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At least 307 records · Page 17Linked to original sources
PubMed1999

Martian soil component in impact glasses in a Martian meteorite.

Chemical compositions of impact melt glass veins, called Lithology C (Lith C) in Martian meteorite EET79001 were determined by electron microprobe analysis. A large enrichment of S, and significant enrichments of Al, Ca, and Na were observed in Lith C glass compared to Lithology A (Lith A). The S enrichment is due to mixing of plagioclase- enriched Lith A material with Martian soil, either prior to or during impact on Mars. A mixture of 87% Lith A, 7% plagioclase, and 6% Martian soil reproduces the average elemental abundances observed in Lith C. Shock melting of such a mixture of plagioclase-enriched, fine-grained Lith A host rock and Martian soil could yield large excesses of S (observed in this study) and Martian atmospheric noble gases (found by Bogard et al., 1983) in Lith C. These mixing proportions can be used to constrain the elemental abundance of phosphorus in Martian soil.

Aluminum Oxide↗
PubMed1999

Irradiated interplanetary dust particles as a possible solution for the deuterium/hydrogen paradox of Earth's oceans.

Determining the source of Earth's oceans is a longstanding problem in planetary science. Possible sources of water include water ice or water of hydration of silicate minerals in the original material from which the bulk Earth accreted and water brought in by late-arriving planetesimals during the heavy bombardment period (4.5-3.8 Gyr ago) [Chyba, 1989, 1991]. Comets are an attractive source of water because their origin in the outer solar system is consistent with the long timescale for heavy bombardment. However, the high deuterium/hydrogen (D/H) ratio of the three comets that have been studied, Halley, Hyakutake, and Hale-Bopp, indicates that Earth must have had a source with a low-D/H ratio as well. Here we suggest that solar wind-implanted hydrogen on interplanetary dust particles (IDPs) provided the necessary low-D/H component of Earth's water inventory.

Cosmic Dust↗
PubMed1989

The case for planetary sample return missions. 2. History of Mars.

Principal science goals for exploration of Mars are to establish the chemical, isotopic, and physical state of Martian material, the nature of major surface-forming processes and their time scales, and the past and present biological potential of the planet. Many of those goals can only be met by detailed analyses of atmospheric gases and carefully selected samples of fresh rocks, weathered rocks, soils, sediments, and ices. The high-fidelity mineral separations, complex chemical treatments, and ultrasensitive instrument systems required for key measurements, as well as the need to adapt analytical strategies to unanticipated results, point to Earth-based laboratory analyses on returned Martian samples as the best means for meeting the stated objectives.

Chemical Phenomena↗
PubMed1992

Airburst origin of dark shadows on Venus.

A simple analytic model for the catastrophic disruption and deceleration of impactors in a thick atmosphere is used to (1) reproduce observed Venusian cratering statistics and (2) generate radar-dark disks by the impact of atmospheric shock waves with the surface. When used as input to Monte Carlo simulations of Venusian cratering, the model nicely reproduces the observed low diameter cutoff. Venusian craters are found to be more consistent with an asteroidal rather than a cometary source. The radar-dark "shadows" of the title are surface features, usually circular, that have been attributed to airbursting impactors. A typical craterless airburst is the equivalent of a approximately 10(6) megaton explosion. The airburst is treated as a massive, extended explosion using a thin-shell, isobaric cavity approximation. The strong atmospheric shock waves excited by the airbust are then coupled to surface rock using the usual impedance matching conditions. Peak shock pressures experienced by surface rock typically exceed 0.2 GPa for distances 15-30 km from ground zero (the place on the surface immediately beneath the site of the airburst), and 1 GPa for 10-20 km. These high shock pressures are felt to considerable depth, often more than a kilometer. Beneath the airburst the shock could reduce surface rocks to fine rubble, while at greater distance the weaker shock would leave fields of broken blocks, perhaps in part accounting for radar-bright halos that often surround the dark shadows.

Astronomy↗
PubMed1995

Influx of cometary volatiles to planetary moons: the atmospheres of 1000 possible Titans.

