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At least 325 records · Page 18Linked to original sources
PubMed2003

Prototype sampling system for measuring workplace protection factors for gases and vapors.

A prototype sampling system for measuring respirator workplace protection factors (WPFs) was developed. Methods for measuring the concentration of contaminants inside respirators have previously been described; however, these studies have typically involved continuous sampling of aerosols. Our work focuses on developing an intermittent sampling system designed to measure the concentration of gases and vapors during inspiration. This approach addresses two potential problems associated with continuous sampling: biased results due to lower contaminant concentrations and high humidity in exhaled air. The system consists of a pressure transducer circuit designed to activate a pair of personal sampling pumps during inspiration based on differential pressure inside the respirator. One pump draws air from inside the respirator while the second samples the ambient air. Solid granular adsorbent tubes are used to trap the contaminants, making the approach applicable to a large number of gases and vapors. Laboratory testing was performed using a respirator mounted on a headform connected to a breathing machine producing a sinusoidal flow pattern with an average flow rate of 20 L/min and a period of 3 seconds. The sampling system was adjusted to activate the pumps when the pressure inside the respirator was less than -0.1 inch H(2)O. Quantitative fit-tests using human subjects were conducted to evaluate the effect of the sampling system on respirator performance. A total of 299 fit-tests were completed for two different types of respirators (half- and full-facepiece) from two different manufacturers (MSA and North). Statistical tests showed no significant differences between mean fit factors for respirators equipped with the sampling system versus unmodified respirators. Field testing of the prototype sampling system was performed in livestock production facilities and estimates of WPFs for ammonia were obtained. Results demonstrate the feasibility of this approach and will be used in developing improved instrumentation for measuring WPFs.

Environmental Monitoring↗
PubMed2004

Operational characteristics of effective removal of H2S and NH3 waste gases by activated carbon biofilter.

Simultaneous removal of hydrogen sulfide (H2S) and ammonia (NH3) gases from gaseous streams was studied in a biofilter packed with granule activated carbon. Extensive studies, including the effects of carbon (C) source on the growth of inoculated microorganisms and gas removal efficiency, product analysis, bioaerosol emission, pressure drop, and cost evaluation, were conducted. The results indicated that molasses was a potential C source for inoculated cell growth that resulted in removal efficiencies of 99.5% for H2S and 99.2% for NH3. Microbial community observation by scanning electron microscopy indicated that granule activated carbon was an excellent support for microorganism attachment for long-term waste gas treatment. No disintegration or breakdown of biofilm was found when the system was operated for 140 days. The low bioaerosol concentration emitted from the biofilter showed that the system effectively avoided the environmental risk of bioaerosol emission. Also, the system is suitable to apply in the field because of its low pressure drop and treatment cost. Because NH3 gas was mainly converted to organic nitrogen, and H2S gas was converted to elemental sulfur, no acidification or alkalinity phenomena were found because of the metabolite products. Thus, the results of this study demonstrate that the biofilter is a feasible bioreactor in the removal of waste gases.

Adsorption↗
PubMed2005

Evaluation of sample recovery of malodorous livestock gases from air sampling bags, solid-phase microextraction fibers, Tenax TA sorbent tubes, and sampling canisters.

Odorous gases associated with livestock operations are complex mixtures of hundreds if not thousands of compounds. Research is needed to know how best to sample and analyze these compounds. The main objective of this research was to compare recoveries of a standard gas mixture of 11 odorous compounds from the Carboxen/PDMS 75-microm solid-phase microextraction fibers, polyvinyl fluoride (PVF; Tedlar), fluorinated ethylene propylene copolymer (FEP; Teflon), foil, and polyethylene terephthalate (PET; Melinex) air sampling bags, sorbent 2,b-diphenylene-oxide polymer resin (Tenax TA) tubes, and standard 6-L Stabilizer sampling canisters after sample storage for 0.5, 24, and 120 (for sorbent tubes only) hrs at room temperature. The standard gas mixture consisted of 7 volatile fatty acids (VFAs) from acetic to hexanoic, and 4 semivolatile organic compounds including p-cresol, indole, 4-ethylphenol, and 2'-aminoacetophenone with concentrations ranging from 5.1 ppb for indole to 1270 ppb for acetic acid. On average, SPME had the highest mean recovery for all 11 gases of 106.2%, and 98.3% for 0.5- and 24-hr sample storage time, respectively. This was followed by the Tenax TA sorbent tubes (94.8% and 88.3%) for 24 and 120 hr, respectively; PET bags (71.7% and 47.2%), FEP bags (75.4% and 39.4%), commercial Tedlar bags (67.6% and 22.7%), in-house-made Tedlar bags (47.3% and 37.4%), foil bags (16.4% and 4.3%), and canisters (4.2% and 0.5%), for 0.5 and 24 hr, respectively. VFAs had higher recoveries than semivolatile organic compounds for all of the bags and canisters. New FEP bags and new foil bags had the lowest and the highest amounts of chemical impurities, respectively. New commercial Tedlar bags had measurable concentrations of N,N-dimethyl acetamide and phenol. Foil bags had measurable concentrations of acetic, propionic, butyric, valeric, and hexanoic acids.

