Solid polymers: a challenge for NMR.
The sheer structural and motional complexity of polymers presents a formidable challenge to the power and versatility of NMR. This challenge is well met through exploitation of the plethora of experimental devices which have been developed over the past 50 years, among which the discovery of Magic Angle Spinning by Raymond Andrew features prominently. This paper presents a brief review of the subject in terms of a number of examples which illustrate the rich and detailed information which NMR provides.
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