cells were cultured with bioactive glass, without bioactive glass, calcium and silicon, with calcium alone and with calcium and silicon. The cell growth, alkaline-phosphatase activity, amount of pro-collagen type I and the number of nodules were measured periodically until the 21st day. The cell growth rate with calcium and silicon was the highest, however the rate with bioactive glass and calcium alone were similar to that without them. The alkaline-phosphatase activity and the amount of pro-collagen showed peaks at the 11th day. At the peak, the alkaline-phosphatase activity with bioactive glass or calcium and silicon, and the pro-collagen with bioactive glass was higher than without them. The number of nodules with bioactive glass, calcium alone or calcium and silicon was greater than without them. These findings suggested that the combination of calcium and silicon released from bioactive glass was concerned with the formation of nodules on the periodontal-ligament cells.

Alkaline Phosphatase↗

Antibacterial and physical properties of resin modified glass-ionomers combined with chlorhexidine.

The purpose of this study was to determine the effect on mechanical properties and antimicrobial activity of the addition of chlorhexidine (CHX) to a resin modified glass-ionomer (Photac-fil, ESPE, Norristown, PA, USA). Chlorhexidine diacetate was combined with a resin modified glass-ionomer material at a concentration of 5%. The samples were tested for hardness, tensile strength and erosion at 24 h and 6-week intervals and for elution of CHX and antimicrobial activity weekly for 6 weeks. At 24 h there was no significant difference in hardness between the two groups, but at 6 weeks the resin modified glass-ionomer group was significantly harder than the CHX groups (P < 0.05). The diametral tensile strength test indicated no difference between the control and CHX groups at 24 h or at 6 weeks. The jet erosion test demonstrated significantly less erosion with the CHX group at 24 h but at 6 weeks the CHX group showed significantly more erosion than the control group. The chemical assay data demonstrated a peak elution of CHX at week 1 with residual amounts at weeks 2 and 3. The microbial data demonstrated that the CHX group had a significant reduction in Streptococcus mutans numbers for weeks 1-3, but after week 4 there was no difference between the glass-ionomer with and without CHX. The addition of CHX to resin modified glass-ionomer altered hardness and erosion of the resin-modified glass-ionomer, but because there are no material specifications, it is difficult to determine clinical implications. Chlorhexidine did significantly improve the antimicrobial effect of the glass-ionomer which was consistent with the chemical assay data. The results indicated that the addition of CHX to resin modified glass-ionomer material (Photac-fil) did not seriously degrade the physical properties during the time period tested and that the addition of CHX resulted in a greater reduction in S. mutans when compared with glass-ionomer alone.

Analysis of Variance↗

An in vivo and ex vivo study to evaluate the use of a glass polyphosphonate cement in orthodontic banding.

The purpose of this study was to examine the effectiveness of a new glass polyphosphonate cement (Diamond) for orthodontic banding. Thirty-one subjects underwent in vivo testing to compare the failure rate of bands cemented using the test cement and bands cemented using a conventional glass polyalkenoate cement (Ketac-Cem) over a 6-month period at the beginning of active appliance therapy. In an ex vivo experiment 60 extracted teeth were banded using either the test cement or a glass polyalkenoate cement, and subjected to a debanding force using a Lloyd universal testing machine until failure. In the in vivo study the overall proportion of failure of the bands cemented with each cement was identical at 0.048. However, in the ex vivo study the probability of failure for the glass polyphosphonate cement was significantly higher than for the glass polyalkenoate cement, and the force to deband the glass polyalkenoate cement was greater than that of the glass polyphosphonate cement. In the clinical setting the new glass polyphosphonate cement performed as well as a conventional glass polyalkenoate cement, and these results suggest that it could be used as an alternative cement for orthodontic banding. The results of the ex vivo test bring into question the usefulness of this laboratory test as an indicator of clinical performance.

Dental Bonding↗

Adherence of streptococci to surface-modified glass.

Four types of surface-modified glass were prepared. Aminopropyl glass was prepared by alkylsilylation of glass slides with gamma-aminopropyltriethoxysilane. This glass carries primary amino groups which may be protonated at pH 7.2. Owing to the presence of both positively charged ions and hydrophobic ethoxyl groups, the glass is considered to be amphipathic. Three other types of surface-modified glass slides were prepared from aminopropyl glass by forming Schiff's bases with three aldehydes: glucose, glyoxylic acid and hexanal. The aldehyde-treated slides were subsequently reduced using sodium borohydride. Thus, the surface of the glass was rendered hydrophilic, ampholytic or hydrophobic, respectively. The adherence of two Streptococcus sanguis strains and two Streptococcus mutans strains to the surface-modified glass slides was studied. Different strains showed differences in adherence to these slides depending on their physico-chemical surface properties. For S. sanguis ATCC 10556, hydrophobic bonds seemed to be most important, while in S. mutans OMZ 176, ionic interactions made the highest contribution to adhesion. Hydrogen bonds seemed to contribute least to adherence.

Bacterial Adhesion↗

Secondary caries formation in vitro around glass ionomer-lined amalgam and composite restorations.

The aim of this in vitro secondary caries study was to examine the glass-ionomer liner's effect on wall-lesion inhibition when a conventional and a light-cured glass ionomer liner was placed under amalgam and composite resin restorations. Class V preparations in extracted upper premolars were used and ten restorations were used for each of the following groups: (i) two layers of copal varnish and amalgam; (ii) conventional glass-ionomer and amalgam; (iii) light-cured glass-ionomer and amalgam; (iv) bonding agent and light-cured composite resin; (v) conventional glass-ionomer, bonding agent and light-cured composite resin; (vi) light-cured glass-ionomer, extended 0.3 mm short of the enamel margin bonding agent and light-cured composite resin; and (vii) light-cured glass-ionomer, extended 1 mm short of the enamel margin, bonding agent and light-cured composite resin. The teeth were thermocycled and artificial caries were created using an acid-gel. The results of this study showed that artificial recurrent caries can be reduced significantly (P < 0.05) with a glass-ionomer liner under amalgam restorations. The results also showed that when the light-cured glass-ionomer liner was placed 0.3 mm from the cavosurface margin under composite resin restoration, the artificial recurrent caries reduced significantly (P < 0.05).

Acids↗

Compositional and weave pattern analyses of glass fibers in dental polymer fiber composites.

PURPOSE: This study compared weave patterns and glass compositions of five glass fiber materials found in commercial fiber-reinforced dental composites. MATERIALS AND METHODS: A scanning electron microscope (SEM) was used to investigate the woven structure of five glass fiber products, and an energy-dispersive x-ray spectrometer (SEM/EDS) was used to determine the elemental composition of these glass fibers in the bulk and at the surface of the fiber. Five fibers of each product were analyzed. RESULTS: The fiber products were either unidirectional rovings or bidirectional weaves. More precisely, the woven structures were linen weave, twill weave, or twill weave ribbon. SEM/EDS analysis revealed that the composition of the glass fibers was typical for E (electrical)-glass fibers with one exception. One product intended for use in fixed prosthodontics included unidirectional fibers with a composition consistent with a modified high-tensile-strength R-glass. Boron oxide found on the surface of glass fibers would likely contribute to an increased potential for corrosion of fiber-reinforced composite. CONCLUSIONS: The predominant fiber composition in these products is E-glass. Because the degree of hydrolytic stability of polymer-fiber composites over time may lead to material failure in permanent restorations, this property should be investigated further.

Acrylic Resins↗