Acetophenones↗
PubMed1996

Efficacy of intraoperative heat administration by ventilation with warm humidified gases and an oesophageal warming system.

We measured changes in body temperature in 12 hypothermic (mean aural temperature 34.4 (SD 1.0) degrees C) pigs during general anaesthesia with an open abdominal cavity and the effect of two warming systems: heating of inspired gases to 39 degrees C (intratracheal temperature) and oesophageal warming to 39 degrees C by a water perfused oesophageal heat exchanger. Each animal underwent both treatments and the control period in random sequence. Each condition was studied over 1 h. No additional protection against heat loss (drapes, blankets, i.v. fluids warming, etc.) was used. Anaesthesia, room temperature and relative humidity, amount and temperature of infusions and extension of exposed visceral surfaces were standardized. Mean decrease in body temperature was 1.0 (0.7) degree C (P < 0.005) without warming and 0.6 (0.2) degree C (P < 0.005) with heated inspired gases: this difference was not statistically significant. Oesophageal warming was very efficient as mean body temperature did not change significantly (-0.1 (0.2) degree C; ns).

Anesthesia, General↗
PubMed1982

Excretion of breath and flatus gases by humans consuming high-fiber diets.

The abilities of dietary fibers to promote the excretion of intestinal fermentation gases were evaluated in five healty men. Flatus and breath gases were collected and analyzed during 3 days of each 9-day metabolic period. Responses to feeding xylan, pectin, cellulose and corn bran were compared to a fiber-free formula diet. Generally, hydrogen production increased throughout the day, whereas methane production remained more constant. Methane excretion was greater while consuming the xylan and pectin diets than while consuming the other diets. These two purified fibers also caused higher flatus volume, hydrogen and carbon dioxide excretion. Cellulose and corn bran generally resulted in breath and flatus gas excretion at levels equivalent to fiber-free diets. Considerable variation was noted in the response of subjects to an individual diet. However, in most cases 2-5 days of frequent and daily consumption of the diets was necessary to establish a relatively constant level of gas excretion. This time may represent the period of microbial and enzymatic adaptation to the new dietary constituents.

Adult↗
PubMed1991

Sealed mini-chamber of variable depth for direct observation and extended evaluation of sperm motility under the influence of various gases.

A new chamber for microscopical observation of living cells, e.g. spermatozoa, under hermetically sealed conditions and over an extended period is described. Motile spermatozoa were serially observed for several hours and the effect of various gases on sperm motility has been studied. The chamber could also be used to study the effect of various toxic gases in the fields of microbiology and toxicology.

Atmosphere Exposure Chambers↗
PubMed2004

Recombination chambers filled with different gases--studies of possible application for BNCT beam dosimetry.

Recombination microdosimetric method (RMM), based on the phenomenon of initial recombination of ions is applied to determine the distribution of the absorbed dose versus linear energy transfer (LET). Usually, the recombination chambers used for RMM are filled with tissue-equivalent gas, but the response of the device can be adjusted to the actual needs by the use of different gases. Using a graphite chamber filled with nitrogen and 10BF3 it was shown that RMM can also be used with chambers containing these gases. This opens the possibility of designing a recombination chamber for the determination of the dose fractions due to gamma radiation, fast neutrons, neutron capture on nitrogen and high-LET particles from the (n,10B) reaction in simulated tissue with different contents of 10B. It was also necessary to improve the method for the determination of initial recombination at low polarising voltages, when volume-recombination and back-diffusion of ions are considerably high.

