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PubMed2006

Depletion forces between nonspherical objects.

We extend the insertion approach for calculating depletion potentials to the case of nonspherical solutes. We suggest to employ the recently developed curvature expansion of density profiles close to complexly shaped walls. The approximations introduced in the calculation by the use of the curvature expansion and of weight functions for nonspherical objects can be tested independently. As an application for our approach we calculate and discuss the depletion potential between two hard oblate ellipsoids in a solvent of hard spheres. For this system we calculate the entropic force and torque acting on the objects.

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PubMed2004

Morphological thermodynamics of fluids: shape dependence of free energies.

We examine the dependence of a thermodynamic potential of a fluid on the geometry of its container. If motion invariance, continuity, and additivity of the potential are satisfied, only four morphometric measures are needed to describe fully the influence of an arbitrarily shaped container on the fluid. These three constraints can be understood as a more precise definition for the conventional term extensive and have as a consequence that the surface tension and other thermodynamic quantities contain, aside from a constant term, only contributions linear in the mean and Gaussian curvature of the container and not an infinite number of curvatures as generally assumed before. We verify this numerically in the entropic system of hard spheres bounded by a curved wall.

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