Biomedical subjects
Publications and source records attributed to R G Craig.
The relationship between the wear of three composite resins and the hardness of the abrasive was studied by a two-body abrasion test. The wear rates of the composites increased linearly with abrasive hardness from 530 to 2080 KHN. Measurement of the slope of the wear rate versus abrasive hardness over this range provided a sensitive method for ranking the composites.
Two methods for controlling the working time of an addition-type silicone impression material are presented. The progress of the polymerization reaction of this modified system was studied using viscosity and a new "compression set" technique. The physical properties are presented and compared to those typical of condensation silicones, and a method of clinical use is suggested.
The color stability of a series of eleven maxillofacial pigments was determined after accelerated aging using reflection spectrophotometry. The results indicate that seven of the pigments demonstrated good to excellent color stability, while four of the pigments were less promising for clinical use.
The resistance of three silicone and one polyvinyl chloride maxillofacial materials to staining by tea, lipstick, and disclosing solution was measured by reflectance spectrophotometry. Changes in color caused by staining were larger than changes caused by color instability of the base elastomers or pigments under conditions of accelerated aging.
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The creep compliance and dynamic modulus of two tissue conditioners and five soft liners were determined after storage in water at 37 degrees C. Under static conditions the tissue conditioners functioned like viscous liquids, whereas the soft liners were more elastic. In general, linear viscoelasticity was not observed. Under dynamic conditions, the materials were stiffer.
A hydrophobic restorative composite based on a fluorocarbon analog of an alkyl methacrylate and a bisphenol adduct was formulated into a one-paste system, which polymerized in the presence of blue light. Physical, mechanical and water-related properties were determined. High contact angles and low water sorption were shown by the experimental composite. Capillary penetration of oral fluids around restorations, therefore, could be prevented in the presence of this highly hydrophobic surface. The physical and mechanical properties of the experimental composite were either comparable to or somewhat less favorable than commercial Bis-GMA composites.
Wear of microfilled composites, a visible light-cured composite, and a conventional composite were characterized by two-body abrasion and single-pass sliding. There were differences in abrasion rates among the materials. Tangential forces, wear track widths, and surface failure modes were different among materials. Wear characteristics are combinations of these properties.
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A concentrated load of 222 N in the region of the central fossa of the second molar resulted in stresses in the supporting bone which increased gradually from zero in the region of the retromolar pad to about 25 MN/m2 distal to the second molar. Stresses in the alveolar bone supporting the second premolar were about 30 MN/m2 at the cemento-enamel junction, decreased to about 20 MN/m2 distal to the apex of the root, increased to 100 MN/m2 at the apex, and decreased to 3 MN/m2 near the mesial upper third of the root surface. When a distributed load of 222 N was applied to the first and second molar region, the stress distribution was similar to that observed for the concentrated load, and stress magnitudes were about 20% lower. Dramatic decreases in stress, with the maximum stress at the apex being 40 MN/m2, occurred when a 222 N load was distributed in the area of the marginal ridge.
Creep compliance measurements were shown to be effective in characterizing the elastic, retarded elastic, and viscous properties of polysulphide, silicone, and polyether impression materials. The test is particularly valuable in that the creep compliance was independent of load, allowing the mechanical properties to be represented by a single total creep compliance curve which can be used to determine the various creep components. The total recovered compliance was shown to be independent of time provided the polymerization had progressed sufficiently before testing was done. The retarded elastic and viscous compliances contributed proportionally to the total creep compliance and thus did not affect the rankings of materials. The viscous compliance of polysulphide A decreased enough after 1 h so that the creep compliance of A and D were not different. The creep compliance measurements showed that the polysulphide materials were the most viscoelastic followed by silicone and polyether impression materials. The polyether was the most nearly ideal elastic material but it had a flexibility comparable to heavy body polysulphide. Of particular interest was the observation that polyether with thinner in ratios up to 1 : 1 by length had no practical effect on the viscoelastic properties.
Synthetic HAP made in the laboratory as 'synthetic bone' may be a possible replacement or repair material, since the mineral phase of dental hard tissue and bone is essentially hydroxyapatite in form. Hydroxyapatite or modified compositions of HAP appear to offer possibilities as a substitute for the original material provided by nature. A high surface area (70.4 m2/g) commercially available hydroxyapatite (HAP) of poor crystallinity was converted to a highly crystalline HAP through sintering at 1200 degrees C in an atmosphere of steam and nitrogen. Compacts were made of the powdered HAP from 500 to 25,000 psi and sintered under the same conditions. The changes in the resulting pore volumes, pore sizes, pore size distributions, densities, and surface areas of the sintered compacts were determined by mercury porosimetry. A 20-fold reduction in open pore volume for sintered compacts was observed. For compacts made at pressures above 5000 psi, the reduction in open pore volume was compensated for by the formation of closed pore volume. The sintering mechanism was attributed mainly to neck formation, growth between particles, diffusion, and plastic deformation.
Ten dental impression waxes were characterized by penetration and differential thermal analysis. Penetration and initial transition temperatures were directly correlated. Penetration at 37 C ranged from 2.5 to 22% for bite waxes and was 100% for corrective waxes. Distortion of an impression wax may occur upon removal from the mouth.
A series of polyurethane elastomers based on an aliphatic diisocyanate and a polyether macroglycol was polymerized with various cross-link densities and OH/NCO ratios. Stoichiometries yielding between 8,600 and 12,900 gm/mole/crosslink and an OH/NCO ratio of 1.1 resulted in polymers with the low modulus, yet high strength and elongation necessary for maxillofacial applications.
Polished enamel surfaces were etched with various commercial and experimental etching solutions and evaluated for changes in surface profile and topography. Enamel surfaces that were exposed to solutions of phosphoric acid in a concentration between 37% and 50% for a minute gave the most suitable surfaces for retention of the polymer. Enamel surfaces that were roughened with a diamond stone were not etched uniformly. Enamel that was exposed to acid etching solutions was better protected by a polycarboxylate cement than by either calcium hydroxide or zinc phosphate.
The wear of cental amalgam was studied by single- and double-pass sliding and by a silicon carbide abrasion test. A dispersed amalgam showed significantly better resistance to two-body abrasion than the spherical amalgams tested. The wear amalgam was determined by resistance to penetration and by a ductile mode of surface failure over the load range studied. Differences in the wear of amalgam and restorative resins and composites are discussed.