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Sedimentology and geochemistry of a perennially ice-covered epishelf lake in Bunger Hills Oasis, East Antarctica.

A process-oriented study was carried out in White Smoke lake, Bunger Hills, East Antarctica, a perennially ice-covered (1.8 to 2.8 m thick) epishelf (tidally-forced) lake. The lake water has a low conductivity and is relatively well mixed. Sediments are transferred from the adjacent glacier to the lake when glacier ice surrounding the sediment is sublimated at the surface and replaced by accumulating ice from below. The lake bottom at the west end of the lake is mostly rocky with a scant sediment cover. The east end contains a thick sediment profile. Grain size and delta 13C increase with sediment depth, indicating a more proximal glacier in the past. Sedimentary 210Pb and 137Cs signals are exceptionally strong, probably a result of the focusing effect of the large glacial catchment area. The post-bomb and pre-bomb radiocarbon reservoirs are c. 725 14C yr and c. 1950 14C yr, respectively. Radiocarbon dating indicates that the east end of the lake is >3 ka BP, while photographic evidence and the absence of sediment cover indicate that the west end has formed only over the last century. Our results indicate that the southern ice edge of Bunger Hills has been relatively stable with only minor fluctuations (on the scale of hundreds of metres) over the last 3000 years.

Antarctic Regions↗

Dicarboxylic acids generated by thermal alteration of kerogen and humic acids.

Significant amounts (up to 2% of organic geopolymers) of low molecular weight (LMW) dicarboxylic acids (C2-C10) have been detected during thermal alteration (270 degrees C, 2 h) of kerogens and humic acids isolated from young or ancient lithified sediments. Their distribution is characterized by predominance of oxalic acid followed by succinic, fumaric and methylsuccinic acids. These acids are probably released by the breakdown of macromolecular structures, which have incorporated biogenic organic compounds, including diacids, during early diagenesis in sediments. Because of their reactivity, LMW diacids may play the following geochemically important roles under natural conditions: (1) the diacids dissolve carbonates and clay minerals to increase porosity and permeability, which enhances migration of oils and gas generated from catagenesis of kerogen dispersed in shale, and (2) the diacids may form organo-metal complexes, which are important for mobilization, transport and accumulation of trace metals in sedimentary basins.

Dicarboxylic Acids↗

Effects of sewage sludges contaminated with chlorinated aromatic hydrocarbons on sludge-treated areas (soils and sediments).

The fate of PCDDs, PCDFs, and PCBs in sewage sludges after different management techniques--such as agricultural application, land restoration, and marine disposal--was studied. Changes observed in the concentrations, in the ratio between PCDD and PCDF levels, and in the isomeric distribution suggest the influence of the sewage sludge on the sludge-treated areas (soils and sediments). Whereas land application techniques seem to produce no serious environmental consequences, marine disposal practices produce considerable increases in the levels of contamination in marine sediments.

Environmental Monitoring↗

Faecal bacteria yields in artificial flood events: quantifying in-stream stores.

Stream sediments have been recognised as an in-channel store of faecal contamination that can be mobilised during floods or other sediment-disturbing events. We studied this store of faecal contamination by creating artificial floods during dry weather when, in the absence of overland flow from the catchment, the only source of faecal bacteria was stores within the channel. Artificial floods, created by releasing water from a supply reservoir, increased the E. coli concentration in the water column by two orders of magnitude, from a background level of 10(2) cfu per 100 mL to over 10(4) cfu per 100 mL. The bacterial peak concentrations and yields declined systematically through a triplicate flood series. The size of the total in-channel store, calculated as the sum of yields of an infinite series of artificial floods, was approximately 10(8) cfu m(-2) of streambed area. Direct measurements of sediment E. coli found few sites (only those associated with cattle crossings) with areal concentrations as high as 10(8) cfu m(-2), consistent with flood yields. Concentrations of E. coli in the biofilms on exposed rocks were orders of magnitude lower, indicating that exposed rocks were not a source of E. coli released by the artificial floods.

Animals↗

Microbial diversity in ultra-high-pressure rocks and fluids from the Chinese Continental Scientific Drilling Project in China.

