Search PubMed⌕ Search

Biomedical subjects

P Bennema

Publications and source records attributed to P Bennema.

10 recordsLinked to original sources

Interlacing of growth steps on crystal surfaces as a consequence of crystallographic symmetry.

During crystal growth, concentric steps of unit-layer thickness [= dhklu with the surface's hkl Miller indices corrected according to the selection rules for non-primitive lattices] are often found to split into lower steps in a regular fashion [Frank (1951). Phil. Mag. 42, 1014-1021]. These 'interlaced' step patterns are introduced by a stacking of two or more growth layers, with different lateral anisotropy in step velocity within each unit layer. In this paper, a general relation between the symmetry of the crystal surface and the configuration of the concentric step patterns thereon is derived and is used to give theoretical shapes of spirals, growth hillocks and etch pits. It is shown that many of the interlaced patterns and their details are imposed by the presence of screw axes and/or glide planes perpendicular to the crystal surface. Finally, the results are compared with the patterns of unit-layer height and lower steps observed by optical and atomic force microscopy on crystals such as SiC, GaN, potash alum, garnet and NiSO4*6H2O.

Journal Article↗

On the prediction of crystal morphology. III. Equilibrium and growth behaviour of crystal faces containing multiple connected nets.

In this paper, the equilibrium and growth behaviour of faces (hkl) with more than one connected net is studied. It is shown that for these types of orientation different surface phases exist under equilibrium conditions as a function of temperature. Depending on the exact bonding topology at the surface, flat, rough or disordered flat phases are found. Moreover, the growth rate R(hkl) of such faces can differ significantly from the usually calculated relative growth rates based on the attachment energy. Monte Carlo simulations confirm the results from the Hartman-Perdok analyses and offer a tool for the prediction of the crystal habit as a function of supersaturation.

Journal Article↗