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PubMed · 9227669

Antidepressants.

A Frazer
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Antidepressive AgentsAntidepressive Agents, Second-GenerationAntidepressive Agents, TricyclicCyclohexanolsDepressive DisorderHumansMianserinMirtazapineMonoamine Oxidase InhibitorsPiperazinesSelective Serotonin Reuptake InhibitorsTriazolesVenlafaxine HydrochlorideJournal ArticleResearch Support, U.S. Gov't, Non-P.H.S.Research Support, U.S. Gov't, P.H.S.Review

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A Frazer. 1997. Antidepressants.. https://pubmed.ncbi.nlm.nih.gov/9227669/

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A new synthesis of indole 5-carboxylic acids and 6-hydroxy-indole-5-carboxylic acids in the preparation of an o-hydroxylated metabolite of vilazodone.

A major metabolite of the potential antidepressant vilazodone formed in rat, dog, monkey and human liver microsomes is the 5-cyano-6-hydroxy-1H-indole derivative. For the construction of the salicyl-like substituted indole we adapted a synthesis of carmoxirole using Japp-Klingemann type Fischer-indole synthesis protocols. Functional group interconversion of carboxylic acid via carboxamide into cyanide was performed with methanesulfonic acid chloride.

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