Biomedical subjects

Stefan Vajda

Publications and source records attributed to Stefan Vajda.

5 recordsLinked to original sources

PubMed2005

Anomalous grazing incidence small-angle x-ray scattering studies of platinum nanoparticles formed by cluster deposition.

The size evolution of platinum nanoparticles formed on a SiO2/Si(111) substrate as a function of the level of surface coverage with deposited clusters has been investigated. The anisotropic shapes of sub-nanometer-size nanoparticles are changed to isotropic on the amorphous substrate as their sizes increased. Using anomalous grazing incidence small-angle x-ray scattering (AGISAXS), the scattering from nanoparticles on the surface of a substrate is well separated from that of surface roughness and fluorescence. We show that AGISAXS is a very effective method to subtract the background and can provide unbiased information about particle sizes of less than 1 nm.

Journal Article↗

PubMed2005

Ultrafast nuclear dynamics induced by photodetachment of Ag2- and Ag2O2-: oxygen desorption from a molecular silver surface.

Femtosecond nuclear dynamics of mass-selected neutral Ag2 and Ag2O2 clusters are investigated with the 'negative ion-to neutral-to positive ion'(NeNePo) technique. For the bare silver dimer, wave packet dynamics occurring in the neutral electronic ground state and in the first excited triplet state are observed after photodetachment from the anion with 3.05 eV photon energy. While the dynamics in the ground state lead to an oscillatory structure in the NeNePo-pump-probe spectra with a vibrational constant of 185 cm-1, the dynamics in the triplet state are assigned to a bound-free transition leading to dissociation. Photodetachment from the Ag2O2- complex results in the desorption of O2. The experimental data clearly show the influence of the desorbing oxygen ligand on the nuclear dynamics of the silver dimer inducing a red shift in the vibrational frequency and an intensity enhancement of the oscillatory signal.

Adsorption↗

PubMed2004

Strongly cluster size dependent reaction behavior of CO with O2 on free silver cluster anions.

Reactions of free silver anions Agn- (n = 1 - 13) with O2, CO, and their mixtures are investigated in a temperature controlled radio frequency ion trap setup. Cluster anions Agn- (n = 1 - 11) readily react with molecular oxygen to yield AgnOm- (m = 2, 4, or 6) oxide products. In contrast, no reaction of the silver cluster anions with carbon monoxide is detected. However, if silver cluster anions are exposed to the mixture of O2 and CO, new reaction products and a pronounced, discontinuous size dependence in the reaction behavior is observed. In particular, coadsorption complexes Agn(CO)O2- are detected for cluster sizes with n = 4 and 6 and, the most striking observation, in the case of the larger odd atom number clusters Ag7-, Ag9-, and Ag11-, the oxide product concentration decreases while a reappearance of the bare metal cluster signal is observed. This leads to the conclusion that carbon monoxide reacts with the activated oxygen on these silver clusters and indicates the prevalence of a catalytic reaction cycle.

Journal Article↗

PubMed2003

Deciphering the reaction dynamics underlying optimal control laser fields.

Femtosecond high-resolution pump-probe experiments have been used together with theoretical ab initio quantum calculations and wave packet dynamics simulations to decode an optimal femtosecond pulse that is generated from adaptive learning algorithms. This pulse is designed to maximize the yield of the organometallic ion CpMn(CO)3 while hindering the competing fragmentation. The sequential excitation and ionization of the target ion are accomplished by an optimized field consisting of two dominant subpulses with optimal frequencies and time delays.

Journal Article↗

PubMed2002

Observation and theoretical description of periodic geometric rearrangement in electronically excited nonstoichiometric sodium-fluoride clusters.

We present two-color fs pump-probe spectra of Na2F which were recorded by employing excitation wavelengths around 1208 nm (pump) and ionization wavelengths around 405 nm (probe). The observed oscillatory structure of the signal with a period of 185 fs shows an excellent agreement with our simulated spectra. The employed ab initio Wigner distribution approach provides clear evidence that this observation is caused by photoinduced metal bond breaking followed by a butterfly-type periodic geometric rearrangement.

Journal Article↗