PubMed · 10660912
The source did not provide an abstract. Follow the original record for more information.
Explore connections, maps & timelines
D B Boyd. 1999. Quantum Chemistry Program Exchange.. https://pubmed.ncbi.nlm.nih.gov/10660912/
Cite the original work for its findings. Save a collection to share your selection of sources.
KEEP EXPLORING
Recent developments in characterising Langmuir monolayers of a variety of film-forming materials and employing several physicochemical techniques are reviewed. The extension of the LB method to non-amphiphilic substances, especially macromolecular systems, has increased the need of a thorough understanding of Langmuir film properties, which requires characterising techniques that provide complementary information. Since there is vast literature in the subject, only selected examples are given of results that illustrate the potential of the techniques discussed.
Explore the source record for details and available documents.
The beginning of the twentieth century saw the development of new theories of acidity and basicity, which are currently well accepted. The thermochemistry of proton transfer in the absence of solvent attracted much interest during this period, because of the fundamental importance of the process. Nevertheless, before the 1950s, few data were available, either from lattice energy evaluations or from calculations using the emerging molecular orbital theory. Advances in mass spectrometry during the last 40 years allowed studies of numerous systems with better accuracy. Thousands of accurate gas-phase acidities or basicities are now available, for simple atomic and molecular systems and for large biomolecules. The intrinsic effect of structure on the Brønsted basic or acidic properties of molecules and the influence of solvents have been unravelled. In this tutorial, the basics of the thermodynamic principles involved are given, and the mass spectrometric techniques are briefly reviewed. Advances in the design and measurements of gas-phase superacids and superbases are described. Recent studies concerning biomolecules are also evoked.