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A mysterious dust clump in a disk around an evolved binary star system.

The discovery of planets in orbit around the pulsar PSR1257+12 shows that planets may form around post-main-sequence stars. Other evolved stars, such as HD44179 (an evolved star which is part of the binary system that has expelled the gas and dust that make the Red Rectangle nebula), possess gravitationally bound orbiting dust disks. It is possible that planets might form from gravitational collapse in such disks. Here we report high-angular-resolution observations at millimetre and submillimetre wavelengths of the dusk disk associated with the Red Rectangle. We find a dust clump with an estimated mass near that of Jupiter in the outer region of the disk. The clump is larger than our Solar System, and far beyond where planet formation would normally be expected, so its nature is at present unclear.

Astronomical Phenomena↗

Unaltered cosmic spherules in a 1.4-Gyr-old sandstone from Finland.

Micrometeorites-submillimetre-sized particles derived from asteroids and comets-occur in significant quantities in deep sea sediments, and the ice sheets of Greenland and Antarctica. The most abundant micrometeorites are cosmic spherules, which contain nickel-rich spinels that were crystallized and oxidized during atmospheric entry, therefore recording the oxygen content in the uppermost atmosphere. But the use of micrometeorites for detecting past changes in the flux of incoming extraterrestrial matter, and as probes of the evolution of the atmosphere, has been hampered by the fact that most objects with depositional ages higher than 0.5 Myr show severe chemical alteration. Here we report the discovery of unaltered cosmic spherules in a 1.4-Gyr-old sandstone (red bed) from Finland. From this we infer that red beds, a common lithology in the Earth's history, may contain substantial unbiased populations of fossil micrometeorites. The study of such populations would allow systematic research on variations in the micrometeorite flux from the early Proterozoic era to recent times (a time span of about 2.5 Gyr), and could help to better constrain the time when the atmospheric oxygen content was raised to its present level.

Earth, Planet↗

Abiotic nitrogen reduction on the early Earth.

The production of organic precursors to life depends critically on the form of the reactants. In particular, an environment dominated by N2 is far less efficient in synthesizing nitrogen-bearing organics than a reducing environment rich in ammonia. Relatively reducing lithospheric conditions on the early Earth have been presumed to favour the generation of an ammonia-rich atmosphere, but this hypothesis has not been studied experimentally. Here we demonstrate mineral-catalysed reduction of N2, NO2- and NO3- to ammonia at temperatures between 300 and 800 degrees C and pressures of 0.1-0.4 GPa-conditions typical of crustal and oceanic hydrothermal systems. We also show that only N2 is stable above 800 degrees C, thus precluding significant atmospheric ammonia formation during hot accretion. We conclude that mineral-catalysed N2 reduction might have provided a significant source of ammonia to the Hadean ocean. These results also suggest that, whereas nitrogen in the Earth's early atmosphere was present predominantly as N2, exchange with oceanic, hydrothermally derived ammonia could have provided a significant amount of the atmospheric ammonia necessary to resolve the early-faint-Sun paradox.

Ammonia↗

D to H ratio and the origin and evolution of Titan's atmosphere.

A value of 1.7 x 10(-3) has been reported for the ratio of CH3D to CH4 in the stratosphere of the saturnian moon Titan. A lower value of 6 x 10(-4) for this ratio in the deeper part of Titan's atmosphere was reported by de Bergh et al. For comparison we note that the CH3D to CH4 ratio on Saturn and Jupiter is 8.7 x 10(-5) and 6.7 x 10(-5), respectively. We estimate the uncertainties in all these observations and data reduction to be about a factor of 2. Despite these uncertainties it appears that Titan's atmosphere is enriched in deuterium by a factor of > or = 3 relative to Jupiter and Saturn. Potential causative factors examined here for this enrichment are condensation to form tropospheric methane clouds, fractionation occurring over a hypothetical CH4-C2H6 ocean and between the ocean and the clathrate crust beneath, fractionation which occurred during the formation of Titan and fractionation occurring as a result of the evolution of Titan's atmosphere. We conclude that the greater part of the observed fractionation is probably derived from the formation of Titan and the subsequent evolution of Titan's atmosphere driven by photochemistry.

Deuterium↗

Evolution of the atmosphere and oceans.

The residence times of most constituents of the atmosphere and oceans are small fractions of the age of the Earth and, in general, their rate of output has been nearly equal to their rate of input. We are disturbing a number of these dynamic equilibria quite severely. The mineralogy of marine evaporites rules out drastic changes in the composition of sea water during the last 900 Myr. The chemistry of soils formed more than 1,000 Myr ago suggests that the atmosphere then contained significantly more CO2 and less O2 than at present. Hydrogen peroxide may well have been the principal oxidant and formaldehyde the main reductant in rain water between 3,000 and 1,000 Myr ago. Major changes in atmospheric chemistry since that time are almost certainly related to the evolution of the biosphere.

