PubMed · 5192305
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Fairall, Lee. 1969. Toothbrushes and toothpaste.. https://pubmed.ncbi.nlm.nih.gov/5192305/
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The method is based upon the reaction between fluoride ions and the coloured complex of Fe(III) with methyl salicylate to form the stable, colourless hexaflouride complex of iron. The conditions of the method (pH, time and combination ratio) were studied and a standard curve was obtained for 0.01-0.08 mg NaF ml-1, at 525 nm. A study was conducted on interference with complexing anions of Fe(III), cations that react with fluoride ions and with common ingredients of dosage forms and dental preparations. The method was validated and the results showed good precision (100.16 +/- = 2.33%) comparable with that of other analytical methods. Good results were obtained in the spectrophotometric determination of fluoride ions in a stomatological gel and in a toothpaste.
The fluorescence of tin(IV) complexed by 8-hydroxyquinoline-5-sulfonic acid (8-HQSA) has been studied in both aqueous and hydroorganic (acetate buffer and dimethylsulfoxide) media. Several experimental parameters such as pH, DMSO/water ratio and reactant concentration have been investigated to increase the fluorescence of the tin(IV)-8-HQSA complex. A linear relationship between tin(IV) concentration and fluorescence intensity was observed between 1.7 and 20 microM). Mechanistic and quantitative studies in the presence of surfactants have been performed. Judiciously selected micellar media permitted solubilisation and quantitation of tin(IV) as well as dibutyltin compounds. A linear relationship between concentration and fluorescence intensity was found for mono-, di- and tributyltin with detection limits of 0.1 microM, 0.7 microM and 1 microM, respectively.
An increased public awareness in dental aesthetics has resulted in the wide availability of techniques of tooth bleaching, both in the dental chair and at home. This article reviews the aetiology of tooth discolouration both at the clinical and the molecular level, together with methods of alleviating such discolouration. Much of the therapeutic and aesthetic actions of commercially-available tooth whiteners, gels, oral rinses and other dentifrices are predominantly dependent on their ability to act as oxidants. A novel method of evaluating these aspects of dentifrice activity is also described: high resolution proton nuclear magnetic resonance (NMR) spectroscopy is a virtually non-invasive, multi component bioanalytical technique that can be employed to study oxidation/reduction reactions at the molecular level and is utilised here to investigate the mechanisms of action of a newly developed dentifrice (Ultrawhite Opal, Janina International). Such methodology also offers much potential for studies concerning the numerous chemical reactions occurring within the oral environment.