Biomedical subjects

P Karamchandani

Publications and source records attributed to P Karamchandani.

4 recordsLinked to original sources

PubMed2000

On artificial dilution of point source mercury emissions in a regional atmospheric model

Previously, we developed and applied a regional atmospheric mercury model to a domain covering most of North America at a horizontal grid resolution of 100 km. The implication of using this coarse resolution is that point sources of mercury emissions are instantaneously spread over a grid volume of horizontal dimensions 100 x 100 km2 and a vertical dimension equal to the depth of the grid cell where the point source emissions are released. Since point sources comprise a significant majority of a regional mercury emissions inventory, it is important to understand what effect this artificial dilution may have on calculated mercury concentrations and deposition fluxes. To understand this effect, we conducted model simulations using a finer grid, embedded within the original coarse grid, over a sub-domain that includes over 50% of the largest mercury point sources in the north-eastern United States. The horizontal resolution of the fine grid is 20 km, i.e. it is five times smaller than that of the coarse grid. We compared short-term (daily) and long-term (annual) averaged mercury concentrations, and deposition (wet and dry) fluxes on the coarse and fine grids. As expected, the effect of grid resolution is more clearly seen in close proximity to point sources than at remote locations. For short-term averages near major point sources, the peak concentrations and dry deposition fluxes of mercury from the fine grid are almost a factor of two greater than the corresponding estimates from the coarse grid. At remote locations, however, the concentrations and dry deposition peaks estimated by the two model grid resolutions are more comparable. For total wet deposition of mercury, the distinction between the fine and the coarse grid model results is less significant, regardless of the location. This could be due to the redistribution of precipitation fields or the effect of mercury aqueous chemistry. The effect of grid resolution is more important when model estimates are averaged over short time periods, e.g. daily, as opposed to over long periods, e.g. seasonally and annually.

Journal Article↗

PubMed2000

Assessment of the nested grid model estimates for driving regional visibility models in the southwestern United States.

The Nested Grid Model (NGM) is a primitive-equation meteorological model that is routinely exercised over North America for forecasting purposes by the National Meteorological Center. While prognostic meteorological models are being increasingly used to drive air quality models, their use in conducting annual simulations requires significant resources. NGM estimates of wind fields and other meteorological variables provide an attractive alternative since they are typically archived and readily available for an entire year. Preliminary evaluation of NGM winds during the summer of 1992 for application to the region surrounding the Grand Canyon National Park showed serious shortcomings. The NGM winds along the borders between California, Arizona and Mexico tend to be northwesterly with a speed of about 6 m/sec, while the observed flow is predominantly southerly at about 2-5 m/sec. The mesoscale effect of a thermal low pressure area over the highly heated Southern California and western Arizona deserts does not appear to be represented by the NGM because of its coarse resolution and the use of sparse observations in that region. Tracer simulations and statistical evaluation against special high resolution observations of winds in the southwest United States clearly demonstrate the northwest bias in NGM winds and its adverse effect on predictions of an air quality model. The "enhanced" NGM winds, in which selected wind observations are incorporated in the NGM winds using a diagnostic meteorological model provide additional confirmation on the primary cause of the northwest bias. This study has demonstrated that in situations where limited resources prevent the use of prognostic meteorological models, previously archived coarse resolution wind fields in which additional observations are incorporated to correct known biases provide an attractive option.

Aerosols↗

PubMed2000

Simulation of stack plume opacity.

The visual impact of primary particles emitted from stacks is regulated according to stack opacity criteria. In-stack monitoring of the flue gas opacity allows plant operators to ensure that the plant meets U.S. Environmental Protection Agency opacity regulations. However, the emission of condensable gases such as SO3 (that hydrolyzes to H2SO4), HCl, and NH3, which may lead to particle formation after their release from the stack, makes the prediction of stack plume opacity more difficult. We present here a computer simulation model that calculates the opacity due to both primary particles emitted from the stack and secondary particles formed in the atmosphere after the release of condensable gases from the stack. A comprehensive treatment of the plume rise due to buoyancy and momentum is used to calculate the location at which the condensed water plume has evaporated (i.e., where opacity regulations apply). Conversion of H2SO4 to particulate sulfate occurs through nucleation and condensation on primary particles. A thermodynamic aerosol equilibrium model is used to calculate the amount of ammonium, chloride, and water present in the particulate phase with the condensed sulfate. The model calculates the stack plume opacity due to both primary and secondary particles. Examples of model simulations are presented for three scenarios that differ by the emission control equipment installed at the power plant: (1) electrostatic precipitators (ESP), (2) ESP and flue gas desulfurization, and (3) ESP and selective catalytic reduction. The calculated opacity is most sensitive to the primary particulate emissions. For the conditions considered here, SO3 emissions showed only a small effect, except if one assumes that most H2SO4 condenses on primary particles. Condensation of NH4Cl occurs only at high NH3 emission rates (about 25 ppm stack concentration).

Aerosols↗

PubMed1992

The development of the acid deposition and oxidant model (ADOM).

This paper describes the development and testing of the Acid Deposition and Oxidant Model (ADOM), a nine-year project funded by a consortium consisting of Environment Ontario, Environment Canada, the German Umweltbundesamt, and the Electric Power Research Institute. The project consisted of three major phases: a design phase, an implementation phase, and an evaluation phase. In the design phase, the system being modeled was divided into its components-transport, gas phase chemistry, aqueous phase chemistry, dry deposition and cloud processes. The formulation of the modules for each of these processes was guided by the requirement that the modules reflect the state of the art, and at the same time be consistent with the available numerical resources. In the implementation phase, submodels were constructed, and then subjected to several tests, which included mathematical consistency checks, sensitivity studies, and evaluation against field and laboratory data. The modules were then assembled and interfaced with the input data sets. The codes for the modules as well as the overall model were vectorized to take advantage of the capabilities of supercomputers such as the CRAY. The North American and West German versions of the model are being tested against data collected in North America and in Europe. This paper describes the evaluation of ADOM with data associated with a regional ozone episode in Ontario in June 1983, and measurements made during an experiment to study the scavenging characteristics of spring storms in the central and northeastern United States in April 1981.

Journal Article↗