We use a Monte Carlo model to simulate impact histories of possible Titans, Callistos, and Ganymedes. Comets create or erode satellite atmospheres, depending on their mass and velocity distributions: faster and bigger comets remove atmophiles; slower or smaller comets supply them. Mass distributions and the minimum total mass of comets passing through the Saturn system were derived from the crater records of Rhea and Iapetus. These were then scaled to give a minimum impact history for Titan. From this cometary population, of 1000 initially airless Titans, 16% acquired atmospheres larger than Titan's present atmosphere (9 x 10(21) g), and more than half accumulated atmospheres larger than 10(21) g. In contrasts to the work of Zahnle et al. (1992), we find that, in most trials, Callisto acquires comet-based atmospheres. Atmospheres acquired by Callisto and, especially, Ganymede are sensitive to assumptions regarding energy partitioning into the ejecta plume. If we assume that only the normal velocity component heats the plume, the majority of Ganymedes and half of the Callistos accreted atmospheres smaller than 10(20) g. If all the impactor's velocity heats the plume, Callisto's most likely atmosphere is 10(17) g and Ganymede's is negligible. The true cometary flux was most likely larger than that derived from crater records, which raises the probability that Titan, Ganymede, and Callisto acquired substantial atmospheres. However, other loss processes (e.g., sputtering by ions swept up by the planetary magnetic field, solar UV photolysis of hydrocarbons) are potentially capable of eliminating small atmospheres over the age of the solar system. The dark material on Callisto's surface may be a remnant of an earlier, now vanished atmosphere.

Atmosphere↗
PubMed1997

Hydrothermal hydration of Martian crust: illustration via geochemical model calculations.

If hydrothermal Systems existed on Mars, hydration of crustal rocks may have had the potential to affect the water budget of the planet. We have conducted geochemical model calculations to investigate the relative roles of host rock composition, temperature, water-to-rock ratio, and initial fluid oxygen fugacity on the mineralogy of hydrothermal alteration assemblages, as well as the effectiveness of alteration to store water in the crust as hydrous minerals. In order to place calculations for Mars in perspective, models of hydrothermal alteration of three genetically related Icelandic volcanics (a basalt, andesite, and rhyolite) are presented, together with results for compositions based on SNC meteorite samples (Shergotty and Chassigny). Temperatures from 150 degrees C to 250 degrees C, water-to-rock ratios from 0.1 to 1000, and two initial fluid oxygen fugacities are considered in the models. Model results for water-to-rock ratios less than 10 are emphasized because they are likely to be more applicable to Mars. In accord with studies of low-grade alteration of terrestrial rocks, we find that the major controls on hydrous mineral production are host rock composition and temperature. Over the range of conditions considered, the alteration of Shergotty shows the greatest potential for storing water as hydrous minerals, and the alteration of Icelandic rhyolite has the lowest potential.

Evolution, Planetary↗
PubMed1997

Energy, volatile production, and climatic effects of the Chicxulub Cretaceous/Tertiary impact.

A comprehensive analysis of volatiles in the Chicxulub impact strongly supports the hypothesis that impact-generated sulfate aerosols caused over a decade of global cooling, acid rain, and disruption of ocean circulation, which contributed to the mass extinction at the Cretaceous/Tertiary (K/T) boundary. The crater size, meteoritic content of the K/T boundary clay, and impact models indicate that the Chicxulub crater was formed by a short period comet or an asteroid impact that released 0.7-3.4 x 10(31) ergs of energy. Impact models and experiments combined with estimates of volatiles in the projectile and target rocks predict that over 200 gigatons (Gt) each of SO2 and water vapor, and over 500 Gt of CO2, were globally distributed in the stratosphere by the impact. Additional volatiles may have been produced on a global or regional scale that formed sulfate aerosols rapidly in cooler parts of the vapor plume, causing an early, intense pulse of sulfuric acid rain. Estimates of the conversion rate of stratospheric SO2 and water vapor to sulfate aerosol, based on volcanic production of sulfate aerosols, coupled with calculations of diffusion, coagulation, and sedimentation, demonstrate that the 200 Gt stratospheric SO2 and water vapor reservoir would produce sulfate aerosols for 12 years. These sulfate aerosols caused a second pulse of acid rain that was global. Radiative transfer modeling of the aerosol clouds demonstrates (1) that if the initial rapid pulse of sulfate aerosols was global, photosynthesis may have been shut down for 6 months and (2) that for the second prolonged aerosol cloud, solar transmission dropped 80% by the end of first year and remained 50% below normal for 9 years. As a result, global average surface temperatures probably dropped between 5 degrees and 31 degrees K, suggesting that global near-freezing conditions may have been reached. Impact-generated CO2 caused less than 1 degree K greenhouse warming and therefore was insignificant compare to the sulfate cooling. The magnitude of sulfate cooling depends largely upon the rate of ocean mixing as surface waters cool, sink, and are replaced by upwelling of deep ocean water. This upwelling apparently drastically altered ocean stratification and circulation, which may explain the global collapse of the delta 13C gradient between surface and deep ocean waters at the K/T boundary.

Acid Rain↗
PubMed1998

Petrologic evidence for low-temperature, possibly flood evaporitic origin of carbonates in the ALH84001 meteorite.