Atmosphere↗

Lunar nodal tide and distance to the Moon during the Precambrian.

The pace of tidal evolution for the past approximately 450 Myr implies an Earth/Moon collision some 1,500-2,000 Myr BP, an event for which there is no corroborating evidence. Here we present the first direct determination of the lunar distance in the Precambrian. We interpret a 23.3 +/- 0.3-yr periodicity preserved in a 2,500 Myr BP Australian banded iron formation (BIF) as reflecting the climatic influence of the lunar nodal tide, which has been detected with its modern 18.6-yr periodicity in some modern climate records. The lunar distance at 2,500 Myr BP would then have been about 52 Earth radii. The implied history of Precambrian tidal friction is in accord with both the more recent palaeontological evidence and the long-term stability of the lunar orbit. The length of the Milankovitch cycles that modulate the ice ages today also evolve with the Earth-Moon system. Their detection in the Precambrian sedimentary record would then permit an independent determination of the lunar distance.

Climate↗

Secular variation in carbon isotope ratios from Upper Proterozoic successions of Svalbard and East Greenland.

Analyses of stratigraphically continuous suites of samples from Upper Proterozoic sedimentary successions of East Greenland, Spitsbergen and Nordaustlandet (Svalbard) provide an approximation to the secular variation in carbon isotope ratios during a geologically and biologically important period of change from around 900 million years ago to the beginning of the Cambrian period. Late Riphean carbonates and organic material show a stratigraphically useful pattern of enrichment in 13C relative to Phanerozoic or earlier Proterozoic samples. Isotopic compositions of isolated samples from other localities are consistent with a worldwide extended interval of enhanced organic burial and consequent net survival of oxidized material, probably O2, just before the initial radiation of metazoans.

Animals↗

Was the Archaean biosphere upside down?

Photosynthesis produces reduced organic carbon and an oxidized partner in equivalent molar amounts. These compounds can react with one another, again in equivalent molar amounts, so that no net change occurs in the overall level of oxidation of the biosphere (here taken to mean the biota together with the part of the Earth with which living things interact). But, the reduced and oxidized partners have different susceptibilities to transport by environmental processes and so, typically, they become separated. Conservation of matter implies that for every mole of excess oxidant in an oxidizing region of the biosphere there must be a mole of excess reductant in a reducing region. Today, the oxidized partner in photosynthesis is usually free oxygen, which floats upward to accumulate in excess in the atmosphere, whereas organic matter settles downward to collect in sediments and stagnant pools. On the anoxic Archean Earth, the oxidized partner was probably iron. As oxidized iron is markedly less soluble and mobile than organic carbon, differential transport in the Archaean biosphere would have had an effect just the opposite of that in the modern biosphere. The oxidized partner would have settled downward more rapidly than the reduced partner, resulting in the accumulation of excess oxidant in sediments and stagnant pools. An equivalent excess of the more volatile reduced compounds would have been left behind in ocean and atmosphere in the form of dissolved organic carbon and gaseous hydrocarbons. On average, therefore, the Archean biosphere may have been oxidizing at the bottom and reducing on top.

Aerobiosis↗

Impact frustration of the origin of life.

One possible definition for the origin of life on Earth is the time at which the interval between devastating environmental insults by impact exceeded the timescale for establishing self-replicating proto-organisms. A quantitative relationship for the Hadean (pre-3,800 Myr ago) and Early Archean (3,800 to 3,400 Myr) impact flux can be derived from the lunar and terrestrial impact records. Also, the effects of impact-related processes on the various environments proposed for abiogenesis (the development of life through chemical evolution from inorganic materials) can be estimated. Using a range of plausible values for the timescale for abiogenesis, the interval in time when life might first have bootstrapped itself into existence can be found for each environment. We find that if the deep marine hydrothermal setting provided a suitable site, abiogenesis could have happened as early as 4,000 to 4,200 Myr ago, whereas at the surface of the Earth abiogenesis could have occurred between 3,700 and 4,000 Myr.

Earth, Planet↗

High-temperature shock formation of N2 and organics on primordial Titan.

