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Biomedical subjects

S Zumer

Publications and source records attributed to S Zumer.

At least 19 recordsLinked to original sources

Annihilation of nematic point defects: pre-collision and post-collision evolution.

The annihilation of the nematic hedgehog and anti-hedgehog within an infinite cylinder of radius R is studied. The semi-microscopic lattice-type model and Brownian molecular dynamics are used. We distinguish among the i) early pre-collision, ii) late pre-collision, iii) early post-collision, and iv) late post-collision stages. In the pre-collision stage our results agree qualitatively with the existing experimental observations and also continuum-type simulations. The core of each defect exhibits a ring-like structure, where the ring axis is set perpendicular to the cylinder symmetry axis. For xi(0)d/(2R) > 1 the interaction between defects is negligible, where xi(0)d describes the initial separation of defects. Consequently, the defects annihilate within the simulation time window for xi(0)d/(2R) < 1. For close enough defects their separation scales as xi(d) [see text] (t(c)- t)(0.4+/-0.1), where t(c) stands for the collision time. In elastically anisotropic medium the hedgehog is faster than the anti-hedgehog. In the early pre-collision stage the defects can be treated as point-like particles, possessing inherent core structure, that interact via the nematic director field. In the late pre-collision stage the cores reflect the interaction between defects. After the collision a charge-less ring structure is first formed. In the early post-collision stage the ring adopts an essentially untwisted circular structure of the radius xi(r). In the late post-collision stage we observe two qualitatively different scenarios. For mu = xi(r)/R < mu(c) approximately 0.25 the ring collapses leading to the escaped radial equilibrium structure. For mu > mu(c) the chargeless ring triggers the nucleation growth into the planar polar structure with line defects.

Anisotropy↗

Casimir interaction in smectic-A liquid crystals caused by coupled fluctuations of positional and orientational order.

A theoretical study of the Casimir interaction in smectic-A systems, considering fluctuations of both types of smectic ordering--positional and orientational--including the coupling between them, is presented. Two model systems with plan-parallel geometry are studied: homeotropic cell and free-standing film. At large thicknesses of the system the behavior of the Casimir force is found to be primarily determined by positional fluctuations, whereas at small thicknesses also the orientational degrees of freedom greatly contribute to the interaction. The influence of different coupling strengths between orientational and positional order is presented. The dependence of the Casimir force on the director anchoring and surface-tension parameters is studied. The possibilities of experimental detection of the interaction are discussed.

Journal Article↗

Laser trapping of low refractive index colloids in a nematic liquid crystal.

We describe and analyze laser trapping of small colloidal particles in a nematic liquid crystal, where the index of refraction of colloids is smaller compared to the indices of the liquid crystal. Two mechanisms are identified that are responsible for this anomalous trapping: (i) below the optical Fréedericksz transition, the trapping is due to the anisotropic dielectric interaction of the polarized light with the inhomogeneous director field around the colloid, (ii) above the optical Fréedericksz transition, the optical trapping is accompanied by the elasticity-mediated interaction between the optically distorted region of a liquid crystal and the colloid. In the majority of the experiments, the trapping above the Fréedericksz transition is highly anisotropic. Qualitative agreement is found with a numerical analysis, considering the nematic director elastic distortion, dielectric director-light field coupling and optical repulsion due to low refraction index colloid in high index surroundings.

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Field-cycling NMR relaxometry of a liquid crystal above in mesoscopic confinement.

We measured the proton spin-lattice relaxation times in the isotropic phase of liquid crystal 4-n-pentyl-4-cyanobiphenyl (5CB) confined into porous glass (CPG) with the average pore diameter approximately 72 nm. The analysis of T1(-1) frequency dispersions, spanning over four decades, shows that the main relaxation mechanism induced by the ordered surface layer are molecular reorientations mediated by translational displacements (RMTD). The RMTD contribution to T1(-1) is proportional to the inverse square root of Larmor frequency, a consequence of the equipartition of diffusion modes along the surface. Low and high frequency cutoffs of the RMTD mechanism clearly reveal that the surface alignment of liquid crystal is random planar with the size of uniformly oriented patches approximately 5 nm, depending on the treatment of the CPG matrix. According to the size of the uniformly oriented patches varies also the thickness of the ordered surface layer and its temperature behavior. The surface-induced order parameter is found to be temperature independent and determined by the local short range surface interactions.

Journal Article↗

Dynamics of nematic liquid crystal disclinations: the role of the backflow.