Algorithms↗
PubMed2005

Effects of pneumoperitoneal gases and pressures on transitional cell carcinoma adhesion, growth, apoptosis and necrosis: an in vitro study.

PURPOSE: We studied the effects of insufflation gas and pressure on the adhesion, growth, apoptosis and necrosis of transitional cell carcinoma (TCC) in an in vitro model. MATERIALS AND METHODS: Tumor adhesion and cell growth of AY-27 rat TCC was measured after 3-hour incubation with CO2, N2 and He insufflation at different pressures (0, 10 and 15 mm Hg) in vitro. The effects of these gases on the rate of tumor cell apoptosis and necrosis were compared. RESULTS: In vitro the tumor adhesion rate was lowest with CO2 and highest with N2. Higher gas pressures resulted in decreased adhesion rates for CO2 and He but increased adhesion rates for N2. N2 enhanced tumor cell proliferation at all pressures studied. He and CO2 resulted in an initial increase in cell proliferation in the first 24 hours, followed by a decrease in tumor growth. Extracellular medium turned acidic in CO2 (pH 6.27 to 6.39) but basic in N2 and He (pH 8.39 to 8.84). At all insufflation pressures studied apoptosis and necrosis rates were increased in the first 24 hours, followed by a decrease for CO2 and N2. He resulted in increasing apoptosis and necrosis throughout the study period. CONCLUSIONS: The type of gas and insufflation pressure affects cell adhesion and tumor growth. There was a significant increase in tumor adhesion and proliferation with N2 insufflation compared with CO2 and He at 0 to 15 mm Hg pressures. CO2 demonstrated the greatest decrease in TCC adhesion and proliferation at 15 mm Hg pressure. Apoptosis and necrosis were highest for He compared with the other gases.

Animals↗
PubMed2005

Velocity distributions of granular gases with drag and with long-range interactions.

We study velocity statistics of electrostatically driven granular gases. For two different experiments, (i) nonmagnetic particles in a viscous fluid and (ii) magnetic particles in air, the velocity distribution is non-Maxwellian, and its high-energy tail is exponential, P(upsilon) approximately exp(-/upsilon/). This behavior is consistent with the kinetic theory of driven dissipative particles. For particles immersed in a fluid, viscous damping is responsible for the exponential tail, while for magnetic particles, long-range interactions cause the exponential tail. We conclude that velocity statistics of dissipative gases are sensitive to the fluid environment and to the form of the particle interaction.

Air Movements↗
PubMedDate not supplied

The effect of various dissolved gases on the heat defect of water.

Recent measurements of the absorbed dose to air-saturated water, made using water calorimetry and assuming a zero heat defect for irradiated water, gave results 2%-5% higher than those determined by more conventional means. According to the current radiation chemical model for air-saturated water, the dose measured by water calorimetry assuming a zero heat defect should actually be 2% too low because of the endothermicity of the radiolysis processes in water. In order to examine possible sources for this discrepancy, we have constructed a small calorimeter (holding 100 ml of water) with which to measure the temperature rise in irradiated water saturated with various gases. The gases used were air, oxygen, argon, nitrogen, and hydrogen/oxygen mixtures. Irradiations were carried out with 20-MV x rays at a dose rate of 0.41 Gy/s. Our results are consistent with model calculations, except for some differences for accumulated doses of less than 100 Gy. The discrepancies we find at low doses and the discrepancies observed by others using water calorimeters may arise from impurities in the water.

Calorimetry↗
PubMed1969

Stabilities of dried suspensions of influenza virus sealed in a vacuum or under different gases.

Suspensions of purified influenza virus, dried to a 1.4% content of residual moisture by sublimation of ice in vacuo, were sealed in a vacuum or under different gases of high purity. The stabilities of the several preparations were determined by an accelerated storage test. Based on the times predicted for the dried preparations stored at different temperatures to lose 1 log of infectivity titer, the order of stabilities in relation to sealing in vacuum or under different gases was as follows: helium > hydrogen > vacuum > argon > nitrogen > oxygen > carbon dioxide.