Titan's atmosphere is composed primarily of N2 with a little methane and other organic molecules. But theoretical models suggest that the initial form of nitrogen in Titan's atmosphere may have been NH3. We have investigated the possible importance of strong shocks produced during high-velocity impacts accompanying the late states of accretion as a method for converting NH3 to N2. To simulate the effects of an impact in Titan's atmosphere we have used the focused beam of a high-power laser, a method that has been shown to simulate shock phenomena. For mixtures of 10%, 50% and 90% NH3 (balance CH4) we obtained yields of 0.25, 1, and 6 x 10(17) molecules of N2 per joule, respectively. We also find that the yield of HCN is comparable to that for N2. In addition, several other hydrocarbons are produced, many with yields in excess of theoretical high-temperature-equilibrium models. The above yields, when combined with models of the satellite's accretion, result in a total N2 production comparable to that present in Titan's atmosphere and putative ocean.

Ammonia↗

Formation of molecular gas in the tidal debris of violent galaxy-galaxy interactions.

In many gravitational interactions between galaxies, gas and stars that have been torn from the precursor galaxies can collect in tidal 'tails'. Star formation begins anew in some of these regions, producing tidal dwarf galaxies. Observations of these new galaxies provides insight into processes relevant to galaxy formation more generally, because the timescale of the interaction is well defined. But tracking the star formation process has hitherto been difficult because the tidal dwarf galaxies with young stars showed no evidence of the molecular gas out of which those young stars formed. Here we report the discovery of molecular hydrogen (traced by carbon monoxide emission) in two tidal dwarf galaxies. In both cases, the concentration of molecular gas peaks at the same location as the maximum in atomic-hydrogen density, unlike the situation in most gas-rich galaxies. We infer from this that the molecular gas formed from the atomic hydrogen, rather than being torn in molecular form from the interacting galaxies. Star formation in the tidal dwarf galaxies therefore appears to mimic the process in normal spiral galaxies like our own.

Astronomical Phenomena↗

North-south geological differences between the residual polar caps on Mars.

Polar processes can be sensitive indicators of global climate, and the geological features associated with polar ice caps can therefore indicate evolution of climate with time. The polar regions on Mars have distinctive morphologic and climatologic features: thick layered deposits, seasonal CO2 frost caps extending to mid latitudes, and near-polar residual frost deposits that survive the summer. The relationship of the seasonal and residual frost caps to the layered deposits has been poorly constrained, mainly by the limited spatial resolution of the available data. In particular, it has not been known if the residual caps represent simple thin frost cover or substantial geologic features. Here we show that the residual cap on the south pole is a distinct geologic unit with striking collapse and erosional topography; this is very different from the residual cap on the north pole, which grades into the underlying layered materials. These findings indicate that the differences between the caps are substantial (rather than reflecting short-lived differences in frost cover), and so support the idea of long-term asymmetry in the polar climates of Mars.

Carbon Dioxide↗

Anomalous 17O compositions in massive sulphate deposits on the Earth

The variation of delta 18O that results from nearly all physical, biological and chemical processes on the Earth is approximately twice as large as the variation of delta 17O. This so-called 'mass-dependent' fractionation is well documented in terrestrial minerals. Evidence for 'mass-independent' fractionation (delta 17O = delta 17O-0.52 delta 18O), where deviation from this tight relationship occurs, has so far been found only in meteoritic material and a few terrestrial atmospheric substances. In the rock record it is thought that oxygen isotopes have followed a mass-dependent relationship for at least the past 3.7 billion years, and no exception to this has been encountered for terrestrial solids. Here, however, we report oxygen-isotope values of two massive sulphate mineral deposits, which formed in surface environments on the Earth but show large isotopic anomalies (delta 17O up to 4.6%). These massive sulphate deposits are gypcretes from the central Namib Desert and the sulphate-bearing Miocene volcanic ash-beds in North America. The source of this isotope anomaly might be related to sulphur oxidation reactions in the atmosphere and therefore enable tracing of such oxidation. These findings also support the possibility of a chemical origin of variable isotope anomalies on other planets, such as Mars.

Africa↗

Determining the ages of comets from the fraction of crystalline dust.

The timescale for the accretion of bodies in the disk surrounding a young star depends upon a number of assumptions, but there are few observational constraints. In our own Solar System, measurements of meteoritic components can provide information about the inner regions of the nebula, but not the outer parts. Observations of the evolution of more massive protostellar systems (Herbig Ae/Be stars) imply that significant changes occur in the physical properties of their dust with time. The simplest explanation is that thermal annealing of the original, amorphous grains in the hot inner nebula slowly increases the fractional abundance of crystalline material over time. Crystalline dust is then transported outward, where it is incorporated into comets that serve as a long-term reservoir for dust disks, such as that surrounding Beta Pictoris. Here we show that when applied to our own Solar System, this process can explain observed variations in both the volatile and dusty components of comets, while also providing a natural indicator of a comet's mean formation age. Studies of comets with different dust contents can therefore be used to investigate the timescales of the early Solar System.

Carbon Monoxide↗