Microbial communities in ultra-high-pressure (UHP) rocks and drilling fluids from the Chinese Continental Scientific Drilling Project were characterized. The rocks had a porosity of 1 to 3.5% and a permeability of approximately 0.5 mDarcy. Abundant fluid and gas inclusions were present in the minerals. The rocks contained significant amounts of Fe2O3, FeO, P2O5, and nitrate (3 to 16 ppm). Acridine orange direct counting and phospholipid fatty acid analysis indicated that the total counts in the rocks and the fluids were 5.2 x 10(3) to 2.4 x 10(4) cells/g and 3.5 x 10(8) to 4.2 x 10(9) cells/g, respectively. Enrichment assays resulted in successful growth of thermophilic and alkaliphilic bacteria from the fluids, and some of these bacteria reduced Fe(III) to magnetite. 16S rRNA gene analyses indicated that the rocks were dominated by sequences similar to sequences of Proteobacteria and that most organisms were related to nitrate reducers from a saline, alkaline, cold habitat; however, some phylotypes were either members of a novel lineage or closely related to uncultured clones. The bacterial communities in the fluids were more diverse and included Proteobacteria, Bacteroidetes, gram-positive bacteria, Planctomycetes, and Candidatus taxa. The archaeal diversity was lower, and most sequences were not related to any known cultivated species. Some archaeal sequences were 90 to 95% similar to sequences recovered from ocean sediments or other subsurface environments. Some archaeal sequences from the drilling fluids were >93% similar to sequences of Sulfolobus solfataricus, and the thermophilic nature was consistent with the in situ temperature. We inferred that the microbes in the UHP rocks reside in fluid and gas inclusions, whereas those in the drilling fluids may be derived from subsurface fluids.

Atmospheric Pressure↗

2D numerical modelling of bed profile changes due to tsunami effects on near shore coasts: Kadikoy case study.

This study was aimed at the investigation of tsunami effects on the seabed profile as these may be important for coastal structures, like sea outfalls or breakwaters. Tsunamis are well known with huge wave heights and destructive effects on the coastal region. A 2D numerical model was set using the software, COSMOS to calculate the cross-shore sediment transport and to evaluate profile changes in the coastal seabed. The study area is Kadikoy region, a densely populated industrial coastal area in South East Istanbul. The model was run for different kinds of tsunami waves. Not only the bed profile changes, but also the wave heights, breaker depths, peak wave bottom orbital velocities, wave set-up and cross-shore sediment transport rates were determined. The results indicated that, at a water depth around 40-50 m, some tsunamis were found to have a wave height of order of 15 m, which became about 5 m at a depth of 10 m. The wave set up near the coast was about 1.5-2 m. The results also implied that tsunami waves, with their destructive nature, could lead to dramatic vertical changes of the seabed.

Disasters↗

A search for soot from global wildfires in central Pacific Cretaceous-Tertiary boundary and other extinction and impact horizon sediments.

Hypotheses of global wildfires following the Cretaceous-Tertiary (KT) boundary impact are supported by high concentrations of elemental carbon (3.6 mg cm(-2)) and soot (1.8 mg cm(-2)) in DSDP Site 465, which was located several thousand kilometers from potential continental sources at 65 Ma. Soot is not preserved at four other central Pacific KT localities, but this is attributed to loss during oxic diagenesis. We find no evidence for wildfires related to major impacts in the late Eocene or to Ir anomalies and extinctions in the late Cenomanian.

Carbon↗

Application of the Weibull extrapolation to 137Cs geochronology in Tokyo Bay and Ise Bay, Japan.

Considerable doubt surrounds the nature of processes by which 137Cs is deposited in marine sediments, leading to a situation where 137Cs geochronology cannot be always applied suitably. Based on extrapolation with Weibull distribution, the maximum concentration of 137Cs derived from asymptotic values for cumulative specific inventory was used to re-establish 137Cs geochronology, instead of original 137Cs profiles. Corresponding dating results for cores in Tokyo Bay and Ise Bay, Japan, by means of this new method, are in much closer agreement with those calculated from 210Pb method than the previous method.

Cesium Radioisotopes↗

Selenium status in soils in Yugoslavia.