Argon↗
PubMed1980

Predictable "individual differences" in uptake and excretion of gases and lipid soluble vapours simulation study.

A five-compartment pharmacokinetic model with two excretory pathways, exhalation and metabolism, based on first order kinetics is used to outline the effect of body build, pulmonary ventilation, and lipid content in blood on uptake, distribution, and clearance of low solubility gases and lipid soluble vapours during and after exposure. The model shows the extent that individual differences have on altering uptake and distribution, with consequent changes in blood concentration, rate of excretion, and toxicity, even when variations in these parameters are within physiological ranges. The model is also used to describe the concentration variation of inhaled substances in tissues of subjects exposed to concentrations with permitted excursions. During the same course of exposure, the tissue concentrations of low solubility gases fluctuate much more than tissue concentrations of lipid soluble vapours. The fluctuation is reduced by metabolism of inhaled substance. These conclusions are recommended for consideration whenever evaluating the effect of excursions above the threshold limit values used in the control of industrial exposures (by excursion factors).

Body Constitution↗
PubMed1979

Solubility of inert gases in homogenates of canine lung tissue.

The solubility of sulfur hexafluoride (SF6), ethane, cyclopropane, halothane, diethyl ether, and acetone in homogenates of dog lung tissue were measured and compared with values obtained in dog blood. The measurements were made to provide data for a method for determining distribution of ventilation, blood flow, and tissue volume (Physiologist 20: 95, 1977) and for reasons discussed, the blood was not washed from the tissue prior to homogenization. All gases except SF6 were significantly more soluble in blood than lung tissue, whereas SF6 was 3.7 times more soluble in tissue than blood. It was further found that SF6 is 5 times more soluble, and ethane is twice as soluble in tissue obtained from lungs containing blood than in tissue obtained from rinsed lungs, suggesting that measurements of parenchymal solubility made on tissue from sinsed lungs may be considerably in error for some lipid-soluble gases.

Animals↗
PubMed1985

Model simulation of single-breath washout of insoluble gases from dog lungs.

Intrapulmonary gas mixing by convection and diffusion is analyzed on the basis of various analog lung models incorporating singly or in combination series inhomogeneity, parallel inhomogeneity, intercompartmental diffusion, sequential inspiration, and sequential expiration. The slope of the alveolar plateau of insoluble gases is used as an indicator for incomplete gas mixing. By use of the models, we have attempted to simulate experimental results obtained in artificially ventilated dog lungs with simultaneous single-breath washout of He and SF6 (Meyer et al., J. Appl. Physiol. 55: 1795-1802, 1983). Sufficient agreement with experimental data is obtained only when diffusion between serial-parallel compartments and sequential expiration are incorporated, the first being mainly responsible for separation of He and SF6, the latter for the slope of the alveolar plateau of these gases. A combined operational model comprising two parallel compartments connected to a mixing compartment, with both convective and diffusive gas transport between the compartments, could account for most of the experimental observations.

Animals↗
PubMed1989

Effects of temperature and composition on the viscosity of respiratory gases.

The steady-state sensitivity of resistance pneumotachographs is proportional to viscosity. Dynamic characteristics of pneumotachographs, pressure transducers, and mass spectrometers are also viscosity dependent. We derive linear equations to approximate the viscosities of O2, N2, CO2, H2O, He, N2O, and Ar for temperatures between 20 and 40 degrees C by using published viscosity data and a nonlinear extrapolation equation. We verify the accuracy of the extrapolation equation by comparison with published data. Our linear equations for pure gas viscosities yield standard errors less than 0.35 microP. We also compare a nonlinear equation for calculating the viscosities of mixtures of gases with published measured viscosities of dry air, humid air, and He-O2 and N2-CO2 mixtures. The maximum difference between published and calculated values is 1.3% for 10% CO2 in N2. All other differences are less than 0.38%. For saturated humid air at 35 degrees C, a linear concentration-weighted combination of viscosities differs from our nonlinear equation by 4.9, 2.1, and 1.7% at barometric pressures of 32, 83, and 100 kPa, respectively. By use of our method, the viscosity of normal respiratory gases can be calculated to within 1% of measured values.

Argon↗
PubMed1990

Effects of hydrostatic pressure and inert gases on platelet aggregation in vitro.

