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Biomedical subjects

R E Jentoft

Publications and source records attributed to R E Jentoft.

6 recordsLinked to original sources
PubMed2006

Diesel engine exhaust emission: oxidative behavior and microstructure of black smoke soot particulate.

Soot particulate collected from a Euro III heavy duty diesel engine run under black smoke conditions was investigated using thermogravimetry, transmission electron microscopy, electron energy loss spectroscopy, and X-ray photoelectron spectroscopy. The characterization results are compared with those of commercial carbon black. The onset temperature toward oxidation of the diesel engine soot in 5% O2 is 150 degrees C lower than that for carbon black. The burn out temperature for the diesel engine soot is 60 degrees C lower than that of the carbon black. The soot primary particles exhibit a core-shell structure. The shell of the soot particles consists of homogeneously stacked basic structure units. The commercial carbon lamp black is more graphitized than the diesel engine soot, whereas the diesel engine soot contains more carbon in aromatic nature than the carbon black and is highly surface-functionalized. Our findings reveal that technical carbon black is not a suitable model for the chemistry of the diesel engine soot.

Air Pollutants↗
PubMed2001

Manganese, iron and sulfur K edge XAFS of promoted sulfated zirconia catalysts.

Promoted sulfated zirconia samples were prepared by the incipient wetness technique to produce isomerization catalysts which were active for the conversion of n-butane to isobutane at 338K (up to 10% conversion of 1% n-butane, 1atm., 0.25 h(-1) WHSV). The local structure of Fe and Mn in promoted sulfated zirconia was investigated using fluorescence yield XAS. Spectra were taken of calcined samples, activated samples, and samples after reaction with n-butane (maximum activity and deactivated). Factor analysis reveals that the Mn K edge XANES can be described by a linear combination of the spectra of two separate components, and that the ratio of these components changes with activation of the catalyst, and during use in the n-butane isomerization reaction. The change in ratio of the Mn species during activation and reaction results in a reduction of the average Mn valence from 2.4 to 2.2. The Fe K edge XANES was not similarly affected by activation and reaction with n-butane.

Journal Article↗