In the last 8 years, a number of data on selenium (Se) content and distribution in the soil of Yugoslavia (Serbia and Montenegro) became available. The Se content of the soil in Yugoslavia varies in a broad range 39 to 440 microg/kg (mean value 230 microg/kg; n = 284). The soil clay fraction is rich in Se (range 146 to 586 microg/kg) in relation to sand and silt fractions. The available Se content (after extraction with ammonium acetate and EDTA) varies in the range of 1.2 to 28.2% of the total Se content. The speciation of Se is shown for the soils derived from volcanic rocks in Serbia. In addition, the influence of some soil properties on the Se content, as well as its content in the rocks, sediment, and wild plants in Yugoslavia, is discussed. The geographical distribution of Se in the soil of Yugoslavia shows that it is found in inadequate amounts in many agricultural regions. Its low content in soil has been thought to be associated with a higher incidence of some diseases. The Se content of the soil in Yugoslavia is not fully known. There is a great need to make a systematic geochemical mapping for Se and other trace elements in the soil.

Chemical Phenomena↗

Soils, water quality, and watershed size: interactions in the Maumee and Sandusky river basins of northwestern Ohio.

Soil variability in watersheds accounts for the problem of partitioning downstream water quality data and evaluating sources of non-point pollution. This review of previous water quality studies was conducted to examine more closely the influence of soil properties on pollutant export. The approach used in this paper was to start with data from the two largest watersheds (Maumee and Sandusky) and then compare them on a unit area export basis with data from intermediate-size and smaller watersheds. General relationships between pollutant levels at the river mouth and upstream soil conditions are vague and seemingly contradictory at the large-watershed scale. With smaller watersheds, it can be determined that soil texture, slope, and internal drainage are controlling factors for pollutant export. Although Paulding (very-fine, illitic, nonacid, mesic Typic Epiaquept) and Roselms (very-fine, illitic, mesic Aeric Epiaqualf) soils occupy only 5% of the Maumee basin, they generate more than 10 times as much sediment per unit area as the tile-drained Hoytville (fine, illitic, mesic Mollic Epiaqualf) soils that occupy 16% of the Maumee basin. Tile drainage of very poorly drained soils that are formed from either glacial till or silty to sandy lake deposits reduces runoff and increases downward movement of soluble nutrients into tile drains. The assumption that sloping moraine areas are the primary source of pollutants should be reexamined based on this review.

Environmental Monitoring↗

Part I: Integrated water quality management: river basin approach. Geochemical techniques on contaminated sediments--river basin view.

The big flood in the upper Elbe River catchment area has revealed a wide spectrum of problems with contaminated sediments. So far, an effective strategy for managing contaminated sediments on a river basin scale is still missing and it seems that not much has been learned from the lessons received during the last decade. In the following overview, special emphasis is given to the utilization of geochemically-based techniques for sediment remediation, which can be applied in different parts of a river basin. The examples presented here are mostly from the Elbe River catchment area. In general, new technical problem solutions need a set of practical process knowledge that uses a wide range of simulation techniques, as well as models in different spatial and temporal scales. The evaluation of recent flood events clearly demonstrates the importance of chemical expertise in the decision-making process for the sustainable development in river basins.

Decision Making↗

Spatial patterns of natural polycyclic aromatic hydrocarbons in sediment in the lower Athabasca River.

The Athabasca Oil Sands is one of the four natural oil sands deposits in Northern Alberta, Canada, and are by far the largest oil sand deposit in North America, covering an area of 46,000 km2. Sediment samples were collected from the bed and bank of several tributaries that have naturally occurring exposures of oil sand material. Oil sand deposited along the lower Athabasca River, more than 100 km downstream of naturally occurring oil sand exposures, were also sampled. The levels of alkylated polycyclic aromatic hydrocarbons (PAHs) in samples collected from these various locations ranged from not detected to almost 50 ppm. Using dibenzothiophene/chrysene (C2/D2 vs. C3/D3) double ratio plots, it is possible to approximate the relative degree of degradation or weathering of the PAHs from these various sediment deposits along the lower Athabasca River and its tributaries. Similarly a plot of dibenzothiophene/phenanthrene (D2/P2 vs. D3/P3) indicate the possible origins of the oil. A combination of these plots, D3/P3 vs. D3/C3, was particularly useful in identifying weathering characteristics of different sources of the oil. Comparison of alkylated PAH distributions between the lower Athabasca River and the tributaries show slight differences consistent with different petrogenic sources and/or different weathering patterns.

Alberta↗

A conceptual review of regional-scale controls on the composition of clastic sediment and the co-evolution of continental blocks and their sedimentary cover.