We measure the electric-field-driven annihilation of nematic disclination pairs with strength +/- 1/2 in the 4-cyano-4'-n-pentylbiphenyl (5CB) liquid crystal. The use of a very weak azimuthal anchoring ensures a two-dimensional director field. The relaxation is governed by the formation of a pi wall connecting the two opposite charge defects. The +1/2 disclinations move almost twice as fast as the -1/2 disclinations. The simple used geometry allows a quantitative comparison with numerical studies based on the hydrodynamics of the tensorial order parameter. The simulations show that in the pi wall regime the symmetry breaking is due to the backflow and not to the elastic anisotropy.

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Evidence of supercritical behavior in liquid single crystal elastomers.

Temperature profiles of the first and the second moment of the nematic order parameter distribution function, as determined from the deuteron nuclear magnetic resonance line shapes, as well as heat capacity response, provide support for the supercritical scenario of the nematic-paranematic phase transition in liquid single crystal elastomers. The relative strength of the locked-in internal mechanical field with respect to the critical field can be decreased by swelling the elastomer samples with low molecular mass nematogen. By increasing the concentration of the dopant, critical and below-critical behavior is promoted.

Journal Article↗

Anchoring and structural transitions as a function of molecular length in confined liquid crystals.

Using deuteron nuclear magnetic resonance to study liquid crystals confined to cylindrical pores, an anchoring transition has been found. The transition exhibits an unexpected sharp dependence of the anchoring strength on cyanobiphenyl liquid crystal molecular length. A structural transition from a parallel axial to a planar radial configuration occurs due to an anchoring transition from planar to weakly homeotropic orientation at the walls. The anchoring strength is at a minimum near the decylcyanobiphenyl (10CB) liquid crystal length. Long chain liquid crystal configurations depend on thermal cycling and on the equilibrium atmosphere leading to a bistable SmA structure. Orientational order wetting in the isotropic phase also depends on molecular length.

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Instability modes of high-strength disclinations in nematics.

We solve the complete tensor fluctuation problem of a long and straight nematic disclination line with a general winding number in the one elastic constant approximation. Focusing on the eigenmodes growing in time, we show that the disclination with strength higher than 1/2 is unstable with respect to the splitting and for integer strength also to the escape--in both cases there is no metastability. Numerically we show that a moderate elastic anisotropy, e.g., as found in thermotropic liquid crystals like 5CB or MBBA, does not introduce any metastability either.

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Annihilation of edge dislocations in smectic-A liquid crystals.

This paper presents a theoretical study of the annihilation of edge dislocations in the same smectic plane in a bulk smectic-A phase. We use a time-dependent Landau-Ginzburg approach where the smectic ordering is described by the complex order parameter psi( r--> ,t) =eta e(iphi) . This quantity allows both the degree of layering and the position of the layers to be monitored. We are able to follow both precollision and postcollision regimes, and distinguish different early and late behaviors within these regimes. The early precollision regime is driven by changes in the phi ( r--> ) configuration. The relative velocity of the defects is approximately inversely proportional to the interdefect separation distance. In the late precollision regime the symmetry changes within the cores of defects also become influential. Following the defect collision, in the early postcollision stage, bulk layer order is approached exponentially in time. At very late times, however, there seems to be a long-time power-law tail in the order parameter fluctuation relaxation.

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Fluctuations of topological disclination lines in nematic liquid crystals: renormalization of the string model.

Using the tensorial Landau-de Gennes theory, we study the fluctuations of a disclination line in a nematic liquid crystal. By analyzing the structure and the spectrum of the eigenmodes of a line of strength +/-1/2 , we reassess the concept of line tension used in the simple string model of the disclination showing that it does not include the complete set of eigenmodes and must be renormalized. In general, the line tension considerably underestimates the thermal amplitude of a disclination and we find that it is only applicable to severely confined disclinations.

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Morphology and structure of thin liquid-crystalline films at nematic-isotropic transition.

We review the main features of very thin nematic liquid-crystalline films on solid substrates, focusing on 5CB on oxidized silicon wafers. By discussing the theoretical aspects of the observed structures, we show that the phenomena at work include isotropic capillary condensation and that the coexistence of isotropic and nematic terraces in thin films is a result of the interplay of several mechanisms. Further theoretical as well as experimental efforts are needed to completely understand the wetting behavior of these systems.

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External and intrinsic anchoring in nematic liquid crystals: a Monte Carlo study.

