Metal-mediated C-H bond activation in a carbon-substituted hemiporphyrazine.
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Biomedical subjects
William S Durfee
Publications and source records attributed to William S Durfee.
Chloro and hydroxo forms of a boron(III) subtriazaporphyrin macrocycle.
cis-3,4-Dicyano-3-hexene undergoes cyclotrimerization with BCl3 to form the new subtriazaporphyrin chloro[hexaethylsubtriazaporphyrinato]boron(III). The hydroxo derivative of this macrocycle has also been made, and the X-ray crystal structure of the hydroxy form was determined. Electronic absorption and magnetic circular dichroism spectra of the hydroxo monomer species were interpreted using time-dependent density functional theory calculations.
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Synthesis of a quinone-functionalized macrocyclic ligand and the intense fluorescence of its zinc complex.
The redox-active quinone-functionalized macrocyclic ligand 1,4,14,17-tetrahydroxyhemiporphyrazine, H2hp(OH)4, has been synthesized and its zinc complex, [Zn(hp(OH)4)(py)], found to exhibit intense fluorescence.
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An optically-active subphthalocyanine dimer.
A subphthalocyanine (SubPc) dimer linked by racemic 1,1'-binaphth-2,2'-dioxy (BINOL), 1, has been synthesized and characterized by 1- and 2-D 1H NMR, high resolution mass spectrometry (FAB), X-ray crystallography and electronic absorption spectroscopy. Additionally, the dimer derived from optically-active (R)-(+)-BINOL, 2, has been made and studied using CD and MCD spectroscopies.
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cis and trans Forms of a binuclear subphthalocyanine.
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