PubMed · 10740313
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S J Tank, S Malik, S M Joshi, M A Gaval, P Varthakavi. 1999. Familial hypoparathyroidism.. https://pubmed.ncbi.nlm.nih.gov/10740313/
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The first total synthesis of the natural cytotoxic agent sporiolide A has been accomplished from D-glucal in 16 steps with 6.1% overall yield. Carbohydrates were applied as the chiral templates to manipulate the absolute configuration during the synthesis. Pyridinium chlorochromate (PCC)-promoted transformation of the cyclic enol-ether to lactone, followed by Yamaguchi esterification and intramolecular ring closure metathesis, greatly facilitates synthesis of the target compound.
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