We present a Monte Carlo study of external surface anchoring in nematic cells with partially disordered solid substrates, as well as of intrinsic anchoring at free nematic interfaces. The simulations are based on the simple hexagonal lattice model with a spatially anisotropic intermolecular potential. We estimate the corresponding extrapolation length b by imposing an elastic deformation in a hybrid cell-like nematic sample. Our estimates for b increase with increasing surface disorder and are essentially temperature independent. Experimental values of b are approached only when both the coupling of nematic molecules with the substrate and the anisotropy of nematic-nematic interactions are weak.

Journal Article↗

Pseudo-Casimir force in chiral smectic liquid crystals.

We present a theoretical study of the pseudo-Casimir force in two chiral smectic systems: a homeotropic cell and a free-standing film. We consider the interaction induced by the fluctuations of orientational order. We demonstrate how the character of the force depends on the type of fluctuation modes and on boundary conditions. We focus on the temperature dependence of the force, which is marked by the vicinity of the smectic-A*-->smectic-C* phase transition. We find that at this transition the force diverges if the system is frustrated; otherwise it remains finite. We expose the analogy between the force in these smectic systems and in previously studied nematic systems, thus demonstrating the universality of the pseudo-Casimir interaction.

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Capillary forces in a confined isotropic-nematic liquid crystal.

We have investigated nematic capillary condensation in the isotropic phase of nematic liquid crystals 5CB (4-cyano-4(')-n-pentylbiphenyl) and 8CB (4-cyano-4(')-n-octylbiphenyl) confined to nanometer thick layers between two orienting surfaces. The capillary condensation was induced by decreasing the liquid crystal layer thickness using an atomic force microscope, and the onset of condensation was detected by monitoring the structural force on a confining surface. Very strong and long-ranged capillary forces were observed at temperatures close to the isotropic-nematic transition. We have analyzed the temperature dependence of the thickness of the liquid crystal layer, at which the condensation occurs, with a thermodynamic Kelvin equation and determined the interfacial tension between the isotropic and nematic phases. The separation dependence of capillary forces was analyzed within the Landau-de Gennes approach, including electrostatic interaction due to surface charging. The quantitative agreement between the measured and calculated force profiles is very good, and a single set of parameters is needed to describe a set of measured force profiles at different temperatures. Surface charge density, surface potential, and Debye screening length were determined directly from the observed surface forces.

Biophysical Phenomena↗

Structures and transitions in thin hybrid nematic films: a Monte Carlo study.

We confirm by Monte Carlo simulations of a Lebwohl-Lasher lattice spin model the existence of a biaxially ordered nonbent structure in a liquid-crystalline cell subject to opposing boundary conditions. We report on the observation of the bending transition from the biaxial to the bent-director structure when the temperature of the system is lowered. The structural transition is monitored both by the change of the order parameters and by heat capacity. We discuss the thickness dependence of the transition temperature by means of wetting-induced phenomena and elastic deformations. We propose the correspondence to the phenomenological description, which agrees well without any fitting parameters.

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Hydrodynamics of pair-annihilating disclinations in SmC films.

The pair annihilation of smectic c-director defects with winding numbers +/-1 in a freestanding SmC film as a representative of the XY model is studied numerically, considering a full coupling of orientational degrees of freedom and hydrodynamics. A reduction of the annihilation time compared to the nonhydrodynamic treatment is observed. It is demonstrated that the +1 disclination moves considerably faster than the -1 one primarily due to hydrodynamic flow, weakly assisted also by elastic anisotropy. The stress tensor terms and material parameters relevant for this effect are identified.

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Nematics with dispersed polymer fibrils: a Monte Carlo study of the external-field-induced switching.

We present a Monte Carlo study of molecular ordering in nematics with dispersed regular and random arrays of straight and distorted polymer fibrils. We focus on the collective molecular reorientation--the switching--resulting from the competing aligning effects of fibrils and of a progressively applied transversal external field, and for straight fibrils identify structural Fréedericksz and saturation transitions. The role of fibril topography in the switching is monitored by simulating electric capacitance Slightly distorted fibrils are shown to give a sharper switching at a lower threshold.

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Surface ordering transitions at a liquid crystal-solid interface above the isotropic smectic-A transition.

The degree of orientational order induced by confining cylindrical surfaces is monitored via deuteron nuclear magnetic resonance linesplitting and linewidth above the smectic-A to isotropic phase transition. The orientational order strongly depends on the length of the surfactant coupling molecule, on the surface coverage, and on the liquid crystal. Continuous and stepwise growth of orientational order and surface-induced orientational order transitions found in the isotropic phase are explained in terms of a simplified model of surface-induced layering and molecular self-diffusion.

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