High-temperature models for origin of the carbonates in Martian meteorite ALH84001 are implausible. The impact metasomatism model, invoking reaction between CO2 rich fluid and the host orthopyroxenite, requires conversion of olivine into orthopyroxene, yet olivine in ALH84001 shows no depletion in carbonate-rich areas; or else conversion of orthopyroxene into silica, which should have yielded a higher silica/carbonate ratio. The impact melt model implies that the fracture-linked carbonates, as products of melt injection, should appear as continuous planar veins, but in many areas they do not. Both vapor deposition and impact melting seem inconsistent with the zoned poikilotopic texture of many large carbonates. The popular hydrothermal model is inconsistent with the virtual absence of secondary hydrated silicates in ALH84001. Prior brecciation should have facilitated alteration. Hydrothermal fluids would be warm, and rate of hydration of mafic silicates obeys an Arrhenius law, at least up to approximately 100 degrees C. Most important, hydrothermal episodes tend to last for many years. Many areas of the ancient Martian crust show evidence for massive flooding. I propose that the carbonates formed as evaporite deposits from floodwaters that percolated through the fractures of ALH84001, but only briefly, as evaporation and groundwater flow caused the water table to quickly recede beneath the level of this rock during the later stages of the flood episode. The setting might have been a layer of megaregolith beneath a surface catchment of pooled floodwater, analogous to a playa lake. Carbonate precipitation would occur in response to evaporative concentration of the water. To explain the scarcity of sulfates in ALH84001, the water table must be assumed to recede quickly relative to the rate of evaporation. During the period when ALH84001 was above the water table, evaporation would have slowed, as the evaporation front passed beneath the surface of the debris layer, and possibly earlier, if the shrinking pool of surface water developed a porous sulfate crust. Alternatively, ALH84001 may have developed as a Martian form of calcrete, i.e., the evaporating flood(s) may have been entirely below ground as it (they) passed slowly through ALH84001. The greatest advantage of the flood evaporite model is that it exposes ALH84001 to carbonate precipitation without prolonged exposure to aqueous alteration. The model also seems consistent with the heavy and extremely heterogeneous oxygen isotopic compositions of the carbonates. However, this hypothesis seems no more than marginally consistent with the suggestion of McKay et al. [1996] that the carbonates are biogenic.

Carbon Dioxide↗
PubMed1998

On the thickness of the oxidized layer of the Martian regolith.

A revised model of the diffusion of H2O2 through the Martian regolith is presented, which argues that oxidant diffusion may be more efficient than previously thought. Recent models of the adsorption of H2O at Mars-like conditions indicate that it adsorbs more poorly than previously believed. H2O adsorption is a necessary proxy for peroxide adsorption; hence the adsorptive slowing of peroxide diffusion is modeled as less efficient. Because the peroxide has a finite lifetime, it has a finite extinction depth as well. The effects of regolith gardening by impacts are quantitatively estimated and combined with the effects of oxidation by atmospheric gases to produce estimates of the degree of oxidation of the Martian surface with depth. We explore the effects of different crater production populations along with variations in H2O2 extinction depths, and hydrothermal oxidation of ejecta. In very select circumstances involving very early onset of oxidizing conditions during heavy bombardment, 150-200 m of regolith could be fully oxidized. More likely scenarios for the crater production population, onset of oxidizing conditions, and oxidant extinction depth yield estimates of no more than a few meters to putative reducing material. In addition, uncertainties remain regarding the degree to which hydrothermal or other high-temperature chemistry might oxidize materials in ejecta blankets. The trade-off between accessing unlithified sediments or rock interiors must be considered.

Diffusion↗
PubMed1998

Introduction to special section: early Mars.

Ongoing studies of the evolution of the Martian cratered highlands, the nature of the planet's early climate, and the recent announcement of possible evidence of ancient life in the ALH 84001 meteorite have reinvigorated interest in the conditions that prevailed on Mars during its first billion years of geologic history. To address this interest and assess our current understanding of these issues, the Lunar and Planetary Institute hosted a 4-day Conference on Early Mars in Houston in April of 1997. The papers contained in this special section are a product of that meeting. The purpose of the conference was twofold: (1) to consider how impacts, volcanism, and the presence of abundant water affected the physical and chemical environment that existed on Mars 4 Gyr ago, particularly as it related to the nature of the global climate, the origin of the valley networks, the geologic and mineralogic evolution of the surface, the aqueous geochemistry of groundwater, and the existence of local environments that may have been conducive to the development of indigenous life and the preservation of its signature in the geologic record; and (2) to discuss what observations or experiments might he included in future spacecraft missions to test the ideas and expectations arising from purpose 1. While pertinent issues of early atmospheric and solar evolution were also addressed, the primary discussion at the conference focused on the evidence and constraints provided by the geologic records of Earth, the Moon, and Mars and analysis of the SNC meteorites. The papers contained in this special section span the full range of these topics, including the stability of the early atmosphere to erosion by the solar wind, the geologic environment from which the SNC meteorites originated, geomorphic evidence regarding the nature of the early Martian climate and hydrologic cycle, the potential impact of the past and present environment on the preserved signature of ancient life, and a discussion of the capabilities of a lander-based X ray diffraction and fluorescence instrument to assess the potential for past fossilization from the mineralogy of the current local surface environment. The issues raised at the conference, and by the papers included in this special section, will be the focus of ongoing attention as the intensity and scope of Mars exploration increases over the next decade.