Both sediment recycling and first-cycle input influence the composition of clastic material in sedimentary systems. This paper examines conceptually the roles played by these processes in governing the composition of clastic sediment on a regional scale by outlining the expected effects on sediment composition of protracted sediment recycling and of continuous first-cycle input on a maturing continental block. Generally speaking, long-term recycling tends to enrich sediments in the most chemically and mechanically stable components: quartz in the sand and silt size fractions, and illite among the clay minerals. Sandstones trend towards pure quartz arenites, and mudrocks become more potassic and aluminous. The average grain size of clastic sediment decreases by a combination of progressive attrition of sand grains and ongoing breakdown of primary silicate minerals to finer-grained clay minerals and oxides. Sandstones derived by continuous first-cycle input from an evolving continental crustal source also become increasingly rich in quartz, but in addition become more feldspathic as the proportion of granitic material in the upper continental crust increases during crustal stabilization. Associated mudrocks also become richer in potassium and aluminum, but will have higher K2O/Al2O3 ratios than recycled muds. The average grain size of the sediment may increase with time as the proportion of sand-prone granitic source rocks increases at the expense of more mud-prone volcanic sources. In general, except in instances where chemical weathering is extreme, first-cycle sediments lack the compositional maturity of recycled detritus, and are characterized by the presence of a variety of primary silicate minerals. Sedimentary systems are not usually completely dominated by either recycling or first-cycle detritus. Generally, however, sedimentary systems associated with the earliest phases of formation and accretion of continental crust are characterized by first-cycle input from igneous and metamorphic rocks, whereas those associated with more mature cratons tend to be dominated by recycled sedimentary material.

Aluminum Oxide↗

Hydrological investigations of forest disturbance and land cover impacts in South-East Asia: a review.

Investigations of land management impacts on hydrology are well developed in South-East Asia, having been greatly extended by national organizations in the last two decades. Regional collaborative efforts, such as the ASEAN-US watershed programme, have helped develop skills and long-running monitoring programmes. Work in different countries is significant for particular aspects: the powerful effects of both cyclones and landsliding in Taiwan, the significance of lahars in Java, of small-scale agriculture in Thailand and plantation establishment in Malaysia. Different aid programmes have contributed specialist knowledge such as British work on reservoir sedimentation, Dutch, Swedish and British work on softwood plantations and US work in hill-tribe agriculture. Much has been achieved through individual university research projects, including PhD and MSc theses. The net result is that for most countries there is now good information on changes in the rainfall-run-off relationship due to forest disturbance or conversion, some information on the impacts on sediment delivery and erosion of hillslopes, but relatively little about the dynamics and magnitude of nutrient losses. Improvements have been made in the ability to model the consequences of forest conversion and of selective logging and exciting prospects exist for the development of better predictions of transfer of water from the hillslopes to the stream channels using techniques such as multilevel modelling. Understanding of the processes involved has advanced through the detailed monitoring made possible at permanent field stations such as that at Danum Valley, Sabah.

Asia, Southeastern↗

Accretionary history of the Archean Barberton Greenstone Belt (3.55-3.22 Ga), southern Africa.

The 3.55-3.22 Ga Barberton Greenstone Belt, South Africa and Swaziland, and surrounding coeval plutons can be divided into four tectono-stratigraphic blocks that become younger toward the northwest. Each block formed through early mafic to ultramafic volcanism (Onverwacht Group), probably in oceanic extensional, island, or plateau settings. Volcanism was followed by magmatic quiescence and deposition of fine-grained sediments, possibly in an intraplate setting. Late evolution involved underplating of the mafic crust by tonalitic intrusions along a subduction-related magmatic arc, yielding a thickened, buoyant protocontinental block. The growth of larger continental domains occurred both through magmatic accretion, as new protocontinental blocks developed along the margins of older blocks, and when previously separate blocks were amalgamated through tectonic accretion. Evolution of the Barberton Belt may reflect an Early Archean plate tectonic cycle that characterized a world with few or no large, stabilized blocks of sialic crust.

Earth, Planet↗

The relationship of lithology and watershed characteristics to fine sediment deposition in streams of the Oregon coast range.