A novel cuvette was used to subject citrated platelet-rich plasma (PRP) to high hydrostatic pressure with negligible contamination by He (used for compression of the apparatus). Aggregation was induced at pressure by ADP and quantified turbidimetrically. The maximum degree of aggregation (MDA) was reduced from a control level of 82.2 to 53.6% by exposure to 101 ATA. Because decompression bubbles did not form, aggregation was also measured immediately after a compression cycle. After exposure to 101 ATA hydrostatic pressure, platelets responded normally to ADP at 1 ATA. In a matching apparatus, PRP was equilibrated with high partial pressures of inert gases. Normal physiological plasma Po2 and pH were maintained during equilibration. N2O (5 ATA) reduced the MDA from 86.5 (control) to 58.1%. N2 (51 ATA) reduced the MDA from 74.7 (control) to 51.6%, and 101 ATA Pn2 reduced the MDA from 78.0 (control) to 32.3%. He (100 ATA) reduced the MDA from 83.6 to 38.6%. It was concluded that platelet aggregation was relatively sensitive to hydrostatic pressure and less sensitive to inert gases than predicted from their anesthetic potency ratios.

Adenosine Diphosphate↗
PubMed1991

Airways impedance during single breaths of foreign gases.

The changes in airways resistance (Raw) and inertance (Iaw) during single inspirations of pure methane, helium, neon, and ethane at a flow of 0.1 l/s were measured in six healthy subjects by use of a forced-oscillation technique. Raw and Iaw were computed from respiratory transfer impedance obtained at a frequency of 20 Hz by applying pressure oscillations at the chest and measuring flow at the mouth with a bag-in-box system. Compared with the air data, the changes of Iaw after inhalation of 500 ml of gas averaged -41.1% with methane, -82.8% with helium, -25.8% with neon, and +4.8% with ethane. These changes were slightly less than the changes in gas density (-45%, -86%, -31%, and +5%, respectively). The inhaled volumes at which 50% of the changes had occurred (V50) did not differ significantly among gases and were approximately 100 ml. For Raw the data were more noisy than for Iaw; they were discarded in two subjects because of a strong and irreproducible volume dependence in air. Consistent differences were seen between the remaining subjects, one of whom exhibited a predominant viscosity dependence of Raw, one a predominant density dependence, and two an intermediate pattern. V50s were larger for Raw than for Iaw, indicating a more peripheral distribution of Raw. For Raw, V50s were lower with helium than with methane, in agreement with the notion that density-dependent resistance is located mainly in the large airways. The results suggest that some information on the serial distribution of Raw and Iaw may be derived from impedance measurements with foreign gases.

Adult↗
PubMed1993

Respiratory input impedance up to 256 Hz in healthy humans breathing foreign gases.

Currently available data concerning respiratory input impedance (Zrs) at frequencies up to 300 Hz indicate that Zrs is determined mainly by the airways and, in particular, the gas compressibility in the airways and the airway wall compliance. Hence, measurements of Zrs when breathing gases with different physical properties would be useful in investigating airway mechanics and the role of acoustic propagation. Zrs measured with a standard generator (Zst) and corrected for the upper airway shunt (Zrs*) were measured in nine healthy subjects breathing air or a gas mixture consisting of 20% O2 and 80% He or SF6. The frequency band was extended up to 256 Hz for air and He-O2 and up to 128 Hz for SF6-O2. Zrs exhibited a similar pattern for the three gases, with a shift toward low frequencies as the gas density increased. Moreover, the resonance peaks tended to be narrower and higher as the gas density increased. The second frequency of resonance for He-O2, air, and SF6-O2 were 220, 180, and 50 Hz, respectively, for Zrs* and were systematically higher for Zst. Zrs* and Zst data were interpreted in terms of a tricompartmental model that partitioned the airways into two segments: a central one featuring the acoustic propagation in the airways and a peripheral one that included bronchial wall elasticity (Farré et al. J. Appl. Physiol. 67: 1973-1981, 1989). The model was able to interpret the gas dependence of Zrs* but not that of Zst. The influence of the gas physical properties on both Zrs* and Zst confirms that total Zrs at high frequencies is basically that of the airways and that the second resonance is related mainly to the gas compressibility in the airways.

Adult↗