Evolution, Planetary↗
PubMed1985

Temperatures within comet nuclei.

We have performed a theoretical study of temperatures beneath the surface of a comet's nucleus. We solve the one-dimensional heat conduction equation for the outer portion of the comet. The upper boundary condition of the model is given by energy balance at the surface of the nucleus, including conduction of heat inward, radiation, insolation as modified by the coma, and sublimation. Our coma model assumes single scattering and includes attenuation of direct sunlight by dust grains, scattering of light onto the nucleus, and infrared radiation by dust grains. The lower boundary condition is zero net heat flux around an orbit. The thermal conductivity expression for the nucleus includes direct conduction at grain boundaries, radiative conduction, and Knudsen flow vapor diffusion. The thermal diffusivity of the nucleus and the resultant temperature profiles are shown to be strongly dependent on the physical properties of the material, including porosity, pore size, and compaction. The temperature profiles and the equilibrium temperature deep within the comet also depend on the functional relationship between thermal conductivity and temperature; the highest deep equilibrium temperatures are found for models where the thermal conductivity increases strongly with increasing temperature. The dependence of temperatures on the albedo and thermal emissivity of the nucleus is also calculated, as well as the variation of temperature with latitude for a variety of pole orientations. The effect of a dust mantle on subsurface temperatures is also investigated. All calculations are presented for short-period comets with orbits that make them accessible for exploration by spacecraft rendezvous. In situ measurements of the thermal profile in the upper meter of a comet nucleus can substantially constrain the thermal diffusivity of the material, which in turn can provide significant information about the physical properties of the nucleus.

Cosmic Dust↗
PubMed1985

Fluid inclusions in stony meteorites--a cautionary note.

Newly discovered fluid inclusions in thin sections of Bjurbole chondrules, shergottite EETA79001, lunar meteorite ALHA81005, and Apollo 16 glasses possess physical properties similar to those fluid inclusions found in thin sections of five stony meteorites recently described by Warner et al. (1983). The distribution and physical properties of these new fluid inclusions indicate they may be artifacts of thin section preparation; we suggest that saw coolant was sucked into vacuum vesicles in glasses and minerals through submicroscopic fractures produced during sawing. The similarities between these fluid inclusions and fluid inclusions previously described by Warner et al. (1983) lead us to conclude that many of the fluid inclusions reported earlier may be artifacts. Consequently, the origin of any fluid inclusions observed in thin sections of extraterrestrial materials must be interpreted with caution. The most probable true extraterrestrial fluid inclusions are those that have been observed in grains prepared without exposure to liquids of any kind.

Extraterrestrial Environment↗
PubMed1999

Sublimation from icy jets as a probe of the interstellar volatile content of comets.

Comets are some of the most primitive bodies left over from the Solar System's early history. They may preserve both interstellar material and material from the proto-solar nebula, and so studies of their volatile components can provide clues about the evolution of gases and ices, as a collapsing molecular cloud transforms into a mature planetary system. Previous observations of emission from rotational transitions in molecules have averaged over large areas of the inner coma, and therefore include both molecules that sublimed from the nucleus and those that result from subsequent chemical processes in the coma Here we present high-resolution observations of emission from the molecules HNC, DCN and HDO associated with comet Hale-Bopp. Our data reveal arc-like structures-icy jets-offset from (but close to) the nucleus. The measured abundance ratios on 1-3" scales are substantially different from those on larger scales, and cannot be accounted for by models of chemical processes in the coma; they are, however, similar to the values observed in the cores of dense interstellar clouds and young stellar objects. We therefore propose that sublimation from millimetre-sized icy grains ejected from the nucleus provides access to relatively unaltered volatiles. The D/H ratios inferred from our data suggest that, by mass, Hale-Bopp (and by inference the outer regions of the early solar nebula) consists of > or =15-40% of largely unprocessed interstellar material.

Deuterium↗