Lithology is one of many factors influencing the amount, grain size distribution, and location of fine sediment deposition on the bed of mountain stream channels. In the Oregon Coast Range, 18 pool-riffle stream reaches with similar slope and intact riparian area and relatively unaffected by logjams were surveyed for assessment of fine sediment deposition. Half of the streams were in watersheds underlain by relatively erodible sandstone. The other half were underlain by a more resistant basalt. Channel morphology, hydraulic variables, particle size, relative pool volume of fine sediment (V*), and wood characteristics were measured in the streams. A significantly higher amount of fine sediment was deposited in the sandstone channels than in the basalt channels, as indicated by V*. Grab samples of sediment from pools also were significantly finer grained in the sandstone channels. Geographic information systems (GIS) software was used to derive several variables that might correlate with fine sediment deposition. These variables were combined with those derived from field data to create multiple linear regression models to be used for further exploration of the type and relative influence of factors affecting fine sediment deposition. Lithology appeared to be significant in some of these models, but usually was not the primary driver. The results from these models indicate that V* at the reach scale is best explained by stream power per unit area and by the volume of wood perpendicular to the flow per channel area (R(2) = 0.46). Findings show that V* is best explained using only watershed scale variables, including negative correlations with relief ratio and basin precipitation index, and positive correlations with maximum slope and circularity.

Chemical Precipitation↗

Paleolimnology of the McMurdo Dry Valleys, Antarctica.

The McMurdo Dry Valleys presently contain more than 20 permanent lakes and ponds, which vary markedly in character. All, with the exception of a hypersaline pond, have a perennial ice-cover. The dry valley lakes, and lakes in other ice-free regions of continental Antarctica, are unique on this planet in that they consistently maintain a thick year-round ice cover (2.8-6.0 m) over liquid water. The persistent ice covers minimize wind-generated currents and reduce light penetration, as well as restricting sediment deposition into a lake and the exchange of atmospheric gases between the water column and the atmosphere. From a paleolimnological perspective, the dry valley lakes offer an important record of catchment and environmental changes. These lakes are also modern-day equivalents of periglacial lakes that were common during glacial periods at temperate latitudes. The present lakes are mostly remnants of larger glacial lakes that occupied the valleys in the past, perhaps up to 4.6 Ma ago. Two of the valleys contain evidence of being filled with large glacial lakes within the last 10000 years. Repeated drying and filling events since then have left a characteristic impression on the salt profiles of some lakes creating a unique paleo-indicator within the water column. These events are also marked in the sediments by the concentration and dilution of certain chemical constituents, particularly salts, and are also corroborated by carbonate speciation and oxygen isotope analysis. Stratigraphic analysis of dry valley lake sediments is made difficult by the occurrence of an 'old carbon' reservoir creating spurious radiocarbon dates, and by the high degree of spatial variability in lake sedimentation. From a biological perspective, the lakes are relatively simple, containing various taxa of planktonic and benthic microorganisms, but no higher forms of life, which is an advantage to paleolimnologists because there is no bioturbation in the sediments. Useful biological paleo-indicators found in the sediments include cyanobacterial filament sheaths, diatom frustules and other eukaryotic algal cells, protozoan cysts, photosynthetic pigments, and minerals (e.g. carbonates) associated with microbial activity. Future work will benefit from fully characterizing the connection between the ice covers, environmental conditions, and paleo-indicators, thereby allowing refinement of inferences made concerning the paleoenvironment. New dating techniques need to be tested in this environment to overcome the problems associated with radiocarbon dating. The establishment of a detailed and focused paleolimnological campaign is proposed.

Antarctic Regions↗

Comparing methods and sediment contaminant indicators for determining produced water fate in a Louisiana estuary.

Produced water is a high salinity by-product resulting from oil and gas production. Disposal methods include surface water discharge. The current field method used to determine its fate in estuarine systems involves extending a compass oriented transect (COT) from the point source discharge--a method designed for a uniformly dispersing effluent discharged into a uniform offshore environment that may be inappropriate for the hydrologic and geomorphologic complexities found in estuarine systems. Prior research established the viability of the salinity stratification transect (SST) method. Both COT and SST methods were used in a small open bay to determine which more accurately detected effluent dispersion. Determination was based on sediment contaminant indicators (SCIs), including interstitial salinity, hydrocarbons, metals, and radium concentrations. Additionally, SCIs were evaluated for their ability to serve as indicators of effluent dispersion. The data revealed that SST stations exhibited higher contaminant concentrations and that this approach was more accurate in tracking the produced water plume. The data also suggested that SCIs varied in their ability to serve as indicators. Good indicators included interstitial salinity, total targeted aromatic hydrocarbons substantiated with a modified fossil fuel pollution index value, certain metals, and radium-228.

Environmental Monitoring↗