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Biomedical subjects

P Zeppenfeld

Publications and source records attributed to P Zeppenfeld.

At least 19 recordsLinked to original sources

Strain oscillations probed with light.

We show that reflectance difference spectroscopy (RDS) is sensitive to the inhomogeneous surface and thin film strain which builds up during hetero- and homoepitaxial growth. The RDS signal is affected by the local, mean square atomic displacements in the substrate resulting from the stress relaxation of strained adlayer islands. For layer-by-layer growth an oscillatory variation of the RDS intensity is observed. These results demonstrate the potentiality of RDS to probe the growth kinetics on structurally anisotropic surfaces.

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Adsorption of argon on carbon nanotube bundles and its influence on the bundle lattice parameter.

We report experimental studies of the adsorption characteristics and structure of both 36Ar and 40Ar on single-wall carbon nanotube bundles. The structural studies make use of the large difference in coherent neutron scattering cross section for the two Ar isotopes to explore the influence of the adsorbate on the nanotube lattice parameter. We observe no dilation of the nanotube lattice with 40Ar, and explain the apparent expansion of this lattice upon 36Ar adsorption by the location of the adsorbed Ar atoms on the outer bundle surface.

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Enhanced optical sensitivity to adsorption due to depolarization of anisotropic surface states.

Reflectance difference spectroscopy is used to probe the optical transitions between surface states on the Cu(110) surface. Upon deposition of smallest amounts of carbon monoxide (CO) the signal is strongly quenched, which translates into a huge cross section of the order of 1000 A(2) for a single adsorbed CO molecule. This strongly enhanced surface sensitivity is interpreted as the loss in anisotropy (depolarization) of the surface states due to scattering from the adsorbed CO molecules. This feature renders RDS an extremely sensitive tool to probe the adsorption kinetics on anisotropic metal surfaces.

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