PubMed · 14815824
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1951. CONTINUOUSLY sensitive diffusion cloud chambers.. https://pubmed.ncbi.nlm.nih.gov/14815824/
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The aim of the current study is to predict the release kinetics of organic molecules entrapped in sol-gel-made silica particles using both pulsed field gradient-nuclear magnetic resonance (PFG-NMR) techniques and model calculations to describe restricted diffusion. The macroscopic release profile of aroma molecules from sol-gel-made particles is measured directly by UV-VIS spectroscopy, while the release kinetics are calculated by the Crank equation. The microscopic restricted pore diffusion coefficient of the aroma molecules in the Crank equation is obtained in situ by pulsed field gradient (PFG) magic angle spinning (MAS) nuclear magnetic resonance (NMR). Furthermore, restricted pore diffusion coefficients obtained by model calculations are in agreement with those measured by PFG-MAS-NMR, indicating the potential of the latter for characterization and screening of encapsulation formulations. Measured and calculated release profiles agree within experimental error.
Micropatterned composite membranes of polymerized and fluid lipid bilayers were constructed on solid substrates. Lithographic photopolymerization of a diacetylene-containing phospholipid, 1,2-bis(10,12-tricosadiynoyl)-sn-glycero-3-phosphocholine (DiynePC), and subsequent removal of nonreacted monomers by a detergent solution (0.1 M sodium dodecyl sulfate (SDS)) yielded a patterned polymeric bilayer matrix on the substrate. Fluid lipid bilayers of phosphatidylcholine from egg yolk (egg-PC) were incorporated into the lipid-free wells surrounded by the polymeric bilayers through the process of fusion and reorganization of suspended small unilamellar vesicles. Spatial distribution of the fluid bilayers in the patterned bilayer depended on the degree of photopolymerization that in turn could be modulated by varying the applied UV irradiation dose. The polymeric bilayer domains blocked lateral diffusion of the fluid lipid bilayers and confined them in the defined areas (corrals), if the polymerization was conducted with a sufficiently large UV dose. On the other hand, lipid molecules of the fluid bilayers penetrated into the polymeric bilayer domains, if the UV dose was relatively small. A direct correlation was observed between the applied UV dose and the lateral diffusion coefficient of fluorescent marker molecules in the fluid bilayers embedded within the polymeric bilayer domains. Artificial control of lateral diffusion by polymeric bilayers may lead to the creation of complex and versatile biomimetic model membrane arrays.
In the following we will discuss a specific problem of explosion protection in dryers for coatings. It is mainly encountered in chamber dryers as these pose specific problems as regards occupational safety and health. During the drying process of most coatings, solvent vapours are released most of which can form explosive mixtures when a specific concentration, the lower explosion limit, is reached. The European Standard EN1539:2000 requires explosion venting areas for most of these dryers without adequate explosion protection measures such as appropriate limitation of the solvent input being taken into account. Different aspects of the model underlying the calculations are evaluated, and it will be shown that this model is still reliable in most applications. The investigations consisted of three parts. At first there have been made investigations of the operating conditions in different enterprises aimed to get information about specific parameters, problems and failures. Laboratory experiments have been made to investigate in detail the major influencing parameters. Attempts to set up a simple but basic physical model for the experimental data have also been made. Evaporation and diffusion have been examined. The numerical models have been kept as simple as possible to be a potential tool for designers/manufacturers and users.